Citation: Feng Jun, Shao Jiang-Yang, Nie Hai-Jing, Gong Zhong-Liang, Zhong Yu-Wu. Synthesis and electrochemical and spectroscopic studies of a N, N, N', N'-tetraphenylbenzidine-bridged bis(2, 2'-bipyridine) ligand and diruthenium complex[J]. Chinese Chemical Letters, ;2018, 29(3): 385-389. doi: 10.1016/j.cclet.2017.11.014 shu

Synthesis and electrochemical and spectroscopic studies of a N, N, N', N'-tetraphenylbenzidine-bridged bis(2, 2'-bipyridine) ligand and diruthenium complex

a.
CAS Key Laboratory of Photochemistry, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Zhong Yu-Wu, zhongyuwu@iccas.ac.cn

Received Date: 12 October 2017
Revised Date: 23 October 2017
Accepted Date: 13 November 2017
Available Online: 15 March 2017

Figures(5)

A N, N, N', N'-tetraphenylbenzidine-bridged bis(2, 2'-bipyridine) ligand and corresponding diruthenium complexes were synthesized and characterized. They show rich multistep redox processes due to the stepwise oxidations of the amine units and ruthenium components. Their absorption and emission spectral changes in response to electrochemical stimulus were examined by spectroelectrochemical measurements. DFT and TDDFT calculations were performed to complement the experimental results.
- Ruthenium,
- Spectroelectrochemistry,
- Electrochromism,
- Redox-active compounds,
- Bipyridine
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