Citation: Meng Dan, Liang Hele, Chen Qingde, Shen Xinghai. Preparation and characterization of a novel single crystal of Th(Ⅳ) with cucurbit[6]uril[J]. Chinese Chemical Letters, ;2018, 29(3): 447-450. doi: 10.1016/j.cclet.2017.09.030 shu

Preparation and characterization of a novel single crystal of Th(Ⅳ) with cucurbit[6]uril

Beijing National Laboratory for Molecular Sciences(BNLMS), Fundamental Science on Radiochemistry and Radiation Chemistry Laboratory, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

Corresponding author: Shen Xinghai, xshen@pku.edu.cn
Received Date: 20 May 2017
Revised Date: 5 September 2017
Accepted Date: 12 September 2017
Available Online: 13 March 2017

Figures(3)

One single crystal based on Th⁴⁺ and cucurbit[6]uril (CB6) in nitric acid aqueous solutions was synthesized by slow evaporation method. The single crystal was characterized by elemental analysis, single crystal X-ray diffraction, XRD, FT-IR and TGA. The complexed cation of Th⁴⁺ is a ten coordinated structure, in which the central thorium ion is coordinated by six monodentate water molecules and two bidentate nitrates. While CB6, as a second-sphere ligand, coordinates with the water molecules of[Th (NO₃)₂(H₂O)₆]²⁺ through the formation of hydrogen bonding. Two other nitrate ions act as the counter anions. Besides, there are two free water molecules in the crystal system. The formation of the Th⁴⁺-CB6 complex can contribute to the study of the coordination of CB6 and the extraction of Th⁴⁺ in HNO₃ system
- Cucurbituril,
- Thorium,
- Single crystal,
- Coordination
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