Citation: Dong Guo-Liang, Fang Wei-Hui, Zhang Lei, Zhang Jian. In situ generated pyroglutamate bridged polyoxotitaniums with strong circular dichroism signal[J]. Chinese Chemical Letters, ;2019, 30(5): 1005-1008. doi: 10.1016/j.cclet.2019.01.032 shu

In situ generated pyroglutamate bridged polyoxotitaniums with strong circular dichroism signal

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

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Received Date: 14 January 2019
Revised Date: 28 January 2019
Accepted Date: 29 January 2019
Available Online: 30 May 2019

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In this text, we use inexpensive and natural amino acid, successfully obtained the asymmetric crystallization of three PTCs, [Ti₆(OⁱPr)₁₄(μ₂-O)(μ₃-O)₂(D/L-pGlu)₂] (D-PTC-53; L-PTC-53; H₂pGlu=pyroglutamic acid) and [Ti₆(OⁱPr)₁₄(μ₂-O)(μ₃-O)₂(D-pGlu)₂][Ti₆(OⁱPr)₁₄(μ₂-O)(μ₃-O)₂(L-pGlu)₂] (D, L-PTC-53). Interestingly, in situ lactamide reaction starting from glutamic acid to pyroglutamic acid was observed. In addition, the chirality features of these PTCs have been thoroughly discussed. The two enantiomers crystallize in chiral P2₁ space group. The optically pure pGlu ligands transform its chirality to the inorganic titanium oxo clusters. As a result, the stack of these inorganic clusters generates homochiral helical chains along the characteristic axial direction. Apart from the microscopic structural analysis, the macroscopic solid-state samples exhibit unusual strong circular dichroism (CD) signals, further verified the homochiral feature of the enantiomers.
- In situ,
- Gyroglutamate,
- Polyoxotitaniums,
- Circular dichroism,
- Chirality
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