Citation: Lu Yanluo, Tang Yanqun, Lin Heyang, Fang Xiaoyu, Lu Bo, Li Dan, Yan Dongpeng. Selective formation of luminescent chiral cocrystal: Molecular self-assembly of 2, 2'-binaphthol and 2-(3-pyridyl)-1H-benzimidazole[J]. Chinese Chemical Letters, ;2018, 29(10): 1541-1543. doi: 10.1016/j.cclet.2017.12.021 shu

Selective formation of luminescent chiral cocrystal: Molecular self-assembly of 2, 2'-binaphthol and 2-(3-pyridyl)-1H-benzimidazole

Lu Yanluo ^a ,
Tang Yanqun ^a ,
Lin Heyang ^a ,
Fang Xiaoyu ^b ,
Lu Bo ^b ,
Li Dan ^b ,
Yan Dongpeng ^a,b,,

a.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
b.
Key Laboratory of Theoretical and Computational Photochemistry, Ministry of Education, College of Chemistry, Beijing Normal University, Beijing 100875, China

Corresponding author: Yan Dongpeng, yandongpeng001@163.com
Received Date: 22 November 2017
Revised Date: 22 January 2018
Accepted Date: 22 January 2018
Available Online: 28 October 2017

Figures(7)

Luminescent cocrystals have been received much attention in fluorescence imaging and sensor application. In this work, we report that the high-quality chiral luminescent cocrystal can be obtained through a molecular self-assembly process of 2, 2'-binaphthol and 2-(3-pyridyl)-1H-benzimidazole. The assembly modes and stacking fashions of as-obtained cocrystal were determined by single crystal X-ray diffractometer. The structure and optical properties of the cocrystals were characterized by fluorescence emission, fluorescence decay, Raman and circular dichroism spectra. The results show that both the pristine co-assembled units (R-BINOL and S-BINOL) give rise to the R conformation within the final cocrystal, suggesting that the formation of cocrystal can be an effective way to achieve R/S-isomeric transformation of 2, 2'-binaphthol. It is also expected that the co-crystallization approach has much flexibility and potential applications for the design and selective formation of chiral luminescent materials.
- Chiral cocrystal,
- Molecular self-assembly,
- Binaphthol
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