Citation: He Mengnan, Zhao Yan, Liu Yunqi, Wei Dacheng. A 3D printable self-healing composite conductive polymer for sensitive temperature detection[J]. Chinese Chemical Letters, ;2020, 31(3): 826-830. doi: 10.1016/j.cclet.2019.06.003 shu

A 3D printable self-healing composite conductive polymer for sensitive temperature detection

State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200433, China

weidc@fudan.edu.cn

Received Date: 24 March 2019
Revised Date: 16 April 2019
Accepted Date: 3 June 2019
Available Online: 3 June 2019

Figures(4)

Recent development of self-healing material has attracted tremendous attention, owing to its biomimetic ability to restore structure and functionality when encountering damages. Here, we develop a threedimensional (3D) printable self-healing composite conductive polymer by mixing hydrogen-bond-based supramolecular polymer with low-cost carbon black. It has a room-temperature self-healing capability in both conductivity and mechanical property, while its shear-thinning behavior enables fabrication of a self-healable circuit by 3D printing technology. As an application, the circuit shows an excellent temperature-dependent behavior of the resistance, indicating its great potential for practical application in the artificial intelligence field.
- Composite conductive polymer,
- Self-healing,
- 3D printing,
- Temperature detection,
- Electronic device
1. [1]
  M. Nadgorny, A. Ameli, ACS Appl. Mater. Interfaces 10(2018) 17489-17507. doi: 10.1021/acsami.8b01786
2. [2]
  X. Kuang, K. Chen, C.K. Dunn, et al., Appl. Mater. Interfaces 10(2018) 7381-7388. doi: 10.1021/acsami.7b18265
3. [3]
  J.T. Muth, D.M. Vogt, R.L. Truby, et al., Adv. Mater. 26(2014) 6307-6312. doi: 10.1002/adma.201400334
4. [4]
  Y. Guo, Z. Ji, Y. Zhang, X. Wang, F. Zhou, J. Mater. Chem. A 10(2017) 1039. doi: 10.1039/C7TA01952A
5. [5]
  N.C. Raut, K.A. Shamery, J. Mater. Chem. C 6(2018) 1618-1641. doi: 10.1039/C7TC04804A
6. [6]
  T. Wu, E. Graya, B. Chen, J. Mater. Chem. C 6(2018) 6200-6207. doi: 10.1039/C8TC01092G
7. [7]
  W. Wu, Nanoscale 9(2017) 7342. doi: 10.1039/C7NR01604B
8. [8]
  S. Khan, L. Lorenzelli, Smart Mater. Struct. 26(2017) 083001. doi: 10.1088/1361-665X/aa7373
9. [9]
  D. Li, W.Y. Lai, Y.Z. Zhang, W. Huang, Adv. Mater. 30(2018) 1704738. doi: 10.1002/adma.201704738
10. [10]
  J. Stringer, T.M. Althagathi, C.C.W. Tse, et al., Manufacturing Rev. 3(2016) 12. doi: 10.1051/mfreview/2016011
11. [11]
  A. Salim, S. Lim, Sensors 17(2017) 2593. doi: 10.3390/s17112593
12. [12]
  S.J. Leigh, R.J. Bradley, C.P. Purssell, D.R. Billson, D.A. Hutchins, PLoS One 7(2012) 365-370. doi: 10.1371/journal.pone.0049365
13. [13]
  D. Zhang, B. Chi, B. Lia, et al., Synth. Met. 217(2016) 79-86. doi: 10.1016/j.synthmet.2016.03.014
14. [14]
  P.Cordier, F.Tournilhac, C.Soulie-Ziakovic, L.Leibler, Nature 451(2008)977-980. doi: 10.1038/nature06669
15. [15]
  K. Heymann, J. Lehmann, D. Solomon, M. Schmidt, T. Regier, Org. Geochem. 42(2011) 1055-1064. doi: 10.1016/j.orggeochem.2011.06.021
16. [16]
  S.H. Foulger, J. Appl. Polym. Sci. 72(1999) 1573-1582. doi: 10.1002/(SICI)1097-4628(19990620)72:12<1573::AID-APP10>3.0.CO;2-6
17. [17]
  B.C. Tee, C. Wang, R. Allen, Z. Bao, Nat. Nanotechnol. 7(2012) 825-832. doi: 10.1038/nnano.2012.192
18. [18]
  W. Huang, Y. Wang, Y. Chen, et al., Adv. Healthcare Mater. 5(2016) 2813-2822. doi: 10.1002/adhm.201600720
19. [19]
  M. Nadgorny, Z. Xiao, L.A. Connal, Mol. Syst. Des. Eng. 2(2017) 283-292. doi: 10.1039/C7ME00023E
20. [20]
  H. Yang, D. Qi, Z. Liu, et al., Adv. Mater. 28(2016) 9175-9181. doi: 10.1002/adma.201602994
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沈阳化工大学材料科学与工程学院沈阳 110142