Citation: Lin Chen, Liu Yitao, Xie Xuming. GO/PVA nanocomposites with significantly enhanced mechanical properties through metalion coordination[J]. Chinese Chemical Letters, ;2019, 30(5): 1100-1104. doi: 10.1016/j.cclet.2018.11.027 shu

GO/PVA nanocomposites with significantly enhanced mechanical properties through metalion coordination

Key Laboratory of Advanced Materials (MOE), Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

xxm-dce@mail.tsinghua.edu.cn

Received Date: 10 October 2018
Revised Date: 18 November 2018
Accepted Date: 22 November 2018
Available Online: 22 May 2018

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In this study, a simple and efficient way is demonstrated to create strong interfacial interaction between graphene oxide (GO) filler and poly(vinyl alcohol) (PVA) matrix through metal ion coordination. The coordination bonding provides efficient load transfer during the tensile process, and enhances the mechanical properties of the nanocomposites significantly. After being coordinated with Cu(Ⅱ) ions, GO/ PVA composites show much higher Young's moduli and yield stresses than pure PVA and noncoordinated GO/PVA. UV-vis and FTIR spectra are performed to confirm the successful coordination between GO and PVA. Ethylene diamine tetraacetic acid disodium salt (EDTA-2Na) is used to confirm the important role of coordination in enhancing the composites. This research provides a new approach to manufacture polymer-matrix nanocomposites with significantly improved mechanical performances.
- Graphene oxide,
- PVA,
- Coordination,
- Composite,
- Mechanical property
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