Citation: Jiang Xindong, Zhang Tingjiang, Sun Changliang, Meng Yanqiu, Xiao Linjiu. Synthesis of aza-BODIPY dyes bearing the naphthyl groups at 1, 7-positions and application for singlet oxygen generation[J]. Chinese Chemical Letters, ;2019, 30(5): 1055-1058. doi: 10.1016/j.cclet.2019.02.016 shu

Synthesis of aza-BODIPY dyes bearing the naphthyl groups at 1, 7-positions and application for singlet oxygen generation

a.
College of Applied Chemistry, Key Laboratory of Rare-earth Chemistry and Applying of Liaoning Province, Shenyang University of Chemical Technology, Shenyang 110142, China
b.
Department of Chemistry, Graduate School of Science, Hiroshima University, Higashi-Hiroshima 739-8526, Japan
c.
Center of Physical and Chemistry Test, Shenyang University of Chemical Technology, Shenyang 110142, China
d.
College of Pharmaceutical and Biological Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China

Received Date: 17 October 2018
Revised Date: 18 February 2019
Accepted Date: 20 February 2019
Available Online: 21 May 2019

Figures(7)

Using 2-vinylnaphthalene, aza-BODIPYs with the naphthyl groups at 1, 7-positions were prepared and their photophysical properties were characterized. Due to attachment of the naphthyl groups at 1, 7-positions, aza-BODIPYs show long-wavelength absorption and emission in the near-infrared region. The singlet oxygen generation of the dibromo substituted aza-BODIPY with the naphthyl groups at 1, 7-positions as a photosensitizer was more effective than that of the corresponding aza-BODIPY with the phenyl groups at 1, 7-positions. No photobleaching of the naphthyl-containing aza-BODIPY was observed and such NIR aza-BODIPY could be used for the singlet oxygen generation.
- Aza-BODIPY,
- NIR,
- Fluorescent dye,
- Naphthyl group,
- PS
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1.
沈阳化工大学材料科学与工程学院沈阳 110142