Citation: Wang Wen-He, Gao Qiang, Li Ai-Lin, Jia Yan-Yuan, Zhang Shi-Yu, Wang Jian-Hong, Zhang Ying-Hui, Bu Xian-He. A coordination compound featuring a supramolecular hydrogen-bonding network for proton conduction[J]. Chinese Chemical Letters, ;2018, 29(2): 336-338. doi: 10.1016/j.cclet.2017.08.033 shu

A coordination compound featuring a supramolecular hydrogen-bonding network for proton conduction

a.
Department of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Nankai University, Tianjin 300071, China
b.
School of Materials Science and Engineering, TKL of Metal-and Molecule-Based Material Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: Zhang Ying-Hui, zhangyhi@nankai.edu.cn Bu Xian-He, buxh@nankai.edu.cn
Received Date: 14 June 2017
Revised Date: 11 August 2017
Accepted Date: 15 August 2017
Available Online: 3 March 2017

Figures(3)

A new coordination compound[Mg(L)(H₂O)₅·H₂O] (NKU-109, H₂L=5-(4H-1, 2, 4-triazol-4-yl)benzene-1, 3-dicarboxylic acid) was solvothermally synthesized, featuring a supramolecular hydrogen-bonding network. A good proton conductivity of 5.87×10^-4 S/cm was recorded at 70℃ and a relative humidity of 75% in alternating current (AC) impedance experiment, which sheds a new light on the design of proton conduction materials based on coordination compounds.
- Coordination compound,
- Fuel cell,
- Hydrogen-bonding network,
- Supramolecular,
- Proton conductivity
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1.
沈阳化工大学材料科学与工程学院沈阳 110142