Citation: Song Yu, He Xing, Yu Bing, Li Hong-Ru, He Liang-Nian. Protic ionic liquid-promoted synthesis of dimethyl carbonate from ethylene carbonate and methanol^☆[J]. Chinese Chemical Letters, ;2020, 31(3): 667-672. doi: 10.1016/j.cclet.2019.07.053 shu

Protic ionic liquid-promoted synthesis of dimethyl carbonate from ethylene carbonate and methanol^☆

Song Yu ^a ,
He Xing ^a ,
Yu Bing ^b ,
Li Hong-Ru ^a,c,*, ,
He Liang-Nian ^a,*,

a.
State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
b.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China
c.
College of Pharmacy, Nankai University, Tianjin 300353, China

^☆

lihongru@nankai.edu.cn

helnnk@126.com

heln@nankai.edu.cn

Received Date: 30 June 2019
Revised Date: 17 July 2019
Accepted Date: 25 July 2019
Available Online: 27 July 2019

Figures(6)

In this work, the protic ionic liquid [DBUH] [Im] (1, 8-diazabicyclo[5.4.0]-7-undeceniumimidazolide) was developed as an efficient catalyst for the transesterification of ethylene carbonate with methanol to produce dimethyl carbonate. At 70 ℃, up to 97% conversion of ethylene carbonate and 91% yield of dimethyl carbonate were obtained with 1 mol% [DBUH] [Im] (relative to ethylene carbonate) as catalyst in 2 h. Even at room temperature, the conversion of ethylene carbonate can reach 94% and the yield of dimethyl carbonate can approach 81% for 6 h. Catalytic mechanism investigation showed the high catalytic efficiency of this ionic liquid results from the synergistic activation effect, wherein the cation can activate ethylene carbonate and the anion can activate methanol through hydrogen bond formation. Although the reusability of the ionic liquid need to be further improved, high efficiency and commercial availability of [DBUH] [Im] render it a promising catalyst for the preparation of dimethyl carbonate.
- Dimethyl carbonate,
- Transesterification,
- Protic ionic liquid,
- Synergistic effect,
- Sustainable chemistry
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沈阳化工大学材料科学与工程学院沈阳 110142

Protic ionic liquid-promoted synthesis of dimethyl carbonate from ethylene carbonate and methanol☆

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通讯作者: 陈斌, bchen63@163.com

Protic ionic liquid-promoted synthesis of dimethyl carbonate from ethylene carbonate and methanol^☆