Citation: Huang Qiang, Zhu Lei, Yi Dong, Zhao Xiaohui, Wei Wei. Silver-mediated aminophosphinoylation of propargyl alcohols with aromatic amines and H-phosphine oxides leading to α-aminophosphine oxides[J]. Chinese Chemical Letters, ;2020, 31(2): 373-376. doi: 10.1016/j.cclet.2019.07.049 shu

Silver-mediated aminophosphinoylation of propargyl alcohols with aromatic amines and H-phosphine oxides leading to α-aminophosphine oxides

Huang Qiang ^a ,
Zhu Lei ^a ,
Yi Dong ^b,**, ,
Zhao Xiaohui ^c,**, ,
Wei Wei ^c,d,*,

a.
Department of Clinical Pharmacy, School of Pharmacy, Zunyi Medical University, Zunyi 563099, China
b.
School of Pharmacy, Southwest Medical University, Luzhou 646000, China
c.
Qinghai Provincial Key Laboratory of Tibetan Medicine Research and Key Laboratory of Tibetan Medicine Research, Northwest Institute of Plateau Biology, Chinese Academy of Sciences, Xining 810008, China
d.
School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China

^**

Received Date: 1 June 2019
Revised Date: 17 July 2019
Accepted Date: 24 July 2019
Available Online: 25 July 2019

Figures(5)

A new silver mediated aminophosphinoylation of propargyl alcohols with aromatic amines and Hphosphine oxides for the construction of α-aminophosphine oxides has been developed. The C-N and C-P bond could be efficiently formed in one pot operation via sequential C-C and C-O bond cleavage of propargylic alcohols. This present methodology, which not only provides a simple and alternative strategy for the synthesis of α-aminophosphine oxides, but also opens a new window for the cleavage reactions of propargyl alcohols via dealkynalation coupling.
- Silver,
- Aminophosphinoylation,
- C-C bond cleavage,
- Propargylic alcohols,
- α-Aminophosphine oxides
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