Citation: Dong Yu, Li Siwu, Hong Shanshan, Wang Lu, Wang Bo. Metal-organic frameworks and their derivatives for Li-air batteries[J]. Chinese Chemical Letters, ;2020, 31(3): 635-642. doi: 10.1016/j.cclet.2019.08.021 shu

Metal-organic frameworks and their derivatives for Li-air batteries

Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Key Laboratory of Cluster Science, Ministry of Education, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China

luwang@bit.edu.cn

bowang@bit.edu.cn

Received Date: 1 May 2019
Revised Date: 17 June 2019
Accepted Date: 15 August 2019
Available Online: 7 September 2019

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Metal-organic frameworks (MOFs) are a class of outstanding materials in Li-air batteries because of their high surface areas, tailorable pore sizes and diverse catalytic centers. However, MOF-based batteries are facing challenges such as poor electronic conductivity and inferior long-cycle stability that limit their further development. This review first summarizes the progress of pristine MOFs and MOF-derived materials in Li-air batteries in the past 5 years, then provides a perspective for subsequent development of MOFs and their derivatives in this emerging field.
- Metal-organic frameworks,
- MOF-derived materials,
- Li-air batteries,
- Li-O₂ batteries,
- Li-CO₂ batteries
1. [1]
  F. Cheng, J. Chen, Chem. Soc. Rev. 41(2012) 2172-2192. doi: 10.1039/c1cs15228a
2. [2]
  J.S. Lee, S. Tai Kim, R. Cao, et al., Adv. Energy Mater. 1(2011) 34-50. doi: 10.1002/aenm.201000010
3. [3]
  Q. Liu, Z. Chang, Z. Li, et al., Small Methods 2 (2018) 1700231.
4. [4]
  D. Larcher, J.M. Tarascon, Nat. Chem. 7(2015) 19-29. doi: 10.1038/nchem.2085
5. [5]
  P.G. Bruce, S.A. Freunberger, L.J. Hardwick, et al., Nat. Mater. 11(2011) 19-29.
6. [6]
  D. Aurbach, B.D. McCloskey, L.F. Nazar, et al., Nat. Energy 1 (2016) 16128.
7. [7]
  M. Asadi, B. Sayahpour, P. Abbasi, et al., Nature 555(2018) 502-506. doi: 10.1038/nature25984
8. [8]
  G. Girishkumar, B. McCloskey, A.C. Luntz, et al., J. Phys. Chem. Lett. 1(2010) 2193-2203. doi: 10.1021/jz1005384
9. [9]
  H. Furukawa, K.E. Cordova, M. O'Keeffe, et al., Science 341 (2013) 1230444.
10. [10]
  J.R. Li, R.J. Kuppler, H.C. Zhou, Chem. Soc. Rev. 38(2009) 1477-1504. doi: 10.1039/b802426j
11. [11]
  J.R. Li, Y. Ma, M.C. McCarthy, et al., Coord. Chem. Rev. 255(2011) 1791-1823. doi: 10.1016/j.ccr.2011.02.012
12. [12]
  D. Farrusseng, S. Aguado, C. Pinel, Angew. Chem. 48(2009) 7502-7513. doi: 10.1002/anie.200806063
13. [13]
  D.M. D'Alessandro, B. Smit, J.R. Long, Angew. Chem. 49(2010) 6058-6082. doi: 10.1002/anie.201000431
14. [14]
  A. Corma, H. Garci'a, F.X. Llabre's i Xamena, Chem. Rev. 110(2010) 4606-4655. doi: 10.1021/cr9003924
15. [15]
  L. Wang, Y. Han, X. Feng, et al., Coord. Chem. Rev. 307(2016) 361-381. doi: 10.1016/j.ccr.2015.09.002
16. [16]
  X. Zhang, A. Chen, M. Zhong, et al., Electrochem. Energy Rev. 2(2018) 29-104.
17. [17]
  R. Zhao, Z. Liang, R. Zou, et al., Joule 2(2018) 2235-2259. doi: 10.1016/j.joule.2018.09.019
18. [18]
  J. Zhou, B. Wang, Chem. Soc. Rev. 46(2017) 6927-6945. doi: 10.1039/C7CS00283A
19. [19]
  D. Wu, Z. Guo, X. Yin, et al., Adv. Mater. 26(2014) 3258-3262. doi: 10.1002/adma.201305492
20. [20]
  X. Hu, Z. Zhu, F. Cheng, et al., Nanoscale 7(2015) 11833-11840. doi: 10.1039/C5NR02487K
21. [21]
  W. Yan, Z. Guo, H. Xu, et al., Mater. Chem. Front. 1(2017) 1324-1330. doi: 10.1039/C6QM00338A
22. [22]
  M. Yuan, R. Wang, W. Fu, et al., ACS Appl. Mater. Interfaces 11(2019) 11403-11413. doi: 10.1021/acsami.8b21808
23. [23]
  S.H. Kim, Y.J. Lee, D.H. Kim, et al., ACS Appl. Mater. Interfaces 10(2017) 660-667.
24. [24]
  Y. Qiao, Y. He, S. Wu, et al., ACS Energy Lett. 3(2018) 463-468. doi: 10.1021/acsenergylett.8b00014
25. [25]
  L. Cao, F. Lv, Y. Liu, et al., Chem. Commun. 51(2015) 4364-4367. doi: 10.1039/C4CC09281C
26. [26]
  K. Takechi, T. Shiga, T. Asaoka, Chem. Commun. 47(2011) 3463-3465. doi: 10.1039/c0cc05176d
27. [27]
  L. Qie, Y. Lin, J.W. Connell, et al., Angew. Chem. 56(2017) 6970-6974. doi: 10.1002/anie.201701826
28. [28]
  F. Cai, Z. Hu, S.-L. Chou, Adv. Sustain. Syst. 2 (2018) 1800060.
29. [29]
  S. Xu, S.K. Das, L.A. Archer, RSC Adv. 3(2013) 6656-6660. doi: 10.1039/c3ra40394g
30. [30]
  Z. Zhao, J. Huang, Z. Peng, Angew. Chem. 57(2018) 3874-3886. doi: 10.1002/anie.201710156
31. [31]
  S. Li, Y. Dong, J. Zhou, et al., Energy Environ. Sci. 11(2018) 1318-1325. doi: 10.1039/C8EE00415C
32. [32]
  Z. Lyu, G.J.H. Lim, R. Guo, et al., Adv. Funct. Mater. 29 (2019) 1806658.
33. [33]
  X. Meng, K. Liao, J. Dai, et al., ACS Appl. Mater. Interfaces 11(2019) 20091-20097. doi: 10.1021/acsami.9b05235
34. [34]
  X.F. Lu, L.F. Gu, J.W. Wang, et al., Adv. Mater. 29 (2017) 1604437.
35. [35]
  L. Yan, L. Cao, P. Dai, et al., Adv. Funct. Mater. 27 (2017) 1703455.
36. [36]
  B. You, N. Jiang, M. Sheng, et al., ACS Catal. 5(2015) 7068-7076. doi: 10.1021/acscatal.5b02325
37. [37]
  S. Zhao, Y. Wang, J. Dong, et al., Nat. Energy 1 (2016) 16184.
38. [38]
  H. Wang, F. Yin, P. Lv, et al., Int. J. Hydrogen Energy 42(2017) 2127-2133. doi: 10.1016/j.ijhydene.2016.11.118
39. [39]
  J. Tang, S. Wu, T. Wang, et al., ACS Appl. Mater. Interfaces 8(2016) 2796-2804. doi: 10.1021/acsami.5b11252
40. [40]
  M.J. Song, I.T. Kim, Y.B. Kim, et al., Electrochim. Acta 182(2015) 289-296. doi: 10.1016/j.electacta.2015.09.100
41. [41]
  G. Zhao, Y. Liu, L. Tang, et al., ACS Appl. Energy Mater. 2(2019) 2113-2121. doi: 10.1021/acsaem.8b02154
42. [42]
  X. Chen, C. Chen, X. Zhang, et al., ChemistrySelect 3(2018) 9276-9283. doi: 10.1002/slct.201801904
43. [43]
  A. Li, X. Zhang, Z. Xie, et al., Inorg. Chem. 57(2018) 14476-14479. doi: 10.1021/acs.inorgchem.8b02544
44. [44]
  C. Hua, Z. Qian, M. Chen, et al., J. Alloys Compd. 749(2018) 378-384. doi: 10.1016/j.jallcom.2018.03.297
45. [45]
  W. Chen, Z. Zhang, W. Bao, et al., Electrochim. Acta 134(2014) 293-301. doi: 10.1016/j.electacta.2014.04.110
46. [46]
  Y. Gan, Y. Lai, Z. Zhang, et al., J. Alloys. Compd. 665(2016) 365-372. doi: 10.1016/j.jallcom.2016.01.087
47. [47]
  W. Yin, Y. Shen, F. Zou, et al., ACS Appl. Mater. Interfaces 7(2015) 4947-4954. doi: 10.1021/am509143t
48. [48]
  Y. Kang, D. Zou, J. Zhang, et al., Electrochim. Acta 244(2017) 222-229. doi: 10.1016/j.electacta.2017.05.100
49. [49]
  Y. Ma, C.W. Tai, R. Younesi, et al., Chem. Mater. 27(2015) 7698-7709. doi: 10.1021/acs.chemmater.5b03288
50. [50]
  M. Prabu, P. Ramakrishnan, H. Nara, et al., ACS Appl. Mater. Interfaces 6(2014) 16545-16555. doi: 10.1021/am5047476
51. [51]
  L. Zhou, D. Zhao, X.W. Lou, Adv. Mater. 24(2012) 745-748. doi: 10.1002/adma.201104407
52. [52]
  J. Zhang, L. Wang, L. Xu, et al., Nanoscale 7(2015) 720-726. doi: 10.1039/C4NR05865H
53. [53]
  J. Li, Y. Deng, L. Leng, et al., ACS Sustain. Chem. Eng. 7(2018) 2296-2303.
54. [54]
  Q. Li, P. Xu, W. Gao, et al., Adv. Mater. 26(2014) 1378-1386. doi: 10.1002/adma.201304218
55. [55]
  Y. Lai, W. Chen, Z. Zhang, et al., Electrochim. Acta 191(2016) 733-742. doi: 10.1016/j.electacta.2016.01.134
56. [56]
  H. Yu, K.N. Dinh, Y. Sun, et al., Nanoscale 10(2018) 14877-14884. doi: 10.1039/C8NR04319A
57. [57]
  K. Liao, T. Zhang, Y. Wang, et al., ChemSusChem 8(2015) 1429-1434. doi: 10.1002/cssc.201403371
58. [58]
  H.T. Bui, D.Y. Kim, D.W. Kim, et al., Carbon 130(2018) 94-104. doi: 10.1016/j.carbon.2017.12.111
59. [59]
  F.L. Meng, Z.W. Chang, J.J. Xu, et al., Mater. Horiz. 5(2018) 298-302. doi: 10.1039/C7MH01014A
60. [60]
  X. Guo, J. Han, P. Liu, et al., Sci. Rep. 6 (2016) 33466.
61. [61]
  Y.C. Lu, Z. Xu, H.A. Gasteiger, et al., J. Am. Chem. Soc. 132(2010) 12170-12171. doi: 10.1021/ja1036572
62. [62]
  F.S. Ke, B.C. Solomon, S.G. Ma, et al., Electrochim. Acta 85(2012) 444-449. doi: 10.1016/j.electacta.2012.08.023
63. [63]
  K. Liao, X. Wang, Y. Sun, et al., Energy Environ. Sci. 8(2015) 1992-1997. doi: 10.1039/C5EE01451D
64. [64]
  R. Bi, G. Liu, C. Zeng, et al., Small 15 (2019) e1804958.
65. [65]
  R. Gao, Z. Shang, L. Zheng, et al., Inorg. Chem. 58(2019) 4989-4996. doi: 10.1021/acs.inorgchem.9b00007
66. [66]
  S. Lee, G.H. Lee, J.C. Kim, et al., ACS Catal. 8(2018) 2601-2610. doi: 10.1021/acscatal.7b03741
67. [67]
  G. Tan, L. Chong, R. Amine, et al., Nano Lett. 17(2017) 2959-2966. doi: 10.1021/acs.nanolett.7b00207
68. [68]
  Y. Dou, R. Lian, Y. Zhang, et al., J. Mater. Chem. A 6(2018) 8595-8603. doi: 10.1039/C8TA01913D
69. [69]
  M. Zhong, X. Zhang, D.H. Yang, et al., Inorg. Chem. Front. 4(2017) 1533-1538.
70. [70]
  S. Li, Y. Liu, J. Zhou, et al., Energy Environ. Sci. 12(2019) 1046-1054. doi: 10.1039/C8EE03283A
71. [71]
  L. Jiao, H.L. Jiang, Chemistry 5(2019) 786-804. doi: 10.1016/j.chempr.2018.12.011
72. [72]
  Y. Chen, S. Ji, C. Chen, et al., Joule 2(2018) 1242-1264. doi: 10.1016/j.joule.2018.06.019
73. [73]
  J. Wang, W. Liu, G. Luo, et al., Energy Environ. Sci. 11(2018) 3375-3379. doi: 10.1039/C8EE02656D
74. [74]
  L. Liu, C. Du, S. Wang, et al., Chin. Chem. Lett. 29(2018) 1781-1784. doi: 10.1016/j.cclet.2018.10.002
75. [75]
  Z. Jiang, T. Liu, L. Yan, et al., Energy Storage Mater. 11(2018) 267-273. doi: 10.1016/j.ensm.2017.11.003
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