Citation: Wada Kenji, Yu Han, Feng Qi. Titania-supported iridium catalysts for dehydrogenative synthesis of benzimidazoles[J]. Chinese Chemical Letters, ;2020, 31(3): 605-608. doi: 10.1016/j.cclet.2019.05.054 shu

Titania-supported iridium catalysts for dehydrogenative synthesis of benzimidazoles

Wada Kenji ^a,*, ,
Yu Han ^b ,
Feng Qi ^b

a.
Department of Chemistry for Medicine, Kagawa University, Miki-Cho, Kita-Gun, Kagawa 761-0793, Japan
b.
Department of Advanced Materials Science, Kagawa University, Takamatsu, Kagawa 761-0396, Japan

wadaken@med.kagawa-u.ac.jp

Received Date: 30 March 2019
Revised Date: 18 May 2019
Accepted Date: 20 May 2019
Available Online: 18 May 2019

Figures(5)

In this review, development of supported catalysts for the dehydrogenative synthesis of benzimidazoles from primary alcohols and 1, 2-phenylenediamine derivatives is briefly summarized. Among them, titania-supported iridium catalysts showed excellent activities under mild reaction conditions. Remarkably, the low-temperature activity of iridium catalyst was significantly affected by titania supports, and the reaction of 1, 2-phenylenediamine and benzyl alcohol in the presence of rutilesupported catalysts proceeded smoothly at 100 ℃ to give 2-phenylbenzimidazole in high yields of up to 88%. On the other hand, catalysts supported on anatase generally showed poor activity at 100 ℃. A significant relationship between CO uptake and the activity of titania-supported catalysts has been reported, indicating that well-reduced iridium species on rutile would be responsible for the predominant catalytic activity. The present results suggest the importance of the selection of suitable titania supports for the iridium catalysts.
- Benzimidazole,
- Iridium,
- Titania,
- Heterogeneous catalysts,
- Dehydrogenation
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