Citation: Jiang Fangling, Peng Hao, Li Cheng, Fu Haiying, Wu Guozhong. Temperature-dependent structural changes of[Bmim]FeCl₄ magnetic ionic liquid characterized by an in-situ X-ray absorption fine structure[J]. Chinese Chemical Letters, ;2020, 31(3): 801-804. doi: 10.1016/j.cclet.2019.05.028 shu

Temperature-dependent structural changes of[Bmim]FeCl₄ magnetic ionic liquid characterized by an in-situ X-ray absorption fine structure

Jiang Fangling ^a,*, ,
Peng Hao ^b ,
Li Cheng ^b ,
Fu Haiying ^b ,
Wu Guozhong ^b,*,

a.
Shanghai Jiao Tong University, Institute of Fuel Cells, Shanghai 200240, China
b.
Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China

jiangfangling33@163.com

wuguozhong@sinap.ac.cn

Received Date: 26 April 2019
Revised Date: 13 May 2019
Accepted Date: 16 May 2019
Available Online: 16 May 2019

Figures(2)

The temperature-dependent structural changes in 1-butyl-3-methylimidazolium tetrafluoride ([Bmim]FeCl₄) magnetic ionic liquid (MIL) were investigated by using in-situ X-ray absorption fine structure (XAFS) combined with Raman spectroscopy and DFTcalculations. XAFS results revealed that the coordination number and bond length of Fe-Cl in the anion of[Bmim]FeCl₄ MIL decreased with increments in temperature. These results directly reflected the dissociation of tetrahedral structure[FeCl₄]^-, and the formation of bridge-chain[Fe₂Cl₅]⁺, and[FeCl₂]⁺ species in the anion of[Bmim]FeCl₄ MIL. These behaviors indicated that[FeCl₄]^- dissociation was endothermic, and was promoted by increased temperature. The results obtained through XAFS were in agreement with those obtained through Raman spectroscopy and DFT calculations.
- Magnetic ionic liquids,
- Temperature-dependent,
- Structure,
- Change,
- XAFS
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沈阳化工大学材料科学与工程学院沈阳 110142

Temperature-dependent structural changes of[Bmim]FeCl4 magnetic ionic liquid characterized by an in-situ X-ray absorption fine structure

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通讯作者: 陈斌, bchen63@163.com

Temperature-dependent structural changes of[Bmim]FeCl₄ magnetic ionic liquid characterized by an in-situ X-ray absorption fine structure