Citation: Ji Yaqiang, Xie Jinqi, Yang Ying, Fu Xianzhu, Sun Rong, Wong Chingping. NiCoP 1D nanothorns grown on 3D hierarchically porous Ni films for high performance hydrogen evolution reaction[J]. Chinese Chemical Letters, ;2020, 31(3): 855-858. doi: 10.1016/j.cclet.2019.06.021 shu

NiCoP 1D nanothorns grown on 3D hierarchically porous Ni films for high performance hydrogen evolution reaction

Ji Yaqiang ^a,b ,
Xie Jinqi ^a ,
Yang Ying ^b ,
Fu Xianzhu ^a,c,*, ,
Sun Rong ^a,*, ,
Wong Chingping ^d

a.
Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China
b.
Key Laboratory of Low-grade Energy Utilization Technologies and Systems, Chongqing University, Chongqing 400044, China
c.
College of Materials Science and Engineering, Shenzhen University, Shenzhen 518055, China
d.
Department of Electronics Engineering, The Chinese University of Hong Kong, Hong Kong, China

xz.fu@szu.edu.cn

rong.sun@siat.ac.cn

Received Date: 12 April 2019
Revised Date: 20 May 2019
Accepted Date: 11 June 2019
Available Online: 12 June 2019

Figures(4)

Highly efficient, cost-effective, and durable electrocatalysts for hydrogen evolution reaction (HER) in water splitting is crucial for energy conversion and storage. Herein, we report NiCoP 1D nanothorn arrays grown on 3D porous Ni film current collectors (Ni/NiCoP) as the novel electrocatalytic electrodes. The 3D hierarchically porous nickel films containing large 7 ± 2 μm pores and small pores less than 1 μm are obtained through using hydrogen bubbles dynamic template method. The NiCoP 1D nanothorns are about 70 nm in diameter and 4-8 μm in length. The porous Ni/NiCoP electrocatalytic electrodes demonstrate much higher catalytic activity and remarkable stability for long-term HER. The excellent electrocatalytic performance might be attributed to the inherent nature of highly catalytic active NiCo bimetal phosphides and the unique architecture of 1D nanothorn active materials directly integrated on the 3D hierarchically porous metallic nickel conductive skeletons. The developed electrode has been fabricated to the integrated solar-driven seawater-splitting system.
- Porous Ni,
- Current collector,
- NiCoP nanothorns,
- Electrochemical property,
- Seawater-splitting system
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