Citation: Zhao Tao, Ren Yuan, Jia Guangyou, Zhao Yuye, Fan Yuchi, Yang Jianping, Zhang Xin, Jiang Wan, Wang Lianjun, Luo Wei. Facile synthesis of mesoporous WO₃@graphene aerogel nanocomposites for low-temperature acetone sensing[J]. Chinese Chemical Letters, ;2019, 30(12): 2032-2038. doi: 10.1016/j.cclet.2019.05.006 shu

Facile synthesis of mesoporous WO₃@graphene aerogel nanocomposites for low-temperature acetone sensing

Zhao Tao ^a ,
Ren Yuan ^b ,
Jia Guangyou ^a ,
Zhao Yuye ^a ,
Fan Yuchi ^c ,
Yang Jianping ^a ,
Zhang Xin ^a ,
Jiang Wan ^a,c,d ,
Wang Lianjun ^a,*, ,
Luo Wei ^a,c,*,

a.
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
b.
Department of Chemistry, State Key Laboratory of Molecular Engineering of Polymers, iChEM, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China
c.
Institute of Functional Materials, Donghua University, Shanghai 201620, China
d.
School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333001, China

wanglj@dhu.edu.cn

wluo@dhu.edu.cn

Received Date: 12 April 2019
Revised Date: 30 April 2019
Accepted Date: 6 May 2019
Available Online: 6 December 2019

Figures(5)

Nanocomposites constructed by combining mesoporous metal oxides and graphene have received tremendous attention in wide fields of catalysis, energy storage and conversion, gas sensing and so on. Herein, we present a facile interface-induced co-assembly process to synthesize the mesoporous WO₃@graphene aerogel nanocomposites (denoted as mWO₃@GA), in which graphene aerogel (GA) was used as a macroporous substrate, mesoporous WO₃ was uniformly coated on both sides of graphene sheets through a solvent evaporation-induced self-assembly (EISA) strategy using diblock copolymer poly(ethylene oxide)-b-polystyrene (PEO-b-PS) as a template. The resultant mWO₃@GA nanocomposites possess well-interconnected macroporous graphene networks covered by mesoporous WO₃ layer with a uniform pore size of 19 nm, high surface area of 167 m²/g and large pore volume of 0.26 cm³/g. The gas sensing performance of mWO₃@GA nanocomposites toward acetone and other gases was studied, showing a high selectivity and great response to acetone at low temperature of 150℃, which could be developed as a promising candidate as novel sensors for VOCs detection.
- Mesoporous materials,
- Tungsten oxide,
- Graphene,
- Gas sensing,
- Acetone
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Facile synthesis of mesoporous WO3@graphene aerogel nanocomposites for low-temperature acetone sensing

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通讯作者: 陈斌, bchen63@163.com

Facile synthesis of mesoporous WO₃@graphene aerogel nanocomposites for low-temperature acetone sensing