Citation: Chen Qiang, Mao Yuqin, Bing Naici, Zou Yongjin, Zhu Luping. Preparation and optical properties of three-dimensional navel-like Bi₂WO₆ hierarchical microspheres[J]. Chinese Chemical Letters, ;2019, 30(3): 783-786. doi: 10.1016/j.cclet.2018.10.036 shu

Preparation and optical properties of three-dimensional navel-like Bi₂WO₆ hierarchical microspheres

Chen Qiang ^a ,
Mao Yuqin ^a ,
Bing Naici ^a,**, ,
Zou Yongjin ^b ,
Zhu Luping ^a,c,*,

a.
School of Environmental and Materials Engineering, Research Center of Resource Recycling Science and Engineering, Shanghai Polytechnic University (SSPU), Shanghai 201209, China
b.
Guangxi Key Laboratory of Information Materials, Guilin University of Electronic Technology (GUET), Guilin 541004, China
c.
Shanghai Innovation Institute for Materials, Shanghai 200444, China

^**

ncbing@sspu.edu.cn

lpzhu@sspu.edu.cn

Received Date: 14 August 2018
Revised Date: 27 October 2018
Accepted Date: 30 October 2018
Available Online: 2 March 2018

Figures(3)

Three-dimensional (3D) navel-like Bi₂WO₆ (BWO) hierarchical microspheres (HMSs) were successfully prepared using a simple hydrothermal method. The as-obtained BWO samples were characterized by a variety of techniques. XRD result indicated that the as-synthesized samples were well-crystallized orthorhombic phase Bi₂WO₆ structure. SEM observations revealed that the hierarchical microspheres with an average diameter of 2 μm were built from several dozen of nanosheets. UV-vis diffuse reflectance spectrum study revealed that the obtained BWO sample had band gap energy of about 3.3 eV. Photoluminescence (PL) result showed that the sample had weak emission intensity. The BET specific surface area of the BWO sample was about 35.40 m²/g. The photocatalytic efficiency of the as-obtained BWO was evaluated by the degradation of norfloxacin (NOR) antibiotic. The result showed an about 67% NOR degradation in 8 h.
- Semiconductors,
- Bi₂WO₆,
- Crystal growth,
- Microstructure,
- Optical properties
1. [1]
  M.H. Khan, H. Bae, J.Y. Jung, J. Hazard. Mater. 181(2010) 659-665. doi: 10.1016/j.jhazmat.2010.05.063
2. [2]
  Z.Y. Lu, X.X. Zhao, Z. Zhu, et al., Chem.-Eur. J. 21(2015) 18528-18533. doi: 10.1002/chem.201503759
3. [3]
  Y. Junejo, A. Güner, A. Baykal, et al., Appl. Surf. Sci. 317(2014) 914-922. doi: 10.1016/j.apsusc.2014.08.133
4. [4]
  X.L. Guo, D. Li, J. Wan, X. Yu, Electrochim. Acta 180(2015) 957-964. doi: 10.1016/j.electacta.2015.09.055
5. [5]
  C. Cai, H.L. Liu, B. Wang, J. Hazard. Mater. 331(2017) 265-272. doi: 10.1016/j.jhazmat.2017.02.034
6. [6]
  G. Zhang, Z.Y. Hu, M. Sun, et al., Adv. Funct. Mater. 25(2015) 3726-3734. doi: 10.1002/adfm.v25.24
7. [7]
  M. Chen, W. Chu, Appl. Catal. B 168-169(2015) 175-182.
8. [8]
  L. Liang, Y. Tursun, A. Nulahong, et al., Ultrason. Sonochem. 39(2017) 93-100. doi: 10.1016/j.ultsonch.2017.03.054
9. [9]
  R. He, S. Cao, J.G. Yu, Acta Phys. Chim. Sin. 32(2016) 2841-2870.
10. [10]
  A. Kudo, S. Hijii, Chem. Lett. 10(1999) 1103-1104.
11. [11]
  J.W. Tang, Z.G. Zou, J.H. Ye, Catal. Lett. 92(2004) 53-56. doi: 10.1023/B:CATL.0000011086.20412.aa
12. [12]
  A. Feteira, D.C. Sinclair, J. Am. Ceram. Soc. 91(2008) 1338-1341. doi: 10.1111/j.1551-2916.2008.02272.x
13. [13]
  A. Kaur, S.K. Kansal, Chem. Eng. 302(2016) 194-203. doi: 10.1016/j.cej.2016.05.010
14. [14]
  Y. Liang, S. Lin, L. Liu, et al., Appl. Catal. B 164(2015) 192-203. doi: 10.1016/j.apcatb.2014.08.048
15. [15]
  S. Babić, M. Periša, I. Škorić, Chemosphere 91(2013) 1635-1642. doi: 10.1016/j.chemosphere.2012.12.072
16. [16]
  L.P. Zhu, L.L. Wang, N.C. Bing, et al., ACS Appl. Mater. Interfaces 5(2013) 12478-12487. doi: 10.1021/am403720r
17. [17]
  L.P. Zhu, N.C. Bing, L.L. Wang, et al., Dalton Trans. 41(2012) 2959-2965. doi: 10.1039/c2dt11822j
18. [18]
  L.P. Zhu, G.H. Liao, N.C. Bing, et al., CrystEngComm 12(2010) 3791-3796. doi: 10.1039/c0ce00038h
19. [19]
  L.P. Zhu, C. Huang, J.W. Liu, et al., Mater. Lett. 106(2013) 348-351. doi: 10.1016/j.matlet.2013.05.093
20. [20]
  D.V. Bavykin, V.N. Parmon, A.A. Lapkin, et al., J. Mater. Chem.14(2004) 3370-3377. doi: 10.1039/b406378c
21. [21]
  J. Yu, G. Yu, B. Cheng, J. Mol. Catal. A 249(2006) 135-142. doi: 10.1016/j.molcata.2006.01.003
22. [22]
  D. Ma, S.M. Huang, J. Phys. Chem. C 113(2009) 4369-4374. doi: 10.1021/jp810726d
23. [23]
  J. Tang, Z. Zou, J. Ye, Chem. Mater. 16(2004) 1644-1649. doi: 10.1021/cm0353815
24. [24]
  W. Luo, T. Zhao, Y. Li, et al., J. Am. Chem. Soc. 138(2016) 12586-12595. doi: 10.1021/jacs.6b07355
25. [25]
  W. Luo, Y. Li, J. Dong, et al., Angew. Chem. 125(2013) 10699-10704. doi: 10.1002/ange.201303353
26. [26]
  T. Zhao, W. Luo, Y. Deng, et al., Nano Energy 26(2016) 16-25. doi: 10.1016/j.nanoen.2016.04.050
27. [27]
  L.Xiang L. Chen, C.H. Mo, et al., J. Mater. Sci. 53(2018) 7657-7671.
28. [28]
  Y. Zhao, Y. Wang, E. Liu, J. Fan, X. Hu, Appl. Surf. Sci. 436(2018) 854-864. doi: 10.1016/j.apsusc.2017.12.064
29. [29]
  M.A. Butler, J. Appl. Phys. 48(1977) 1914-1918. doi: 10.1063/1.323948
30. [30]
  Q. Zhu, X. Shen, L. Wang, et al., Chin. Chem. Lett. 29(2018) 1310-1312. doi: 10.1016/j.cclet.2017.12.018
1. [1]
  Ruizhi Yang , Xia Li , Weiping Guo , Zixuan Chen , Hongwei Ming , Zhong-Zhen Luo , Zhigang Zou . New thermoelectric semiconductors Pb5Sb12+xBi6-xSe32 with ultralow thermal conductivity. Chinese Journal of Structural Chemistry, 2024, 43(3): 100268-100268. doi: 10.1016/j.cjsc.2024.100268
2. [2]
  Weiping Guo , Ying Zhu , Hong-Hua Cui , Lingyun Li , Yan Yu , Zhong-Zhen Luo , Zhigang Zou . β-Pb₃P₂S₈: A new optical crystal with exceptional birefringence effect. Chinese Chemical Letters, 2025, 36(2): 110256-. doi: 10.1016/j.cclet.2024.110256
3. [3]
  Yuanqing Wang , Yusong Pan , Hongwu Zhu , Yanlei Xiang , Rong Han , Run Huang , Chao Du , Chengling Pan . Enhanced Catalytic Activity of Bi₂WO₆ for Organic Pollutants Degradation under the Synergism between Advanced Oxidative Processes and Visible Light Irradiation. Acta Physico-Chimica Sinica, 2024, 40(4): 2304050-0. doi: 10.3866/PKU.WHXB202304050
4. [4]
  Peng-Fei Li , Chun-Li Hu , Bo Zhang , Jiang-Gao Mao , Fang Kong . From HgGa₂(SeO₃)₄ to Hg₂Ga(SeO₃)₂F: The first Hg^Ⅰ-based selenite birefringent crystal triggered by linear groups and fluoride ions. Chinese Chemical Letters, 2026, 37(2): 110588-. doi: 10.1016/j.cclet.2024.110588
5. [5]
  Xingyan Liu , Kaili Wu , Yacen Tang , Ning Qi , Yumeng Zhang , Youzhou He , Min Fu , Yanhui Ao . Ti₃C₂ MXene-derived TiO₂@C attached on Bi₂WO₆ with oxygen vacancies to fabricate S-scheme heterojunction for photocatalytic antibiotics degradation and NO removal. Chinese Chemical Letters, 2025, 36(11): 110882-. doi: 10.1016/j.cclet.2025.110882
6. [6]
  Weinan Hu , Li Li , Xinyu Wang , Yongqiang Zhang , Maoping Song , Linlin Shi , Xinqi Hao , Siyu Lu . Carbonized polymer dots: Illuminating synthesis pathways, optical frontiers, and photoelectronic breakthroughs. Chinese Chemical Letters, 2025, 36(11): 111612-. doi: 10.1016/j.cclet.2025.111612
7. [7]
  Jieqiong Xu , Wenbin Chen , Shengkai Li , Qian Chen , Tao Wang , Yadong Shi , Shengyong Deng , Mingde Li , Peifa Wei , Zhuo Chen . Organic stoichiometric cocrystals with a subtle balance of charge-transfer degree and molecular stacking towards high-efficiency NIR photothermal conversion. Chinese Chemical Letters, 2024, 35(10): 109808-. doi: 10.1016/j.cclet.2024.109808
8. [8]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
9. [9]
  Zirui Zhu , Peng Liu , Jinhua Wang , Hongbin Zhang , Wei Luo . Effects of nano-metakaolin on the enhanced properties and microstructure development of natural hydraulic lime. Chinese Chemical Letters, 2025, 36(4): 109794-. doi: 10.1016/j.cclet.2024.109794
10. [10]
  Yuqing Ding , Zhiying Yi , Zhihui Wang , Hongyu Chen , Yan Zhao . Liquid nitrogen post-treatment for improved aggregation and electrical properties in organic semiconductors. Chinese Chemical Letters, 2024, 35(12): 109918-. doi: 10.1016/j.cclet.2024.109918
11. [11]
  Menglan Wei , Xiaoxia Ou , Yimeng Wang , Mengyuan Zhang , Fei Teng , Kaixuan Wang . S-scheme heterojunction g-C₃N₄/Bi₂WO₆ highly efficient degradation of levofloxacin: performance, mechanism and degradation pathway. Acta Physico-Chimica Sinica, 2025, 41(9): 100105-0. doi: 10.1016/j.actphy.2025.100105
12. [12]
  Qishen Wang , Changzhao Chen , Mengqing Li , Lingmin Wu , Kai Dai . Lignin derived carbon quantum dots and oxygen vacancies coregulated S-scheme LCQDs/Bi₂WO₆ heterojunction for photocatalytic H₂O₂ production. Acta Physico-Chimica Sinica, 2025, 41(11): 100147-0. doi: 10.1016/j.actphy.2025.100147
13. [13]
  Zhinan GUO , Junli WANG , Qiang ZHAO , Zhifang JIA , Zuopeng LI , Kewei WANG , Yong GUO . Cu₂O/Bi₂CrO₆ Z-scheme heterojunction: Construction and photocatalytic degradation properties for tetracycline. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 741-752. doi: 10.11862/CJIC.20240403
14. [14]
  Hui Li , Chunlang Gao , Guo Yang , Lu Xia , Wulyu Jiang , Cheng Wu , Kaiwen Wang , Yingtang Zhou , Xiaodong Han . Enhanced photocatalytic CO₂ reduction of Bi₂WO₆-BiOCl heterostructure with coherent interface for charge utilization. Chinese Chemical Letters, 2025, 36(9): 110547-. doi: 10.1016/j.cclet.2024.110547
15. [15]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
16. [16]
  Tianli Hui , Tao Zheng , Xiaoluo Cheng , Tonghui Li , Rui Zhang , Xianghai Meng , Haiyan Liu , Zhichang Liu , Chunming Xu . A review of plasma treatment on nano-microstructure of electrochemical water splitting catalysts. Chinese Journal of Structural Chemistry, 2025, 44(3): 100520-100520. doi: 10.1016/j.cjsc.2025.100520
17. [17]
  Zihe SONG , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Crystal structure, thermal analysis, and luminescence properties of six heterocyclic lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 181-192. doi: 10.11862/CJIC.20250126
18. [18]
  Gongxi Li , Jun Jin , Junxuan Tu , Haoguo Yue , Ying Wang , Xiaohui Jia , Weiyuan Yin , Zhenglin Han , Yuxuan Deng , Chunfeng Shi , Yonggang Zhen . Intrinsically stretchable polymer semiconductors synergistically constructed by hydrogen bonds and metal coordination. Chinese Chemical Letters, 2025, 36(12): 111716-. doi: 10.1016/j.cclet.2025.111716
19. [19]
  Yinghao Zhang , Ke Shao , Yihang Zhu , Haokun Zhang , Yinuo Zhuo , Huihui Bao , Yeye Ai , Yongguang Li . Unanticipated optical properties of π-conjugated cyclometalated Pt(Ⅱ) complexes for advanced information storage and anti-counterfeiting materials. Chinese Chemical Letters, 2025, 36(9): 110735-. doi: 10.1016/j.cclet.2024.110735
20. [20]
  Ying Xu , Yan Pu , Qiong Zhang , Xi Kang , Manzhou Zhu . Order-by-order control over the nonlinear optical properties of atomically precise nanoclusters. Chinese Journal of Structural Chemistry, 2025, 44(10): 100735-100735. doi: 10.1016/j.cjsc.2025.100735

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(1580)
HTML views(100)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and optical properties of three-dimensional navel-like Bi2WO6 hierarchical microspheres

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and optical properties of three-dimensional navel-like Bi₂WO₆ hierarchical microspheres