Citation: Fang Yongzheng, Yang Bowen, He Dongtong, Li Huipeng, Zhu Kai, Wu Lin, Ye Ke, Cheng Kui, Yan Jun, Wang Guiling, Cao Dianxue. Porous and free-standing Ti₃C₂T_x-RGO film with ultrahigh gravimetric capacitance for supercapacitors[J]. Chinese Chemical Letters, ;2020, 31(4): 1004-1008. doi: 10.1016/j.cclet.2019.08.043 shu

Porous and free-standing Ti₃C₂T_x-RGO film with ultrahigh gravimetric capacitance for supercapacitors

Fang Yongzheng ^a,1 ,
Yang Bowen ^a,1 ,
He Dongtong ^a ,
Li Huipeng ^a ,
Zhu Kai ^a,c,*, ,
Wu Lin ^b,**, ,
Ye Ke ^a ,
Cheng Kui ^a ,
Yan Jun ^a ,
Wang Guiling ^a ,
Cao Dianxue ^a,*,

a.
Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China
b.
Teachers Education College of Harbin Normal University, Harbin 150001, China
c.
Key Laboratory of Advanced Chemical Power Sources, Guizhou Meiling Power Sources Co., Ltd., Zunyi 563003, China

^**

kzhu@hrbeu.edu.cn

hsdhxwulin@163.com

caodianxue@hrbeu.edu.cn

Received Date: 29 July 2019
Revised Date: 15 August 2019
Accepted Date: 19 August 2019
Available Online: 26 August 2019

Figures(4)

MXene-based electrode materials exhibit favorable supercapacitor performance in sulfuric acid due to praised pseudocapacitance charge storage mechanism. However, self-stacking of conventional MXene electrodes severely restricts their electrochemical performance, especially at high loading. Herein, a flexible cross-linked porous Ti₃C₂T_x-MXene-reduced graphene oxide (Ti₃C₂T_x-RGO) film is skillfully designed and synthesized by microscopic explosion of graphene oxide (GO) at sudden high temperature. The generated chamber structure between layers could hold a few of electrolyte, leading to a close-fitting reaction at interlayer and avoiding complex ions transmission paths. The Ti₃C₂T_x-RGO film displayed a preferable rate performance than that of pure Ti₃C₂T_x film and a high capacitance of 505 F/g at 2 mV/s. Furthermore, the uniform intralayer structure and unique energy storage process lead to thickness-independenct electrochemical performances. This work provides a simple and feasible improvement approach for the design of MXene-based electrodes, which can be spread other electrochemical systems limited by ions transport, such as metal ions batteries and catalysis.
- MXene,
- RGO,
- Cross-linked porous,
- Supercapacitors,
- High capacitance,
- Thickness independent
1. [1]
  Y. Wang, Y. Song, Y. Xia, Chem. Soc. Rev. 45(2016) 5925-5950. doi: 10.1039/C5CS00580A
2. [2]
  M.R. Lukatskaya, S. Kota, Z. Lin, et al., Nat. Energy 2(2017) 17105. doi: 10.1038/nenergy.2017.105
3. [3]
  M. Boota, Y. Gogotsi, Adv. Energy Mat. 9(2019) 1802917. doi: 10.1002/aenm.201802917
4. [4]
  Q. Jiang, N. Kurra, M. Alhabeb, Y. Gogotsi, H.N. Alshareef, Adv. Energy Mater. 8(2018) 1703043. doi: 10.1002/aenm.201703043
5. [5]
  X. Zhang, P. Yu, H. Zhang, et al., Electrochim. Acta 89(2013) 523-529. doi: 10.1016/j.electacta.2012.11.089
6. [6]
  X. Zhang, X. Sun, H. Zhang, D. Zhang, Y. Ma, Electrochim. Acta 87(2013) 637-644. doi: 10.1016/j.electacta.2012.10.022
7. [7]
  X. Zhang, X. Sun, H. Zhang, C. Li, Y. Ma, Electrochim. Acta 132(2014) 315-322. doi: 10.1016/j.electacta.2014.03.176
8. [8]
  J. Qin, Z.S. Wu, F. Zhou, et al., Chin. Chem. Lett. 29(2018) 582-586. doi: 10.1016/j.cclet.2017.08.007
9. [9]
  Y. Chen, C. Chen, R. Lv, et al., Chin. Chem. Lett. 29(2018) 616-619.
10. [10]
  F. Liu, Z. Chen, G. Fang, et al., Nano-Micro Lett. 11(2019) 25. doi: 10.1007/s40820-019-0256-2
11. [11]
  Y. Yang, Y. Tang, G. Fang, et al., Energy Environ. Sci. 11(2018) 3157-3162. doi: 10.1039/C8EE01651H
12. [12]
  C. Wang, P. Sun, G. Qu, J. Yin, X. Xu, Chin. Chem. Lett. 29(2018) 1731-1740. doi: 10.1016/j.cclet.2018.12.005
13. [13]
  Y. Xia, T.S. Mathis, M.Q. Zhao, et al., Nature 557(2018) 409-412. doi: 10.1038/s41586-018-0109-z
14. [14]
  K. Zhu, Y. Jin, F. Du, et al., J. Energy Chem. 31(2019) 11-18. doi: 10.1016/j.jechem.2018.03.010
15. [15]
  J. Yan, C.E. Ren, K. Maleski, et al., Adv. Funct. Mater. 27(2017) 1701264. doi: 10.1002/adfm.201701264
16. [16]
  Q. Shan, X. Mu, M. Alhabeb, et al., Electrochem. Commun. 96(2018) 103-107. doi: 10.1016/j.elecom.2018.10.012
17. [17]
  S. Zhao, X. Meng, K. Zhu, et al., Energy Storage Mater. 8(2017) 42-48. doi: 10.1016/j.ensm.2017.03.012
18. [18]
  M. Hu, Z. Li, T. Hu, et al., ACS Nano 10(2016) 11344-11350. doi: 10.1021/acsnano.6b06597
19. [19]
  X. Liu, R. Zhang, W. Yu, et al., Energy Storage Mater. 11(2018) 83-90. doi: 10.1016/j.ensm.2017.09.008
20. [20]
  D. Lin, Y. Liu, Z. Liang, et al., Nat. Nanotechnol. 11(2016) 626. doi: 10.1038/nnano.2016.32
21. [21]
  Z. Ma, K. Wang, Y. Qiu, et al., Energy 143(2018) 43-55. doi: 10.1016/j.energy.2017.10.110
22. [22]
  M.Q. Zhao, X. Xie, C.E. Ren, et al., Adv. Mater. 29(2017) 1702410. doi: 10.1002/adma.201702410
23. [23]
  H. Hu, Z. Zhao, W. Wan, Y. Gogotsi, J. Qiu, Adv. Mater. 25(2013) 2219-2223. doi: 10.1002/adma.201204530
24. [24]
  Y. Fang, R. Hu, B. Liu, et al., J. Mater. Chem. 7(2019) 5363-5372.
25. [25]
  Y. Luan, R. Hu, Y. Fang, et al., Nano-Micro Lett. 11(2019) 30. doi: 10.1007/s40820-019-0260-6
1. [1]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
2. [2]
  Fangling Cui , Zongjie Hu , Jiayu Huang , Xiaoju Li , Ruihu Wang . MXene-based materials for separator modification of lithium-sulfur batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100337-100337. doi: 10.1016/j.cjsc.2024.100337
3. [3]
  Tong Su , Yue Wang , Qizhen Zhu , Mengyao Xu , Ning Qiao , Bin Xu . Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage. Chinese Chemical Letters, 2024, 35(8): 109191-. doi: 10.1016/j.cclet.2023.109191
4. [4]
  Xiangyuan Zhao , Jinjin Wang , Jinzhao Kang , Xiaomei Wang , Hong Yu , Cheng-Feng Du . Ni nanoparticles anchoring on vacuum treated Mo2TiC2Tx MXene for enhanced hydrogen evolution activity. Chinese Journal of Structural Chemistry, 2023, 42(10): 100159-100159. doi: 10.1016/j.cjsc.2023.100159
5. [5]
  Changle Liu , Mingyuzhi Sun , Haoran Zhang , Xiqian Cao , Yuqing Li , Yingtang Zhou . All in one doubly pillared MXene membrane for excellent oil/water separation, pollutant removal, and anti-fouling performance. Chinese Journal of Structural Chemistry, 2024, 43(8): 100355-100355. doi: 10.1016/j.cjsc.2024.100355
6. [6]
  Kun Rong , Cuilian Wen , Jiansen Wen , Xiong Li , Qiugang Liao , Siqing Yan , Chao Xu , Xiaoliang Zhang , Baisheng Sa , Zhimei Sun . 层状MoS₂/Ti₃C₂T_x异质结光热转换材料用于太阳能驱动水蒸发. Acta Physico-Chimica Sinica, 2025, 41(6): 100053-. doi: 10.1016/j.actphy.2025.100053
7. [7]
  Minying Wu , Xueliang Fan , Wenbiao Zhang , Bin Chen , Tong Ye , Qian Zhang , Yuanyuan Fang , Yajun Wang , Yi Tang . Highly dispersed Ru nanospecies on N-doped carbon/MXene composite for highly efficient alkaline hydrogen evolution. Chinese Chemical Letters, 2024, 35(4): 109258-. doi: 10.1016/j.cclet.2023.109258
8. [8]
  Yaping Wang , Pengcheng Yuan , Zeyuan Xu , Xiong-Xiong Liu , Shengfa Feng , Mufan Cao , Chen Cao , Xiaoqiang Wang , Long Pan , Zheng-Ming Sun . Ti₃C₂T_x MXene in-situ transformed Li₂TiO₃ interface layer enabling 4.5 V-LiCoO₂/sulfide all-solid-state lithium batteries with superior rate capability and cyclability. Chinese Chemical Letters, 2024, 35(6): 108776-. doi: 10.1016/j.cclet.2023.108776
9. [9]
  Jingxuan Liu , Shiqi Zhao , Xiang Wu . Flexible electrochemical capacitor based NiMoSSe electrode material with superior cycling and structural stability. Chinese Chemical Letters, 2024, 35(7): 109059-. doi: 10.1016/j.cclet.2023.109059
10. [10]
  Min LUO , Xiaonan WANG , Yaqin ZHANG , Tian PANG , Fuzhi LI , Pu SHI . Porous spherical MnCo₂S₄ as high-performance electrode material for hybrid supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 413-424. doi: 10.11862/CJIC.20240205
11. [11]
  Jieqiong Qin , Zhi Yang , Jiaxin Ma , Liangzhu Zhang , Feifei Xing , Hongtao Zhang , Shuxia Tian , Shuanghao Zheng , Zhong-Shuai Wu . Interfacial assembly of 2D polydopamine/graphene heterostructures with well-defined mesopore and tunable thickness for high-energy planar micro-supercapacitors. Chinese Chemical Letters, 2024, 35(7): 108845-. doi: 10.1016/j.cclet.2023.108845
12. [12]
  Zixuan Guo , Xiaoshuai Han , Chunmei Zhang , Shuijian He , Kunming Liu , Jiapeng Hu , Weisen Yang , Shaoju Jian , Shaohua Jiang , Gaigai Duan . Activation of biomass-derived porous carbon for supercapacitors: A review. Chinese Chemical Letters, 2024, 35(7): 109007-. doi: 10.1016/j.cclet.2023.109007
13. [13]
  Ting Shi , Ziyang Song , Yaokang Lv , Dazhang Zhu , Ling Miao , Lihua Gan , Mingxian Liu . Hierarchical porous carbon guided by constructing organic-inorganic interpenetrating polymer networks to facilitate performance of zinc hybrid supercapacitors. Chinese Chemical Letters, 2025, 36(1): 109559-. doi: 10.1016/j.cclet.2024.109559
14. [14]
  Xiaoxing Ji , Xiaojuan Li , Chenggang Wang , Gang Zhao , Hongxia Bu , Xijin Xu . Ni_xB/rGO as the cathode for high-performance aqueous alkaline zinc-based battery. Chinese Chemical Letters, 2024, 35(10): 109388-. doi: 10.1016/j.cclet.2023.109388
15. [15]
  Hao Deng , Yuxin Hui , Chao Zhang , Qi Zhou , Qiang Li , Hao Du , Derek Hao , Guoxiang Yang , Qi Wang . MXene−derived quantum dots based photocatalysts: Synthesis, application, prospects, and challenges. Chinese Chemical Letters, 2024, 35(6): 109078-. doi: 10.1016/j.cclet.2023.109078
16. [16]
  Rui Liu , Jinbo Pang , Weijia Zhou . Monolayer water shepherding supertight MXene/graphene composite films. Chinese Journal of Structural Chemistry, 2024, 43(10): 100329-100329. doi: 10.1016/j.cjsc.2024.100329
17. [17]
  Yiyue Ding , Qiuxiang Zhang , Lei Zhang , Qilu Yao , Gang Feng , Zhang-Hui Lu . Exceptional activity of amino-modified rGO-immobilized PdAu nanoclusters for visible light-promoted dehydrogenation of formic acid. Chinese Chemical Letters, 2024, 35(7): 109593-. doi: 10.1016/j.cclet.2024.109593
18. [18]
  Hui Gu , Mingyue Gao , Kuan Shen , Tianli Zhang , Junhao Zhang , Xiangjun Zheng , Xingmei Guo , Yuanjun Liu , Fu Cao , Hongxing Gu , Qinghong Kong , Shenglin Xiong . F127 assisted fabrication of Ge/rGO/CNTs nanocomposites with three-dimensional network structure for efficient lithium storage. Chinese Chemical Letters, 2024, 35(9): 109273-. doi: 10.1016/j.cclet.2023.109273
19. [19]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
20. [20]
  Junqi Wang , Shuai Zhang , Jingjing Ma , Xiangjun Liu , Yayun Ma , Zhimin Fan , Jingfeng Wang . Augmenting levoglucosan production through catalytic pyrolysis of biomass exploiting Ti₃C₂T_x MXene. Chinese Chemical Letters, 2024, 35(12): 109725-. doi: 10.1016/j.cclet.2024.109725

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1113)
HTML views(16)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Porous and free-standing Ti3C2Tx-RGO film with ultrahigh gravimetric capacitance for supercapacitors

Metrics

通讯作者: 陈斌, bchen63@163.com

Porous and free-standing Ti₃C₂T_x-RGO film with ultrahigh gravimetric capacitance for supercapacitors