Citation: Zhang Zhijia, Hou Yuxuan, Zhang Shaofei, Zhang Guoliang, Li Ming, Lu Huanming, Li Yong, Zheng Xuerong, Qiao Zhijun, Yu Zhenyang, Huang Qin, Kang Jianli. Facile synthesized Cu-SnO₂ anode materials with three-dimensional metal cluster conducting architecture for high performance lithium-ion batteries[J]. Chinese Chemical Letters, ;2018, 29(11): 1656-1660. doi: 10.1016/j.cclet.2018.06.017 shu

Facile synthesized Cu-SnO₂ anode materials with three-dimensional metal cluster conducting architecture for high performance lithium-ion batteries

Zhang Zhijia ^a,c,*,, ,
Hou Yuxuan ^b ,
Zhang Shaofei ^a ,
Zhang Guoliang ^a ,
Li Ming ^d ,
Lu Huanming ^d ,
Li Yong ^d ,
Zheng Xuerong ^e ,
Qiao Zhijun ^b,, ,
Yu Zhenyang ^b ,
Huang Qin ^a,c ,
Kang Jianli ^a,c,f,*,,

a.
School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, China
b.
School of Mechanical Engineering, Tianjin Polytechnic University, Tianjin 300387, China
c.
Tianjin Municipal Key Laboratory of Advanced Fibers and Energy Storage, Tianjin 300387, China
d.
Test Center, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Science(CAS), Ningbo 315201, China
e.
School of Materials Science and Engineering, Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin 300072, China
f.
State key laboratory of separation membrane and membrane processes, Tianjin Polytechnic University, Tianjin 300387, China

Corresponding author: Zhang Zhijia, zhangzhijia@tjpu.edu.cn Qiao Zhijun, zjqtjpu@163.com Kang Jianli, kangjianli@tjpu.edu.cn

Received Date: 22 March 2018
Revised Date: 26 April 2018
Accepted Date: 11 June 2018
Available Online: 11 November 2018

Figures(4)

Metal oxide anode material is one of promising candidates for the next-generation LIBs, due to its high theoretical capacity and low cost. The poor conductivity and huge volume change during charge/discharge, however, restrict the commercialization of metal oxide anode material. In this work, we design a novel Cu-SnO₂ composite derived from Cu₆Sn₅ alloy with three dimensional (3D) metal cluster conducting architecture. The novel Cu structure penetrates in the composite particles inducing high conductivity and space-confined SnO₂, which restrict the pulverization of SnO₂ during lithiation/delithiation process. The optimized Cu-SnO₂ composite anode delivers an initial discharge capacity of 933.7 mA h/g and retains a capacity of 536.1 mA h/g after 200 cycles, at 25℃ and a rate of 100 mA/g. Even at the high rate of 300 mA/g, the anode still exhibits a capacity of more than 29% of that tested at 50 mA/g. Combining with the phase and morphology analysis, the novel Cu-SnO₂ composite not only has good electrical conductivity, but also possesses high theoretical capacity (995 mAh/g), which may pave a new way for the design and construction of next-generation metal oxide anode materials with high power and cycling stability.
- Cu-SnO₂ composite,
- Cu₆Sn₅ alloy,
- Ball milling,
- Anode materials,
- Lithium-ion batteries
1. [1]
  J. Mei, T. Liao, Z. Sun, J. Energy Chem. 27(2018) 117-127. doi: 10.1016/j.jechem.2017.10.012
2. [2]
  S. Chu, A. Majumdar, Nature 488(2012) 294-303. doi: 10.1038/nature11475
3. [3]
  Y. Sun, X. Liang, H. Xiang, Y. Yu, Chin. Chem. Lett. 28(2017) 2251-2253. doi: 10.1016/j.cclet.2017.11.028
4. [4]
  L. Ellingsen, C.R. Hung, G. Majeau-Bettez, et al., Nat. Nanotechnol. 11(2016) 1039. doi: 10.1038/nnano.2016.237
5. [5]
  J. Mei, T. Liao, L. Kou, Z. Sun, Adv. Mater. 29(2017) 1700176. doi: 10.1002/adma.v29.48
6. [6]
  J. Lu, Z. Chen, Z. Ma, et al., Nat. Nanotechnol. 11(2016) 1031-1038. doi: 10.1038/nnano.2016.207
7. [7]
  S. Chu, Y. Cui, N. Liu, Nat. Mater. 16(2016) 16-22.
8. [8]
  Y. Sun, N. Liu, Y. Cui, Nat. Energy 1(2016) 16071. doi: 10.1038/nenergy.2016.71
9. [9]
  J. Peng, Y. Zuo, G. Li, G. Wang, Chin. Chem. Lett. 27(2016) 1559-1562. doi: 10.1016/j.cclet.2016.02.028
10. [10]
  J.T. Xu, J.M. Ma, Q.H. Fan, S.J. Guo, S.X. Dou, Adv. Mater. 29(2017) 1606454. doi: 10.1002/adma.v29.28
11. [11]
  R. Hu, Y. Ouyang, T. Liang, et al., Adv. Mater. 29(2017) 1605006. doi: 10.1002/adma.201605006
12. [12]
  Q. Liu, Y. Dou, B. Ruan, Chem. Eur. J. 22(2016) 5853-5857. doi: 10.1002/chem.201505122
13. [13]
  Q. Yang, T. Sun, J. Yu, J. Ma, Chin. Chem. Lett. 27(2016) 412-416. doi: 10.1016/j.cclet.2015.12.025
14. [14]
  W. Dong, J. Xu, C. Wang, et al., Adv. Mater. 29(2017) 1700136. doi: 10.1002/adma.201700136
15. [15]
  D. Cui, Z. Zheng, X. Peng, et al., J. Power Sources 362(2017) 20-26. doi: 10.1016/j.jpowsour.2017.07.024
16. [16]
  C. Cui, J. Xu, L. Wang, et al., ACS Appl. Mater. Int. 8(2016) 8568-8575. doi: 10.1021/acsami.6b02962
17. [17]
  M.S. Park, G.X. Wang, Y.M. Kang, et al., Angew. Chem. Int. Ed. 119(2007) 764-767. doi: 10.1002/ange.200603309
18. [18]
  J.H. Jeun, K.Y. Park, D.H. Kim, et al., Nanoscale 5(2013) 8480-8483. doi: 10.1039/c3nr01964k
19. [19]
  W. Wei, F. Jia, K. Wang, P. Qu, Chin. Chem. Lett. 28(2017) 324-328. doi: 10.1016/j.cclet.2016.09.003
20. [20]
  R. Hu, W. Sun, H. Liu, M. Zeng, M. Zhu, Nanoscale 5(2013) 11971-11979. doi: 10.1039/c3nr03756h
21. [21]
  C. Zhong, J. Wang, Z. Chen, H. Liu, J. Phys. Chem. C 115(2011) 25115-25120. doi: 10.1021/jp2061128
22. [22]
  H. Kim, S.W. Kim, Y.U. Park, et al., Nano. Res. 3(2010) 813-821. doi: 10.1007/s12274-010-0050-4
23. [23]
  J. Liao, C. Yuan, H. Li, et al., Nano-Micro Lett. 10(2018) 21. doi: 10.1007/s40820-017-0172-2
24. [24]
  H. Li, H. Zhou, Chem. Commun. 48(2012) 1201-1217. doi: 10.1039/C1CC14764A
25. [25]
  K. Huang, B. Li, M. Zhao, et al., Chin. Chem. Lett. 28(2017) 2195-2206. doi: 10.1016/j.cclet.2017.11.010
26. [26]
  R. Hu, G.H. Waller, Y. Wang, et al., Nano Energy 18(2015) 232-244. doi: 10.1016/j.nanoen.2015.10.037
27. [27]
  H. He, W. Fu, H. Wang, et al., Nano Energy 34(2017) 449-455. doi: 10.1016/j.nanoen.2017.03.017
28. [28]
  L. Zu, Q. Su, F. Zhu, et al., Adv. Mater. 29(2017) 1701494. doi: 10.1002/adma.v29.34
29. [29]
  J. Kang, S. Zhang, Z. Zhang, Adv. Mater. 29(2017) 1700515. doi: 10.1002/adma.v29.48
30. [30]
  J. Chen, L. Yang, S. Fang, Z. Zhang, S. Hirano, Electrochim. Acta 105(2013) 629-634. doi: 10.1016/j.electacta.2013.05.052
31. [31]
  K.D. Kepler, J.T. Vaughey, M.M. Thackeray, J. Power. Sources 81-82(1999) 383-387. doi: 10.1016/S0378-7753(99)00111-1
32. [32]
  Q. Han, Z. Yi, Y. Cheng, Y. Wu, L. Wang, RSC Adv. 6(2016) 15279-15285. doi: 10.1039/C5RA23788B
33. [33]
  B. Lu, R. Hu, J. Liu, et al., RSC Adv. 6(2016) 13384-13391. doi: 10.1039/C5RA23988E
34. [34]
  Y.J. Mai, X.L. Wang, J.Y. Xiang, et al., Electrochim. Acta 56(2011) 2306-2311. doi: 10.1016/j.electacta.2010.11.036
35. [35]
  J. Liang, X. Gao, J. Guo, et al., Sci. China Mater. 61(2018) 30-38. doi: 10.1007/s40843-017-9119-2
36. [36]
  Z. Zhang, Y. Wang, S. Chou, et al., J. Power Sources 280(2015) 107-113. doi: 10.1016/j.jpowsour.2015.01.092
1. [1]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
2. [2]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
3. [3]
  Mei-Chen Liu , Qing-Song Liu , Yi-Zhou Quan , Jia-Ling Yu , Gang Wu , Xiu-Li Wang , Yu-Zhong Wang . Phosphorus-silicon-integrated electrolyte additive boosts cycling performance and safety of high-voltage lithium-ion batteries. Chinese Chemical Letters, 2024, 35(8): 109123-. doi: 10.1016/j.cclet.2023.109123
4. [4]
  Wendi Dou , Guangying Wan , Tiefeng Liu , Lin Han , Wu Zhang , Chuang Sun , Rensheng Song , Jianhui Zheng , Yujing Liu , Xinyong Tao . Conductive composite binder for recyclable LiFePO₄ cathode. Chinese Chemical Letters, 2024, 35(11): 109389-. doi: 10.1016/j.cclet.2023.109389
5. [5]
  Guihuang Fang , Ying Liu , Yangyang Feng , Ying Pan , Hongwei Yang , Yongchuan Liu , Maoxiang Wu . Tuning the ion-dipole interactions between fluoro and carbonyl (EC) by electrolyte design for stable lithium metal batteries. Chinese Chemical Letters, 2025, 36(1): 110385-. doi: 10.1016/j.cclet.2024.110385
6. [6]
  Zhong-Hui Sun , Yu-Qi Zhang , Zhen-Yi Gu , Dong-Yang Qu , Hong-Yu Guan , Xing-Long Wu . CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(1): 109590-. doi: 10.1016/j.cclet.2024.109590
7. [7]
  Hui Gu , Mingyue Gao , Kuan Shen , Tianli Zhang , Junhao Zhang , Xiangjun Zheng , Xingmei Guo , Yuanjun Liu , Fu Cao , Hongxing Gu , Qinghong Kong , Shenglin Xiong . F127 assisted fabrication of Ge/rGO/CNTs nanocomposites with three-dimensional network structure for efficient lithium storage. Chinese Chemical Letters, 2024, 35(9): 109273-. doi: 10.1016/j.cclet.2023.109273
8. [8]
  Mianying Huang , Zhiguang Xu , Xiaoming Lin . Mechanistic analysis of Co2VO4/X (X = Ni, C) heterostructures as anode materials of lithium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100309-100309. doi: 10.1016/j.cjsc.2024.100309
9. [9]
  Peng Zhou , Ziang Jiang , Yang Li , Peng Xiao , Feixiang Wu . Sulphur-template method for facile manufacturing porous silicon electrodes with enhanced electrochemical performance. Chinese Chemical Letters, 2024, 35(8): 109467-. doi: 10.1016/j.cclet.2023.109467
10. [10]
  Guihuang Fang , Wei Chen , Hongwei Yang , Haisheng Fang , Chuang Yu , Maoxiang Wu . Improved performance of LiMn_0.8Fe_0.2PO₄ by addition of fluoroethylene carbonate electrolyte additive. Chinese Chemical Letters, 2024, 35(6): 108799-. doi: 10.1016/j.cclet.2023.108799
11. [11]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
12. [12]
  Haixia Wu , Kailu Guo . Iodized polyacrylonitrile as fast-charging anode for lithium-ion battery. Chinese Chemical Letters, 2024, 35(10): 109550-. doi: 10.1016/j.cclet.2024.109550
13. [13]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
14. [14]
  Shuo Zhang , Haitao Liao , Zhi-Qun Liu , Chong Yan , Jia-Qi Huang . Re-evaluating the nano-sized inorganic protective layer on Cu current collector for anode free lithium metal batteries. Chinese Chemical Letters, 2024, 35(7): 109284-. doi: 10.1016/j.cclet.2023.109284
15. [15]
  Yue Qian , Zhoujia Liu , Haixin Song , Ruize Yin , Hanni Yang , Siyang Li , Weiwei Xiong , Saisai Yuan , Junhao Zhang , Huan Pang . Imide-based covalent organic framework with excellent cyclability as an anode material for lithium-ion battery. Chinese Chemical Letters, 2024, 35(6): 108785-. doi: 10.1016/j.cclet.2023.108785
16. [16]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
17. [17]
  Huanyan Liu , Jiajun Long , Hua Yu , Shichao Zhang , Wenbo Liu . Rational design of highly conductive and stable 3D flexible composite current collector for high performance lithium-ion battery electrodes. Chinese Chemical Letters, 2025, 36(3): 109712-. doi: 10.1016/j.cclet.2024.109712
18. [18]
  Yang LIU , Lijun WANG , Hongyu WANG , Zhidong CHEN , Lin SUN . Surface and interface modification of porous silicon anodes in lithium-ion batteries by the introduction of heterogeneous atoms and hybrid encapsulation. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 773-785. doi: 10.11862/CJIC.20250015
19. [19]
  Huixin Chen , Chen Zhao , Hongjun Yue , Guiming Zhong , Xiang Han , Liang Yin , Ding Chen . Unraveling the reaction mechanism of high reversible capacity CuP₂/C anode with native oxidation PO_x component for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109650-. doi: 10.1016/j.cclet.2024.109650
20. [20]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(891)
HTML views(24)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Facile synthesized Cu-SnO2 anode materials with three-dimensional metal cluster conducting architecture for high performance lithium-ion batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Facile synthesized Cu-SnO₂ anode materials with three-dimensional metal cluster conducting architecture for high performance lithium-ion batteries