Citation: Wang Chenhui, Lai Qinzhi, Xu Pengcheng, Li Xianfeng, Zhang Huamin. A non-aqueous Li/organosulfur semi-solid flow battery[J]. Chinese Chemical Letters, ;2018, 29(5): 716-718. doi: 10.1016/j.cclet.2017.12.025 shu

A non-aqueous Li/organosulfur semi-solid flow battery

Wang Chenhui ^a,c ,
Lai Qinzhi ^a ,
Xu Pengcheng ^a ,
Li Xianfeng ^a,b,, ,
Zhang Huamin ^a,b,,

a.
Division of energy storage, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
b.
Collaborative Innovation Centre of Chemistry for Energy Materials(iChEM), Dalian 116023, China
c.
University of Chinese Academy of Sciences, Beijing 100039, China

Corresponding author: Li Xianfeng, lixianfeng@dicp.ac.cn Zhang Huamin, zhanghm@dicp.ac.cn
Received Date: 26 August 2017
Revised Date: 25 November 2017
Accepted Date: 30 December 2017
Available Online: 30 May 2017

Figures(2)

Non-aqueous flow batteries have attracted extensive attention due to the advantages of wide voltage window, high energy density and wide operating temperature and so on. Herein, tetramethylthiuram disulfide (TMTD) with high intrinsic capacity (223 mAh/g) and high solubility (~1 mol/L in chloroform) is investigated as the positive active material of the non-aqueous Li/disulfide semi-solid flow battery. The electrochemical activity and reversibility are investigated by cyclic voltammetry and linear scan voltammetry. This Li/TMTD battery with a high cell voltage of 3.36 V achieves coulombic efficiency of 99%, voltage efficiency of 73% and energy efficiency of 72% at the current density of 5 mA/cm² with active material concentration of 0.1 mol/L. Moreover, the Li/TMTD battery can operate for 100 cycles without obvious efficiency decay, indicating good stability.
- Energy storage,
- Batteries,
- Organosulfur,
- High energy density,
- High cell voltage
1. [1]
  F. Díaz-González, A. Sumper, O. Gomis-Bellmunt, R. Villafáfila-Robles, Renew. Sustain. Energy Rev. 16(2012) 2154-2171. doi: 10.1016/j.rser.2012.01.029
2. [2]
  C. Schaber, P. Mazza, R. Hammerschlag, Electr. J. 17(2004) 21-29.
3. [3]
  Z. Yang, J. Zhang, M.C.W. Kintner-Meyer, et al., Chem. Rev. 111(2011) 3577-3613. doi: 10.1021/cr100290v
4. [4]
  E.J. Cairns, Encycl. Energy (2004) 117-126.
5. [5]
  F. Beck, P. Rüetschi, Electrochim. Acta 45(2000) 2467-2482. doi: 10.1016/S0013-4686(00)00344-3
6. [6]
  P.G. Bruce, S.A. Freunberger, L.J. Hardwick, J.M. Tarascon, Nat. Mater. 11(2012) 19-29. doi: 10.1038/nmat3191
7. [7]
  X. Ji, K.T. Lee, L.F. Nazar, Nat. Mater. 8(2009) 500-506. doi: 10.1038/nmat2460
8. [8]
  H. Wang, Y. Yang, Y. Liang, et al., Nano Lett. 11(2011) 2644-2647. doi: 10.1021/nl200658a
9. [9]
  C. Zhang, H.B. Wu, C. Yuan, Z. Guo, X.W. Lou, Angew. Chem. Int. Ed. 51(2012) 9592-9595. doi: 10.1002/anie.v51.38
10. [10]
  L. Xiao, Y. Cao, J. Xiao, et al., Adv. Mater. 24(2012) 1176-1181. doi: 10.1002/adma.v24.9
11. [11]
  Y. Zhao, W. Zhu, G.Z. Chen, E.J. Cairns, J. Power Sources 327(2016) 447-456. doi: 10.1016/j.jpowsour.2016.07.082
12. [12]
  W. Li, Q. Zhang, G. Zheng, et al., Nano Lett. 13(2013) 5534-5540. doi: 10.1021/nl403130h
13. [13]
  W. Zhou, Y. Yu, H. Chen, F.J. DiSalvo, H.D. Abruña, J. Am. Chem. Soc. 135(2013) 16736-16743. doi: 10.1021/ja409508q
14. [14]
  Z. Wei Seh, W. Li, J.J. Cha, et al., Nat. Commun. 4(2013) 1331. doi: 10.1038/ncomms2327
15. [15]
  N. Ding, L. Zhou, C. Zhou, et al., Sci. Rep. 6(2016) 33154. doi: 10.1038/srep33154
16. [16]
  Y. NuLi, Z. Guo, H. Liu, J. Yang, Electrochem. Commun. 9(2007) 1913-1917. doi: 10.1016/j.elecom.2007.05.009
17. [17]
  S.J. Visco, M. Liu, L.C. De Jonghe, J. Electrochem. Soc. 137(1990) 1191-1192. doi: 10.1149/1.2086627
18. [18]
  M. Liu, S.J. Visco, L.C. De Jonghe, J. Electrochem. Soc. 136(1989) 2570-2575. doi: 10.1149/1.2097478
19. [19]
  M. Liu, S.J. Visco, L.C. De Jonghe, J. Electrochem. Soc. 137(1990) 750-759. doi: 10.1149/1.2086549
20. [20]
  K. Naoi, K. i. Kawase, Y. Inoue, J. Electrochem. Soc. 144(1997) L170-L172. doi: 10.1149/1.1837714
21. [21]
  C. Wang, X. Li, X. Xi, et al., RSC Adv. 6(2016) 40169-40174. doi: 10.1039/C6RA03712G
22. [22]
  X. Wei, L. Cosimbescu, W. Xu, et al., Adv. Energy Mater. 5(2015) 1400678. doi: 10.1002/aenm.201400678
1. [1]
  Jieqiong Qin , Zhi Yang , Jiaxin Ma , Liangzhu Zhang , Feifei Xing , Hongtao Zhang , Shuxia Tian , Shuanghao Zheng , Zhong-Shuai Wu . Interfacial assembly of 2D polydopamine/graphene heterostructures with well-defined mesopore and tunable thickness for high-energy planar micro-supercapacitors. Chinese Chemical Letters, 2024, 35(7): 108845-. doi: 10.1016/j.cclet.2023.108845
2. [2]
  Shuangliang Xie , Yuyue Chen , Qing He , Liang Chen , Jikun Yang , Shiqing Deng , Yimei Zhu , He Qi . Relaxor antiferroelectric-relaxor ferroelectric crossover in NaNbO₃-based lead-free ceramics for high-efficiency large-capacitive energy storage. Chinese Chemical Letters, 2024, 35(7): 108871-. doi: 10.1016/j.cclet.2023.108871
3. [3]
  Xinyu Ren , Hong Liu , Jingang Wang , Jiayuan Yu . Electrospinning-derived functional carbon-based materials for energy conversion and storage. Chinese Chemical Letters, 2024, 35(6): 109282-. doi: 10.1016/j.cclet.2023.109282
4. [4]
  Jian Wang , Baohui Wang , Pin Ma , Yifei Zhang , Honghong Gong , Biyun Peng , Sen Liang , Yunchuan Xie , Hailong Wang . Regulation of uniformity and electric field distribution achieved highly energy storage performance in PVDF-based nanocomposites via continuous gradient structure. Chinese Chemical Letters, 2025, 36(4): 109714-. doi: 10.1016/j.cclet.2024.109714
5. [5]
  Ningning Zhao , Yuyan Liang , Wenjie Huo , Xinyan Zhu , Zhangxing He , Zekun Zhang , Youtuo Zhang , Xianwen Wu , Lei Dai , Jing Zhu , Ling Wang , Qiaobao Zhang . Separator functionalization enables high-performance zinc anode via ion-migration regulation and interfacial engineering. Chinese Chemical Letters, 2024, 35(9): 109332-. doi: 10.1016/j.cclet.2023.109332
6. [6]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
7. [7]
  Jun-Ming Cao , Kai-Yang Zhang , Jia-Lin Yang , Zhen-Yi Gu , Xing-Long Wu . Differential bonding behaviors of sodium/potassium-ion storage in sawdust waste carbon derivatives. Chinese Chemical Letters, 2024, 35(4): 109304-. doi: 10.1016/j.cclet.2023.109304
8. [8]
  Qingyun Hu , Wei Wang , Junyuan Lu , He Zhu , Qi Liu , Yang Ren , Hong Wang , Jian Hui . High-throughput screening of high energy density LiMn_1-xFe_xPO₄ via active learning. Chinese Chemical Letters, 2025, 36(2): 110344-. doi: 10.1016/j.cclet.2024.110344
9. [9]
  Xin Li , Ling Zhang , Yunyan Fan , Shaojing Lin , Yong Lin , Yongsheng Ying , Meijiao Hu , Haiying Gao , Xianri Xu , Zhongbiao Xia , Xinchuan Lin , Junjie Lu , Xiang Han . Carbon interconnected microsized Si film toward high energy room temperature solid-state lithium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109776-. doi: 10.1016/j.cclet.2024.109776
10. [10]
  Yue Wang , Caixia Xu , Xingtao Tian , Siyu Wang , Yan Zhao . Challenges and Modification Strategies of High-Voltage Cathode Materials for Li-ion Batteries. Chinese Journal of Structural Chemistry, 2023, 42(10): 100167-100167. doi: 10.1016/j.cjsc.2023.100167
11. [11]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
12. [12]
  Lingjiang Kou , Yong Wang , Jiajia Song , Taotao Ai , Wenhu Li , Mohammad Yeganeh Ghotbi , Panya Wattanapaphawong , Koji Kajiyoshi . Mini review: Strategies for enhancing stability of high-voltage cathode materials in aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 110368-. doi: 10.1016/j.cclet.2024.110368
13. [13]
  Haining Peng , Huijun Liu , Chengzong Li , Yingfu Li , Qizhi Chen , Tao Li . Diluent modified weakly solvating electrolyte for fast-charging high-voltage lithium metal batteries. Chinese Chemical Letters, 2025, 36(1): 109556-. doi: 10.1016/j.cclet.2024.109556
14. [14]
  Zhen-Zhen Dong , Jin-Hao Zhang , Lin Zhu , Xiao-Zhong Fan , Zhen-Guo Liu , Yi-Bo Yan , Long Kong . Attenuating reductive decomposition of fluorinated electrolytes for high-voltage lithium metal batteries. Chinese Chemical Letters, 2025, 36(4): 109773-. doi: 10.1016/j.cclet.2024.109773
15. [15]
  Jun Jiang , Tong Guo , Wuxin Bai , Mingliang Liu , Shujun Liu , Zhijie Qi , Jingwen Sun , Shugang Pan , Aleksandr L. Vasiliev , Zhiyuan Ma , Xin Wang , Junwu Zhu , Yongsheng Fu . Modularized sulfur storage achieved by 100% space utilization host for high performance lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(4): 108565-. doi: 10.1016/j.cclet.2023.108565
16. [16]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
17. [17]
  Mei-Chen Liu , Qing-Song Liu , Yi-Zhou Quan , Jia-Ling Yu , Gang Wu , Xiu-Li Wang , Yu-Zhong Wang . Phosphorus-silicon-integrated electrolyte additive boosts cycling performance and safety of high-voltage lithium-ion batteries. Chinese Chemical Letters, 2024, 35(8): 109123-. doi: 10.1016/j.cclet.2023.109123
18. [18]
  Hangwen Zheng , Ziqian Wang , HuiJie Zhang , Jing Lei , Rihui Li , Jian Yang , Haiyan Wang . Synthesis and applications of B, N co-doped carbons for zinc-based energy storage devices. Chinese Chemical Letters, 2025, 36(3): 110245-. doi: 10.1016/j.cclet.2024.110245
19. [19]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
20. [20]
  Yan-Jiang Li , Shu-Lei Chou , Yao Xiao . Detecting dynamic structural evolution based on in-situ high-energy X-ray diffraction technology for sodium layered oxide cathodes. Chinese Chemical Letters, 2025, 36(2): 110389-. doi: 10.1016/j.cclet.2024.110389

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