Citation: Kan Yanfang, Ning Guoqing, Ma Xinlong. Sulfur-decorated nanomesh graphene for high-performance supercapacitors[J]. Chinese Chemical Letters, ;2017, 28(12): 2277-2280. doi: 10.1016/j.cclet.2017.11.026 shu

Sulfur-decorated nanomesh graphene for high-performance supercapacitors

State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China

Corresponding author: Ning Guoqing, ngq@cup.edu.cn; ninggq@qq.com

Received Date: 28 September 2017
Revised Date: 2 November 2017
Accepted Date: 16 November 2017
Available Online: 21 December 2017

Figures(5)

Sulfur-decorated nanomesh graphene (S@G) has been synthesized by a 155℃ heat treatment of a mixture of nanomesh graphene and S. The as-obtained S@G materials keep a high specific surface area, and exhibit obviously enhanced conductivity and hydrophilicity as compared to the pristine graphene. X-ray photoelectron spectroscopy and thermogravimetric analysis indicate that most S atoms in the S@G samples are stably combined with nanomesh graphene via covalent bonds rather than exist as free elemental S. As an electrode material for aqueous supercapacitors, the S@G with a S content of 5 wt% delivers a specific capacitance up to 257 F/g at the current density of 0.25 A/g, which is 23.6% higher than that of the undoped graphene. Our results provide a simple approach to scalable synthesis of S-doped porous carbon materials, which have potential applications in the high-performance capacitive energy storage devices.
- Sulfur-decorated,
- Graphene,
- Supercapacitor,
- Doping,
- High performance
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