Citation: Dang Rui, Jia Xilai, Wang Peng, Zhang Xiaowei, Wang Danni, Wang Ge. Hydrothermal synthesis of peony-like CuO micro/nanostructures for high-performance lithium-ion battery anodes[J]. Chinese Chemical Letters, ;2017, 28(12): 2263-2268. doi: 10.1016/j.cclet.2017.09.064 shu

Hydrothermal synthesis of peony-like CuO micro/nanostructures for high-performance lithium-ion battery anodes

Beijing Key Laboratory of Function Materials for Molecule & Structure Construction, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China

Corresponding author: Jia Xilai, jiaxl@ustb.edu.cn Wang Ge, gewang@mater.ustb.edu.cn
Received Date: 22 June 2017
Revised Date: 21 September 2017
Accepted Date: 25 September 2017
Available Online: 3 December 2017

Figures(6)

The peony-like CuO micro/nanostructures were fabricated by a facile hydrothermal approach. The peonylike CuO micro/nanostructures about 3-5 μm in diameter were assembled by CuO nanoplates. These CuO nanoplates, as the building block, were self-assembled into multilayer structures under the action of ethidene diamine, and then grew into uniform peony-like CuO architecture. The novel peony-like CuO micro/nanostructures exhibit a high cycling stability and improved rate capability. The peony-like CuO micro/nanostructures electrodes show a high reversible capacity of 456 mAh/g after 200 cycles, much higher than that of the commercial CuO nanocrystals at a current 0.1 C. The excellent electrochemical performance of peony-like CuO micro/nanostructures might be ascribed to the unique assembly structure, which not only provide large electrode/electrolyte contact area to accelerate the lithiation reaction, but also the interval between the multilayer structures of CuO nanoplates electrode could provide enough interior space to accommodate the volume change during Li⁺ insertion and de-insertion process.
- CuO micro/nanostructure,
- Self-assembly,
- Hydrothermal method,
- Hierarchical nanostructure,
- Lithium-ion battery
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