Citation: Wu Rui-Juan, Liu Meng, Peng Ye-Wang, Yao Shuang, Guo Xiang-Wei, Geng Ai-Fang, Zhang Zhi-Ming. MOF/CC-derivatives with trace amount of cobalt oxides as efficient electrocatalysts for oxygen reduction reaction[J]. Chinese Chemical Letters, ;2019, 30(5): 989-994. doi: 10.1016/j.cclet.2019.02.021 shu

MOF/CC-derivatives with trace amount of cobalt oxides as efficient electrocatalysts for oxygen reduction reaction

Wu Rui-Juan ^a,b ,
Liu Meng ^c ,
Peng Ye-Wang ^a,b ,
Yao Shuang ^a,b,**, ,
Guo Xiang-Wei ^c ,
Geng Ai-Fang ^a,*, ,
Zhang Zhi-Ming ^c,*,

a.
School of Chemicala nd Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, China
b.
School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, China
c.
Institute for New Energy Materials and Low Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China

^**

E-mail addresses:

Received Date: 26 December 2018
Revised Date: 28 January 2019
Accepted Date: 22 February 2019
Available Online: 22 May 2019

Figures(4)

The development of high-efficiency, earth-abundant, and durable oxygen reduction reaction (ORR) electrocatalysts is desirable for commercialization of fuel cells, but remains a great challenge. Herein, we develop a facile and practical method for preparing efficient ORR electrocatalysts by directly growing metal-organic frameworks (MOFs) Co₂(INA)₄·DMF (HINA=isonicotinic acid, 1) and {[Co₂(TPI) (H₂O)₂(OH)]·DMF} (H₃TPI=5-(4-(tetrazol-5-yl) phenyl) isophthalic acid, 2) on the commercial carbon (CC). The resulting MOF/CCs were further pyrolysis to functionalize CC by trace amount of cobalt oxides, resulting in two composites Cal-MOF-1/CC (3) and Cal-MOF-2/CC (4), which can be used as efficient electrocatalysts for ORR with remarkable stability and large diffusion-limited current density, even superior to that of commercial Pt/C catalysts. Detail study reveals that the linking ligands with different structure and nitrogen contents in 1 and 2 smartly influence the types of cobalt oxides. The catalytic activity of Co₃O₄/CoO/Co co-doped CC in 4 was much enhanced compared to that of CoO-doped CC in 3.
- Metal-organic framework,
- Cobalt oxide,
- Oxygen reduction reaction,
- Commercial carbon,
- Electrocatalyst
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