Citation: Bian Hang, Zhang Xuejian, Zhao Hongkai, Zhang Ning. Controlled synthesis of silver nanoparticles from polyoxometalates-immobilized poly(4-vinylpyridine) brushes[J]. Chinese Chemical Letters, ;2019, 30(5): 1097-1099. doi: 10.1016/j.cclet.2019.01.030 shu

Controlled synthesis of silver nanoparticles from polyoxometalates-immobilized poly(4-vinylpyridine) brushes

a.
School of Material Science and Engineering, Jilin Jianzhu University, Changchun 130118, China
b.
Department of Chemistry, Northeast Normal University, Changchun 130024, China

zhangn380@nenu.edu.cn

Received Date: 10 January 2019
Revised Date: 24 January 2019
Accepted Date: 28 January 2019
Available Online: 30 May 2019

Figures(6)

This contribution reports the immobilization of polyoxometalate (POM) into poly(4-vinyl pyridine) (P4VP) brushes and the controlled reduction of silver ions, in-situ generating metal nanoparticles in the brushes. P4VP brushes were straightforwardly created by UV-assisted photopolymerization of 4-vinyl pyridine (4VP) on silicon or glass substrates. Phosphotungstic acid (H₃PW₁₂O₄₀), one of the most widely used Keggin-type POM was anchored onto these pyridine moieties through electrostatic interaction, leading to the P4VP/POM hybrid brushes. The immobilized POM was further reduced to heteropolyblue, which could be used to generate silver nanoparticles in a controlled fashion. AFM, UV-vis and IR characterization indicate that P4VP brushes not only provide an efficient platform in the controlled preparation of Ag nanoparticles, but also efficiently disperse and stabilize POM, thus preventing the aggregation of the generated Ag nanoparticles.
- Polymer brushes,
- Polyoxometalate,
- Ag nanoparticles,
- Grafting polymerization
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1.
沈阳化工大学材料科学与工程学院沈阳 110142