Citation: Zhang Ding, Sha Min, Pan Renming, Lin Xiangyang, Xing Ping, Jiang Biao. Design and synthesis of the novel branched fluorinated surfactant intermediates with CF₃CF₂CF₂C(CF₃)₂ group[J]. Chinese Chemical Letters, ;2019, 30(3): 566-568. doi: 10.1016/j.cclet.2018.11.014 shu

Design and synthesis of the novel branched fluorinated surfactant intermediates with CF₃CF₂CF₂C(CF₃)₂ group

Zhang Ding ^a,b ,
Sha Min ^c ,
Pan Renming ^a ,
Lin Xiangyang ^a,*, ,
Xing Ping ^b,*, ,
Jiang Biao ^a,b,*,

a.
School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
b.
CAS Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
c.
School of Management Science & Engineering, Nanjing University of Finance & Economics, Nanjing 210046, China

linxiangyang@njust.edu.cn

xingping@mail.sioc.ac.cn

jiangb@mail.sioc.ac.cn

Received Date: 16 September 2018
Revised Date: 5 November 2018
Accepted Date: 13 November 2018
Available Online: 14 March 2018

Figures(3)

Perfluorooctanoic acid (PFOA) or perfluorooctane sulphonate (PFOS) was one of the most prominent fluorosurfactants and applied widely in firefighting and daily chemical, etc. However, these surfactants have recently been identified as toxic and undegradability in the environment. Developing an efficient approach to environment-friendly fluorosurfactants is essential. A fluorocarbon branched chain strategy was adopted to develop /PFOS substitutes. A series of intermediates of novel branched fluorinated surfactants with CF₃CF₂CF₂C(CF₃)₂ group were synthesized from perfluoro-2-methyl-2-pentene. All the steps were mild, easy-handled and cheap. It is expected to be a very significant direction for the development of non-bioaccumulable alternatives of PFOA or PFOS.
- Perfluoro-2-methyl-2-pentene,
- Branched fluorinated surfactants,
- Oxy fluorocarbon chain
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Design and synthesis of the novel branched fluorinated surfactant intermediates with CF₃CF₂CF₂C(CF₃)₂ group