Citation: Zhang Xiaolong, Han Yifei, Liu Guangyao, Wang Feng. Macrocyclic versus acyclic preorganization in organoplatinum(Ⅱ)-based host-guest complexes[J]. Chinese Chemical Letters, ;2019, 30(11): 1927-1930. doi: 10.1016/j.cclet.2019.05.007 shu

Macrocyclic versus acyclic preorganization in organoplatinum(Ⅱ)-based host-guest complexes

CAS Key Laboratory of Soft Matter Chemistry, iChEM(Collaborative Innovation Center of Chemistry for Energy Materials), Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China

drfwang@ustc.edu.cn

Received Date: 2 April 2019
Revised Date: 17 April 2019
Accepted Date: 18 April 2019
Available Online: 7 November 2019

Figures(5)

Two host-guest systems have been constructed, by employing structurally similar terpyridine platinum (Ⅱ) macrocycle and molecular tweezer as the synthetic receptors. The macrocycle/guest complex displays low-energy emission signal, reinforced non-covalent binding affinity, and enhanced photosensitization capability than those of the molecular tweezer/guest one. The discrepancy between macrocyclic and acyclic preorganization modes originates from the different numbers of Pt(Ⅱ)…Pt(Ⅱ) metal-metal bonds in host-guest complexation structures.
- Supramolecular chemistry,
- Preorganization,
- Host-guest recognition,
- Metal-metal interactions,
- Photosensitization
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