Citation: Lin Xiao, Ning Erlong, Li Xiaomin, Li Qiaowei. Construction of mixed carboxylate and pyrogallate building units for luminescent metal-organic frameworks[J]. Chinese Chemical Letters, ;2020, 31(3): 813-817. doi: 10.1016/j.cclet.2019.05.055 shu

Construction of mixed carboxylate and pyrogallate building units for luminescent metal-organic frameworks

Department of Chemistry, iChEM(Collaborative Innovation Center of Chemistry for Energy Materials), Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China

qwli@fudan.edu.cn

Received Date: 29 March 2019
Revised Date: 9 May 2019
Accepted Date: 28 May 2019
Available Online: 29 May 2019

Figures(3)

A metal-organic framework, Ce-FDM-50, was constructed by employing gallic acid featuring both carboxylate and pyrogallate as the coordinating sites and Ce(Ⅲ). The co-assembly of the carboxylates and pyrogallates with two metal ions have achieved a new type of paddle wheel secondary building unit. These building units were further joined by organic struts to obtain frameworks in sql topology. This synthetic approach could be expanded to five different lanthanide metals (Nd, Eu, Gd, Tb, Yb) for the construction of a series of isoreticular MOFs based on FDM-50, and even MTV-MOFs in which mixed lanthanide metals with specific ratios were distributed. In addition, featuring the lanthanide metals as the inorganic nodes in the network, Tb-FDM-50 showed distinct luminescence properties that could be furtherly tuned for variable applications.
- Metal-organic framework,
- Secondary building units,
- Gallic acid,
- Bimetallic,
- Luminescence
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