Citation: Zhou Haitao, Yang Kang, Liu Yao, Tang Yunzhi, Wei Wenjuan, Shu Qing, Zhao Jinjun, Tan Yuhui. In situ[2 + 3] cycloaddition synthesis, crystal structures, strong SHG responses and fluorescence properties of three novel Zn coordination polymers[J]. Chinese Chemical Letters, ;2020, 31(3): 841-845. doi: 10.1016/j.cclet.2019.06.017 shu

In situ[2 + 3] cycloaddition synthesis, crystal structures, strong SHG responses and fluorescence properties of three novel Zn coordination polymers

School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China

tyxcn@163.com

Received Date: 3 April 2019
Revised Date: 3 June 2019
Accepted Date: 10 June 2019
Available Online: 11 June 2019

Figures(8)

We report on the synthesis of two acentric and one centrosymmetric Zn metal-organic complexes with 3-tetrazolemethyl pyridine spacers obtained in situ by hydrothermal routes. X-ray diffraction structural analysis reveals that they have the same equivalent nodes but with dissimilar topologies. The two acentric frameworks[Zn(Tzmp)Cl]_n (1) and ([Zn(Tzmp)Br]_n (2), HTzmp=3-tetrazolemethyl pyridine) are isomorphism which exhibit an acentric 3D framework with (10, 3)-b net called "ths", while the centrosymmetric complex ([Zn(Tzmp)N₃]_n (3)) features a distinctive 2D sheet with Shubnikov hexagonal plane net. Photo-luminescent studies suggest the ligand-field strength of coordinated negative ions (Cl^- > Br^- > N₃^-) has ordered adjusting effects on the emission redshift. The second harmonic generation (SHG) measurement shows that compounds 1 and 2 are nonlinear optically active, with SHG responses being 2/3 and half of the standard potassium dihydrogen phosphate (KDP), respectively.
- In situ synthesis,
- Tetrazole complexes,
- Zinc complex,
- SHG responses,
- Luminescence properties
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