Citation: He Hongtian, Xia Qixun, Wang Bingxin, Wang Libo, Hu Qianku, Zhou Aiguo. Two-dimensional vanadium carbide (V₂CT_x) MXene as supercapacitor electrode in seawater electrolyte[J]. Chinese Chemical Letters, ;2020, 31(4): 984-987. doi: 10.1016/j.cclet.2019.08.025 shu

Two-dimensional vanadium carbide (V₂CT_x) MXene as supercapacitor electrode in seawater electrolyte

School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, China

xqx@hpu.edu.cn

zhouag@hpu.edu.cn

Received Date: 11 June 2019
Revised Date: 8 August 2019
Accepted Date: 11 August 2019
Available Online: 16 August 2019

Figures(2)

In this study, two-dimensional V₂CT_x MXene has been prepared by selectively etching Al layers from V₂AlC MAX phase by NaF+HCl etching at 90 ℃ for 72 h and its performance as supercapacitor (SC) electrode were tested using simulating seawater as electrolyte. V₂CT_x MXene-based electrodes shows a good capacitance of 181.1 F/g, which is in accordance with the volumetric specific capacitance of 317.8 F/cm³, and with 89.1% capacitance retention even after 5000 cycle. Compared with other MXenes, V₂CT_x have better electrochemical performance as SC electrode. This work provides an innovative strategy to apply V₂CT_x MXene as SC electrode in safety and effective seawater electrolyte.
- MXene,
- Two-dimensional carbide,
- V₂CT_x,
- Supercapacitor,
- Seawater
1. [1]
  M. Naguib, O. Mashtalir, J. Carle, et al., ACS Nano 6 (2012) 1322-1331. doi: 10.1021/nn204153h
2. [2]
  S.P. Zhang, X.Z. Song, S.H. Liu, et al., Electrochim. Acta 312 (2019) 1-10. doi: 10.1016/j.electacta.2019.04.177
3. [3]
  M.A. Bissett, I.A. Kinloch, R.A.W. Dryfe, ACS Appl. Mater. Inter. 7 (2015) 17388-17398. doi: 10.1021/acsami.5b04672
4. [4]
  L.J. Cao, S.B. Yang, W. Gao, et al., Small 9 (2013) 2905-2910. doi: 10.1002/smll.201203164
5. [5]
  S. Dong, X. He, H. Zhang, et al., J. Mater. Chem. A 6 (2018) 15954-15960. doi: 10.1039/C8TA04080J
6. [6]
  X. He, N. Zhang, X. Shao, et al., Chem. Eng. J. 297 (2016) 121-127. doi: 10.1016/j.cej.2016.03.153
7. [7]
  X. He, X. Li, H. Ma, et al., J. Power Sources 340 (2017) 183-191. doi: 10.1016/j.jpowsour.2016.11.073
8. [8]
  X. He, H. Zhang, H. Zhang, et al., J. Mater. Chem. A 2 (2014) 19633-19640. doi: 10.1039/C4TA03323J
9. [9]
  L. Zu, X. Gao, H.Q. Lian, et al., J. Alloys Compd. 770 (2019) 26-34. doi: 10.1016/j.jallcom.2018.07.265
10. [10]
  M.W. Barsoum, MAX Phases: Properties of Machinable Ternary Carbides and Nitrides, Wiley-VCH, Weinheim, 2013.
11. [11]
  M.W. Barsoum, Prog. Solid State Chem. 28 (2000) 201-281. doi: 10.1016/S0079-6786(00)00006-6
12. [12]
  D. Er, J. Li, M. Naguib, Y. Gogotsi, V.B. Shenoy, ACS Appl. Mater. Interface 6 (2014) 11173-11179. doi: 10.1021/am501144q
13. [13]
  Q. Tang, Z. Zhou, P. Shen, J. Am. Chem. Soc. 134 (2012) 16909-16916. doi: 10.1021/ja308463r
14. [14]
  X. Wang, T.S. Mathis, K. Li, et al., Nat. Energy 4 (2019) 241. doi: 10.1038/s41560-019-0339-9
15. [15]
  M.R. Lukatskaya, S. Kota, Z. Lin, et al., Nat. Energy 2 (2017) 17105. doi: 10.1038/nenergy.2017.105
16. [16]
  M.R. Lukatskaya, O. Mashtalir, C.E. Ren, et al., Science 341 (2013) 1502-1505. doi: 10.1126/science.1241488
17. [17]
  M.D. Levi, M.R. Lukatskaya, S. Sigalov, et al., Adv. Energy Mater. 5 (2015) 1400815. doi: 10.1002/aenm.201400815
18. [18]
  B.S. Shen, H. Wang, L.J. Wu, et al., Chin. Chem. Lett. 27 (2016) 1586-1591. doi: 10.1016/j.cclet.2016.04.012
19. [19]
  M. Kurtoglu, M. Naguib, Y. Gogotsi, M.W. Barsoum, MRS Commun. 2 (2012) 133-137. doi: 10.1557/mrc.2012.25
20. [20]
  Y. Zhu, S. Murali, M.D. Stoller, et al., Science 332 (2011) 1537-1541. doi: 10.1126/science.1200770
21. [21]
  P. Simon, Y. Gogotsi, Materials for Electrochemical Capacitors, World Scientific, 2010, pp. 320-329.
22. [22]
  J. Yan, Q. Wang, T. Wei, Z. Fan, Adv. Energy Mater. 4 (2014) 1300816. doi: 10.1002/aenm.201300816
23. [23]
  C. Wang, P. Sun, G. Qu, J. Yin, X. Xu, Chin. Chem. Lett. 29 (2018) 1731-1740. doi: 10.1016/j.cclet.2018.12.005
24. [24]
  N.M. Shinde, Q.X. Xia, P.V. Shinde, et al., ACS Appl. Mater. Inter.11 (2019) 4551-4559. doi: 10.1021/acsami.8b17689
25. [25]
  N.M. Shinde, Q.X. Xia, J.M. Yun, et al., Electrochim. Acta 296 (2019) 308-316. doi: 10.1016/j.electacta.2018.11.044
26. [26]
  T.F. Zhang, Q.X. Xia, Z. Wan, et al., Chem. Eng. J. 360 (2019) 1310-1319. doi: 10.1016/j.cej.2018.10.220
27. [27]
  M. Ghidiu, M.R. Lukatskaya, M.Q. Zhao, Y. Gogotsi, M.W. Barsoum, Nature 516 (2014) 78-81.
28. [28]
  Z. Ling, C.E. Ren, M.Q. Zhao, et al., Proc. Natl. Acad. Sci. U. S. A.111 (2014) 16676-16681. doi: 10.1073/pnas.1414215111
29. [29]
  R. Rakhi, B. Ahmed, M.N. Hedhili, D.H. Anjum, H.N. Alshareef, Chem. Mater. 27 (2015) 5314-5323. doi: 10.1021/acs.chemmater.5b01623
30. [30]
  M. Ghidiu, M.R. Lukatskaya, M.Q. Zhao, Y. Gogotsi, M.W. Barsoum, Nature 516 (2014) 78. doi: 10.1038/nature13970
31. [31]
  Q.X. Xia, N.M. Shinde, J.M. Yun, et al., Electrochim. Acta 271 (2018) 351-360. doi: 10.1016/j.electacta.2018.03.168
32. [32]
  A. Byeon, A.M. Glushenkov, B. Anasori, et al., E. J. Power Sources 326 (2016) 686-694. doi: 10.1016/j.jpowsour.2016.03.066
33. [33]
  Y. Yoon, M. Lee, S.K. Kim, et al., Adv. Energy Mater. 8 (2018) 1703173. doi: 10.1002/aenm.201703173
34. [34]
  D. Sun, Q. Hu, J. Chen, et al., ACS Appl. Mater. Inter. 8 (2016) 74. doi: 10.1021/acsami.5b03863
35. [35]
  M. Naguib, J. Halim, J. Lu, et al., J. Am. Chem. Soc. 135 (2013) 15966-15969. doi: 10.1021/ja405735d
36. [36]
  F. Liu, J. Zhou, S. Wang, et al., J. Electrochem. Soc. 164 (2017) A709-A713. doi: 10.1149/2.0641704jes
37. [37]
  C. Eames, M.S. Islam, J. Am. Chem. Soc. 136 (2014) 16270-16276. doi: 10.1021/ja508154e
38. [38]
  Y. Xie, Y. Dall'Agnese, M. Naguib, et al., ACS Nano 8 (2014) 9606-9615. doi: 10.1021/nn503921j
39. [39]
  Y. Dall'Agnese, P.L. Taberna, Y. Gogotsi, P. Simon, J. Phys. Chem. Lett. 6 (2015) 2305-2309. doi: 10.1021/acs.jpclett.5b00868
40. [40]
  Q. Shan, X. Mu, M. Alhabeb, et al., Electrochem. Commun. 96 (2018) 103-107. doi: 10.1016/j.elecom.2018.10.012
41. [41]
  K. Fic, G. Lota, M. Meller, E. Frackowiak, Energy Environ. Sci. 5 (2012) 5842-5850. doi: 10.1039/C1EE02262H
42. [42]
  J.K. Kim, E. Lee, H. Kim, et al., ChemElectroChem 2 (2015) 328-332. doi: 10.1002/celc.201402344
43. [43]
  Y. Liu, X. Zhang, S. Dong, Z. Ye, Y. Wei, J. Mater. Sci. 52 (2017) 2200-2209. doi: 10.1007/s10853-016-0509-0
44. [44]
  A. Lipatov, H. Lu, M. Alhabeb, et al., Sci. Adv. 4 (2018) eaat0491. doi: 10.1126/sciadv.aat0491
45. [45]
  R.B. Rakhi, B. Ahmed, M.N. Hedhili, D.H. Anjum, H.N. Alshareef, Chem. Mater. 27 (2015) 5314-5323. doi: 10.1021/acs.chemmater.5b01623
46. [46]
  J. Xie, P. Yang, Y. Wang, et al., J. Power Sources 401 (2018) 213-223. doi: 10.1016/j.jpowsour.2018.08.090
47. [47]
  Y. Xie, Y. Dall'Agnese, M. Naguib, et al., ACS Nano 8 (2014) 9606-9615. doi: 10.1021/nn503921j
48. [48]
  C.J. Zhao, Q. Wang, H. Zhang, S. Passerini, X.Z. Qian, ACS Appl. Mater. Interface 8 (2016) 15661-15667. doi: 10.1021/acsami.6b04767
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4. [4]
  Tong Su , Yue Wang , Qizhen Zhu , Mengyao Xu , Ning Qiao , Bin Xu . Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage. Chinese Chemical Letters, 2024, 35(8): 109191-. doi: 10.1016/j.cclet.2023.109191
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沈阳化工大学材料科学与工程学院沈阳 110142

Two-dimensional vanadium carbide (V2CTx) MXene as supercapacitor electrode in seawater electrolyte

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Two-dimensional vanadium carbide (V₂CT_x) MXene as supercapacitor electrode in seawater electrolyte