Citation: Gao Aiqin, Liu Hui, Hu Liu, Zhang Hongjuan, Hou Aiqin, Xie Kongliang. Synthesis of Fe₃O₄@SiO₂-Au/Cu magnetic nanoparticles and its efficient catalytic performance for the Ullmann coupling reaction of bromamine acid[J]. Chinese Chemical Letters, ;2018, 29(8): 1301-1304. doi: 10.1016/j.cclet.2017.11.040 shu

Synthesis of Fe₃O₄@SiO₂-Au/Cu magnetic nanoparticles and its efficient catalytic performance for the Ullmann coupling reaction of bromamine acid

Gao Aiqin ^a ,
Liu Hui ^a ,
Hu Liu ^a ,
Zhang Hongjuan ^a ,
Hou Aiqin ^b ,
Xie Kongliang ^a,,

a.
College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
b.
National Engineering Research Center for Dyeing and Finishing of Textiles, Donghua University, Shanghai 200051, China

Corresponding author: Xie Kongliang, klxie@dhu.edu.cn
Received Date: 21 August 2017
Revised Date: 9 November 2017
Accepted Date: 28 November 2017
Available Online: 2 August 2017

Figures(3)

Novel magnetic core/shell bimetallic Au/Cu nanoparticles (Fe₃O₄@SiO₂-Au/Cu NPs) were prepared using SiO₂-coated iron oxide (Fe₃O₄@SiO₂) as a supported material. The magnetic Fe₃O₄ colloidal nanocrystal clusters (CNCs) as nano-core were modified with a silica coating for improvement stability and superficial area of the Au-Cu particles. The morphological structure and chemical composition of the Fe₃O₄@SiO₂-Au/Cu NPs were characterized with high-resolution transmission electron microscopy (HRTEM), energy-dispersive X-ray (EDX) and X-ray photoelectron spectroscopy (XPS) analyses. The Au and Cu NPs were deposited on the SiO₂ surface in a highly dense and well dispersed manner with an average size of approximately 5 nm. The Fe₃O₄@SiO₂-Au/Cu NPs as magnetic nano-catalysts were applied to the Ullmann coupling reaction of bromamine acid to synthesize 4, 40-diamino-1, 10-dianthraquinonyl-3, 30-disulfonic acid (DAS). The prepared Fe₃O₄@SiO₂-Au/Cu NPs exhibited efficient catalytic activity with higher conversion and selectivity. A bromamine acid conversion of 97.35% and selectivity for DAS of 88.67% were obtained in aqueous medium. The magnetic nano-catalysts can be readily separated from the reaction system and reused. This new nano-catalytic reaction represents a useful and attractive cleaner production system. The new catalyst system has important and potential applications in dye and pigment industry.
- Dye synthesis,
- Nano-catalyst,
- Fe₃O₄@SiO₂-Au/Cu NPs,
- Magnetic separation,
- Ullmann coupling reaction,
- Recyclability
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Synthesis of Fe3O4@SiO2-Au/Cu magnetic nanoparticles and its efficient catalytic performance for the Ullmann coupling reaction of bromamine acid

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通讯作者: 陈斌, bchen63@163.com

Synthesis of Fe₃O₄@SiO₂-Au/Cu magnetic nanoparticles and its efficient catalytic performance for the Ullmann coupling reaction of bromamine acid