Citation: He Mengnan, Chen Xiaosong, Liu Donghua, Wei Dacheng. Two-dimensional self-healing hydrogen-bond-based supramolecular polymer film[J]. Chinese Chemical Letters, ;2019, 30(5): 961-965. doi: 10.1016/j.cclet.2019.01.008 shu

Two-dimensional self-healing hydrogen-bond-based supramolecular polymer film

State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200433, China

weidc@fudan.edu.cn

Received Date: 4 December 2018
Revised Date: 7 January 2019
Accepted Date: 9 January 2019
Available Online: 9 May 2019

Figures(4)

Self-healing materials have been developed over the past decade with the recovery ability after damage. However, most researches focused on the self-healing process at three-dimension. Herein, we prepare monolayer self-healing hydrogen-bond-based supramolecular polymer film and explore the self-healing process at the two-dimensional limit. The healing process, which can be reversibly repeated for at least three times, is influenced by the temperature, the molecule-substrate interaction and the substrate roughness. In the application, the monolayer self-healing polymer film can be used to modify the SiO₂ dielectric for copper phthalocyanine field effect transistor with improved mobility. This work will be valuable for developing two-dimensional functional self-healing materials in the future.
- Supramolecular polymer,
- Self-healing,
- Monolayer film,
- Self-assembly,
- Organic field effect transistor
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