Citation: Li Xinyue, Semin Sergey, A. Estrada Leandro, Yuan Chunqing, Duan Yulong, Cremers Jonathan, Tinnemans Paul, Kouwer Paul, E. Rowan Alan, Rasing Theo, Xu Jialiang. Strong optical nonlinearities of self-assembled polymorphic microstructures of phenylethynyl functionalized fluorenones[J]. Chinese Chemical Letters, ;2018, 29(2): 297-300. doi: 10.1016/j.cclet.2017.11.001 shu

Strong optical nonlinearities of self-assembled polymorphic microstructures of phenylethynyl functionalized fluorenones

a.
School of Chemical and Engineering Technology, Tianjin University, Tianjin 300350, China
b.
Institute for Molecules and Materials(IMM), Radboud University, 6525 AJ, Nijmegen, The Netherlands
c.
Center for Photochemical Sciences, Bowling Green State University, Bowling Green OH 43403, USA
d.
Solvay Specialty Polymers, Alpharetta GA 30005, USA
e.
Australian Institute for Bioengineering and Nanotechnology(AIBN), The University of Queensland, Brisbane QLD 4072, Australia

Corresponding author: Xu Jialiang, jialiang.xu@tju.edu.cn
Received Date: 26 August 2017
Revised Date: 2 November 2017
Accepted Date: 2 November 2017
Available Online: 6 February 2017

Figures(5)

Highly efficient nonlinear optical (NLO) materials with well-defined architectures in the wavelength and subwavelength length scales are of particular importance for next generation of integrated photonic circuits. Fluorenone analogues have been demonstrated to be promising candidates as building blocks for assembly of organic NLO materials thanks to their synergistic supramolecular interactions and brilliant optical properties. Here we have studied the polymorphs of a phenylethynyl functionalized fluorenone derivative, and their controlled self-assembly for microstructures with different morphologies. These polymorphic microcrystals exhibit very distinctive NLO properties, highly related to their supramolecular and electronic structures.
- Nonlinear optics,
- Second harmonic generation,
- Two-photon excited fluorescence,
- Transition dipole,
- Fluorenone
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1.
沈阳化工大学材料科学与工程学院沈阳 110142