Citation: Zhu Quping, Shen Xinying, Wang Lingling, Zhu Luping, Wang Lijun, Liao Guihong. Polyvinylpyrrolidone-assisted growth and optical properties of ZnO hexagonal bilayer disk-like microstructures[J]. Chinese Chemical Letters, ;2018, 29(8): 1310-1312. doi: 10.1016/j.cclet.2017.12.018 shu

Polyvinylpyrrolidone-assisted growth and optical properties of ZnO hexagonal bilayer disk-like microstructures

a.
School of Environmental and Materials Engineering, Shanghai Polytechnic University, Shanghai 201209, China
b.
School of Civil Engineering, Chongqing Institute of Engineering, Chongqing 400054, China
c.
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China

Corresponding author: Zhu Luping, lpzhu@sspu.edu.cn; sspulpzhu@163.com
Received Date: 6 June 2017
Revised Date: 29 November 2017
Accepted Date: 22 December 2017
Available Online: 27 August 2017

Figures(4)

ZnO hexagonal bilayer disk-like microstructures are successfully fabricated using a simple solvothermal method assisted with polyvinylpyrrolidone (PVP). The structure and morphology were investigated by Xray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDX). XRD result indicated that the as-obtained samples were well-crystallized wurtzite hexagonal ZnO structure. SEM images showed that the ZnO hexagonal bilayer disk-like assembles consist of two uniform and smooth disks with an average edge length of 6 μm and thickness of 4 μm. UV-vis spectrum reveals that ZnO sampls show an appreciable red shift and the band gap energy of the obtained ZnO samples were about 3.15 eV. A very strong ultraviolet (UV) emission at the UV region was observed in the photoluminescence (PL) spectrum of the as-prepared ZnO samples tested at room temperature. A possible growth process of the ZnO hexagonal bilayer disk-like microstructures was schematically illustrated.
- Semiconductor,
- ZnO,
- Synthesis,
- Structural characterization,
- Optical properties
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1.
沈阳化工大学材料科学与工程学院沈阳 110142