Citation: Lu Ling-Hui, Wang Zheng, Xia Weng, Cheng Ping, Zhang Bo, Cao Zhong, He Wei-Min. Sustainable routes for quantitative green selenocyanation of activated alkynes[J]. Chinese Chemical Letters, ;2019, 30(6): 1237-1240. doi: 10.1016/j.cclet.2019.04.033 shu

Sustainable routes for quantitative green selenocyanation of activated alkynes

Lu Ling-Hui ^a,b ,
Wang Zheng ^b ,
Xia Weng ^c ,
Cheng Ping ^c ,
Zhang Bo ^d ,
Cao Zhong ^d ,
He Wei-Min ^a,b,*,

a.
Department of Chemistry, Hunan University, Changsha 410082, China
b.
Department of Chemistry, Hunan University of Science and Engineering, Yongzhou 425100, China
c.
School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China
d.
Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha 410114, China

E-mail address:

weiminhe2016@yeah.net

Received Date: 17 March 2019
Revised Date: 2 April 2019
Accepted Date: 15 April 2019
Available Online: 16 June 2019

Figures(4)

Most organic reactions require the usage of volatile organic compounds in the synthesis, work-up and purification processes, thus resulting in major environmental pollution and high manufacturing cost. By using cheap biomass lactic acid as the reaction media and catalyst, a sustainable protocol for the synthesis of Z-3-selenocyanatoacrylates and analogues through green selenocyanation of activated alkynes has been achieved. A principal advantage of this protocol is that the usage of organic volatile compounds can be avoided entirely, as the conversion of substrate is almost quantitative or quantitative with a minimal amount of lactic acid employed as reaction media, and the pure products can be conveniently collected through water precipitation.
- Green chemistry,
- Organic volatile compounds,
- Biomass,
- Alkynes,
- Potassium selenocyanate
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