Citation: Wan Yan, Ma Jia-Qi, Hong Chao, Li Mei-Chao, Jin Li-Qun, Hu Xin-Quan, Hu Bao-Xiang, Mo Wei-Min, Sun Nan, Shen Zhen-Lu. Direct synthesis of imines by 9-azabicyclo-[3, 3, 1]nonan-N-oxyl/KOHcatalyzed aerobic oxidative coupling of alcohols and amines[J]. Chinese Chemical Letters, ;2018, 29(8): 1269-1272. doi: 10.1016/j.cclet.2017.10.006 shu

Direct synthesis of imines by 9-azabicyclo-[3, 3, 1]nonan-N-oxyl/KOHcatalyzed aerobic oxidative coupling of alcohols and amines

College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: Shen Zhen-Lu, zhenlushen@zjut.edu.cn
Received Date: 15 June 2017
Revised Date: 4 September 2017
Accepted Date: 11 October 2017
Available Online: 14 August 2017

Figures(2)

A simple and efficient method for preparation of imines by the oxidative coupling of benzyl alcohols with aromatic amines or aliphatic amines was developed. The reaction was catalyzed by 9-azabicyclo[3.3.1] nonan-N-oxyl (ABNO)/KOH with air as the economic and green oxidant. Under the optimal reaction conditions, a variety of imines were obtained in 80%-96% isolated yields.
- Imines,
- Benzyl alcohols,
- Amines ABNO,
- Air
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