Citation: Wang Hua-Hua, Liu Hai-Yang, Cheng Fan, Ali Atif, Shi Lei, Xiao Xin-Yan, Chang Chi-Kwong. Silver(Ⅱ) 5, 10, 15, 20-tetra(ethoxycarbonyl) porphyrin:An unexpected six-coordinate linear assembled structure[J]. Chinese Chemical Letters, ;2018, 29(9): 1404-1408. doi: 10.1016/j.cclet.2017.12.027 shu

Silver(Ⅱ) 5, 10, 15, 20-tetra(ethoxycarbonyl) porphyrin:An unexpected six-coordinate linear assembled structure

Wang Hua-Hua ^a,b ,
Liu Hai-Yang ^a,, ,
Cheng Fan ^a ,
Ali Atif ^a ,
Shi Lei ^c ,
Xiao Xin-Yan ^a,, ,
Chang Chi-Kwong ^d,,

a.
School of Chemistry and Chemical Engineering, Key Laboratory of Functional Molecular Engineering of Guangdong Province, South China University of Technology, Guangzhou 510641, China
b.
Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, China
c.
Department of Chemistry, Guangdong University of Education, Guangzhou 510303, China
d.
Department of Chemistry, Michigan State University, E. Lansing, MI 48824, USA

Corresponding author: Liu Hai-Yang, chhyliu@scut.edu.cn Xiao Xin-Yan, cexyxiao@scut.edu.cn Chang Chi-Kwong, changc@msu.edu
Received Date: 30 September 2017
Revised Date: 7 December 2017
Accepted Date: 28 December 2017
Available Online: 29 September 2017

Figures(9)

The crystal structure of silver(Ⅱ) 5, 10, 15, 20-tetra(ethoxycarbonyl)porphyrin (Ag[Ⅱ]TECP) revealed it formed a one-dimensional coordination polymer through weak Ag-O interactions with an unusual sixcoordinated central silver(Ⅱ) atom.
- Porphyrin,
- Silver,
- Six-coordinated assembly,
- Crystal structure,
- Hydrogen bond
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