Citation: Wang Tong, Guo Xiaotian, Duan Huiyu, Chen Changyun, Pang Huan. SiO_x-based (0 < x ≤ 2) composites for lithium-ion batteries[J]. Chinese Chemical Letters, ;2020, 31(3): 654-666. doi: 10.1016/j.cclet.2019.06.002 shu

SiO_x-based (0 < x ≤ 2) composites for lithium-ion batteries

Wang Tong ^a,1 ,
Guo Xiaotian ^b,1 ,
Duan Huiyu ^a ,
Chen Changyun ^a,*, ,
Pang Huan ^b

a.
College of Environmental Science, Nanjing Xiaozhuang University, Nanjing 211171, China
b.
School of Chemistry and Chemical Engineering, Guangling College, Yangzhou University, Yangzhou 225009, China

Author Bio:

Huan Pang received his PhD degree from Nanjing University in 2011. He now is a university distinguished professor in Yangzhou University and the managing editor of EnergyChem, Elsevier. In the past 10 years, his group has been engaged in the design and synthesis of functional nanomaterials, especially for MOF-based materials. He has published more than 200 papers in peer-reviewing journals including Chem. Soc. Rev., Adv. Mater., Energy Environ. Sci., with 7400 citations (Hindex = 52). His research interests include the development of inorganic nanostructures and their applications in nanoelectrochemistry with a focus on energy devices

cychen@njxzc.edu.cn

Received Date: 18 May 2019
Revised Date: 20 May 2019
Accepted Date: 20 May 2019
Available Online: 8 June 2019

Figures(7)

Silicon (Si) materials as anode materials for applications in lithium-ion batteries (LIBs) have received increasing attention. Among the Si materials, the electrochemical properties of SiO_x-based (0 < x ≤ 2) composites are the most prominent. However, due to the cycling stability of SiO_x being far from practical, there are some problems, such as low initial coulombic efficiency (ICE), obvious volume expansion and poor conductivity. Researchers in various countries have optimized the electrochemical properties of SiO_x-based composites by means of pore formation, surface modification, and the choice of constituents. In this review, SiO_x-based composites are classified into three categories based on the valency of Si (SiO₂ composites, SiO composites and SiO_x (0 < x < 2) composites). The synthesis, morphologies and electrochemical properties of the SiO_x-based composites that are applied in LIB are discussed. Finally, the properties of several common SiO_x-based composites are briefly compared and the challenges faced by SiO_x-based composites are highlight.
- Lithium-ion battery,
- Anode material,
- SiO₂ composites,
- SiO composites,
- SiO_x-based (0 < x ≤ 2) composite
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

SiOx-based (0 < x ≤ 2) composites for lithium-ion batteries

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通讯作者: 陈斌, bchen63@163.com

SiO_x-based (0 < x ≤ 2) composites for lithium-ion batteries