Citation: Rong Xiaohui, Gao Fei, Lu Yaxiang, Yang Kai, Hu Yongsheng. P2-type Na_0.6[Mg(Ⅱ)_0.3Mn(Ⅳ)_0.7]O₂ as a new model material for anionic redox reaction[J]. Chinese Chemical Letters, ;2018, 29(12): 1791-1794. doi: 10.1016/j.cclet.2018.11.023 shu

P2-type Na_0.6[Mg(Ⅱ)_0.3Mn(Ⅳ)_0.7]O₂ as a new model material for anionic redox reaction

Rong Xiaohui ^a,b,1 ,
Gao Fei ^a,1 ,
Lu Yaxiang ^b,*, ,
Yang Kai ^a ,
Hu Yongsheng ^b

a.
State Key Laboratory of Operation and Control of Renewable Energy and Storage Systems, China Electric Power Research Institute, Beijing 100192, China
b.
Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100190, China

yxlu@iphy.ac.cn

Received Date: 19 September 2018
Revised Date: 5 November 2018
Accepted Date: 16 November 2018
Available Online: 20 December 2018

Figures(4)

A new model material of Na_0.6[Mg(Ⅱ)_0.3Mn(Ⅳ)_0.7]O₂, with only Mg²⁺ and Mn⁴⁺ in the transition metal layers, is synthesized for the research of anionic redox reaction. The material delivers a capacity of~130 mAh/g with a long plateau at~4.2 V in the initial charge profile, indicating anionic redox reaction (ARR) involved during the initial desodiation process. In the following cycles, the reversible capacity can reach a high value of~210 mAh/g, which is probably derived from the participation of both ARR and Mn³⁺/Mn⁴⁺ redox couples, further proving the charge compensation from ARR during the initial charge and following cycles. The designed cathode material without Mn³⁺ helps avoid the influence of oxygen activity from transition metals, enabling the investigation of ARR without other distractions.
- Na-ion batteries,
- Layered oxide,
- Cathode,
- Anionic redox reaction,
- Na_0.6[Mg_0.3Mn_0.7]O₂
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

P2-type Na0.6[Mg(Ⅱ)0.3Mn(Ⅳ)0.7]O2 as a new model material for anionic redox reaction

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通讯作者: 陈斌, bchen63@163.com

P2-type Na_0.6[Mg(Ⅱ)_0.3Mn(Ⅳ)_0.7]O₂ as a new model material for anionic redox reaction