Citation: Su Xiaodan, Tao Jun, Chen Sui, Xu Peng, Wang Dan, Teng Zhaogang. Uniform hierarchical silica film with perpendicular macroporous channels and accessible ordered mesopores for biomolecule separation[J]. Chinese Chemical Letters, ;2019, 30(5): 1089-1092. doi: 10.1016/j.cclet.2019.01.022 shu

Uniform hierarchical silica film with perpendicular macroporous channels and accessible ordered mesopores for biomolecule separation

Su Xiaodan ^a ,
Tao Jun ^a ,
Chen Sui ^b ,
Xu Peng ^c ,
Wang Dan ^d ,
Teng Zhaogang ^a,b,*,

a.
Key Laboratory for Organic Electronics & Information Displays and Institute of Advanced Materials, Nanjing University of Posts and Telecommunications, Nanjing 210046, China
b.
Department of Medical Imaging, Jinling Hospital, School of Medicine, Nanjing University, Nanjing 210002, China
c.
College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China
d.
Department of Gynecology & Obstetrics, Affiliated Changzheng Hospital, The Second Military Medical University, Shanghai 200003, China

tzg@fudan.edu.cn

Received Date: 16 December 2018
Revised Date: 16 January 2019
Accepted Date: 16 January 2019
Available Online: 23 May 2019

Figures(7)

Herein, we demonstrate that silica films with perpendicular macroporous channels and accessible ordered mesopores can be conveniently prepared. The hierarchical macroporous-mesoporous silica films are synthesized by using zinc oxide nanorod array as macroporous template and CTAB surfactant as mesoporous template. In basic surfactant-containing solution, ordered mesoporous silica shells homogeneously grow on the zinc oxide nanorod array. The growth of the mesostructures do not require any chemical modification for the zinc oxide nanorod, which opens a new way for preparing hierarchical silica films with perpendicular mesochannels. The prepared hierarchical macroporous- mesoporous silica films possess a uniform thickness of 2 μm, large perpendicular macropores with a length of 1.8 μm and a width of 80 nm, and accessible ordered mesopores. Separation experiment demonstrates that this macroporous-mesoporous film can effectively separate biomolecules with different sizes.
- Silica,
- Film,
- Macroporous,
- Mesoporous,
- Separation
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