Citation: Yuan Jinkai. Percolation of carbon nanomaterials for high-k polymer nanocomposites[J]. Chinese Chemical Letters, ;2017, 28(11): 2036-2044. doi: 10.1016/j.cclet.2017.08.020 shu

Percolation of carbon nanomaterials for high-k polymer nanocomposites

Yuan Jinkai ^,

Centre de Recherche Paul Pascal, CNRS, Université de Bordeaux, Pessac 33600, France

Author Bio: Jinkai Yuan received his B.S. (2006) and M.S. (2009) degrees in Materials Science from Beijing University of Chemical Technology, and subsequently obtained a Ph.D. degree in Materials Science from Ecole Centrale Paris in 2012 under supervision of Dr. Jinbo Bai. Before taking his tenured CNRS researcher position, he worked as a postdoctoral fellow from 2013 to 2015 with Dr. Philippe Poulin at Centre de Recherche Paul Pascal, CNRS, France. His research interests mainly focus on functional polymer nanocompositesfor the applications of actuators, sensors, and energy harvesters
Corresponding author: Yuan Jinkai, yuan@crpp-bordeaux.cnrs.fr
Received Date: 27 June 2017
Revised Date: 1 August 2017
Accepted Date: 3 August 2017
Available Online: 18 November 2017

Figures(11)

High-k polymer composite materials are next-generation dielectrics that show amazing applications in diverse electrical and electronic devices. Establishing near-percolated network of conducting filler in an insulating polymer matrix is a promising approach to develop flexible high-k dielectrics. However, challenges still exist today on fine controlling the network morphology to achieve extremely high k values and low losses simultaneously. The relationship between the network morphology and the dielectric properties of polymer composites is raising a number of fundamental questions. Herein, recent progress towards high-k polymer composites based on carbon nanomaterials is reviewed. Particular attention is paid on the influence of the network morphology on the dielectric properties. Some perspectives that warrant further investigation in the future are also addressed.
- Percolation,
- Carbon nanomaterials,
- Polymer composites,
- Dielectric constant,
- Permittivity
1. [1]
  Q. Chen, Y. Shen, S.H. Zhang, Q.M. Zhang, Annu. Rev. Mater. Res. 45(2015) 433-458. doi: 10.1146/annurev-matsci-070214-021017
2. [2]
  V.K. Prateek, R.K. Thakur Gupta, Chem. Rev. 116(2016) 4260-4317. doi: 10.1021/acs.chemrev.5b00495
3. [3]
  M. Lallart, P.J. Cottinet, D. Guyomar, L. Lebrun, J. Polym. Sci. Pol. Phys. 50(2012) 523-535.
4. [4]
  Z.H. Yao, Z. Song, H. Hao, et al., Adv. Mater. 29(2017) 1601727. doi: 10.1002/adma.v29.20
5. [5]
  E. Baer, L. Zhu, Macromolecules 50(2017) 2239-2256. doi: 10.1021/acs.macromol.6b02669
6. [6]
  A. Mannodi-Kanakkithodi, G.M. Treich, T.D. Huan, et al., Adv. Mater. 28(2016) 6277-6291. doi: 10.1002/adma.201600377
7. [7]
  B. Neese, B. Chu, S.G. Lu, et al., Science 321(2008) 821-823. doi: 10.1126/science.1159655
8. [8]
  Q. Li, G.Z. Zhang, X.S. Zhang, et al., Adv. Mater. 27(2015) 2236-2241. doi: 10.1002/adma.201405495
9. [9]
  Q.M. Zhang, H.F. Li, M. Poh, et al., Nature 419(2002) 284-287. doi: 10.1038/nature01021
10. [10]
  C. Park, J.H. Kang, J.S. Harrison, R.C. Costen, S.E. Lowther, Adv. Mater. 20(2008) 2074-2079. doi: 10.1002/(ISSN)1521-4095
11. [11]
  L.J. Romasanta, M.A. Lopez-Manchado, R. Verdejo, Prog. Polym. Sci. 51(2015) 188-211. doi: 10.1016/j.progpolymsci.2015.08.002
12. [12]
  C. Choi, J.M. Lee, S.H. Kim, et al., Nano Lett. 16(2016) 7677-7684. doi: 10.1021/acs.nanolett.6b03739
13. [13]
  W. Hu, X. Niu, R. Zhao, Q. Pei, Appl. Phys. Lett. 102(2013) 083303. doi: 10.1063/1.4794143
14. [14]
  D.J. Lipomi, M. Vosgueritchian, B.C.K. Tee, et al., Nature Nanotech. 6(2011) 788-792. doi: 10.1038/nnano.2011.184
15. [15]
  Z.M. Dang, J.K. Yuan, J.W. Zha, et al., Prog. Mater. Sci. 57(2012) 660-723. doi: 10.1016/j.pmatsci.2011.08.001
16. [16]
  T. Zhou, J.W. Zha, R.Y. Cui, et al., ACS Appl. Mater. Interfaces 3(2011) 2184-2188. doi: 10.1021/am200492q
17. [17]
  X. Huang, P. Jiang, Adv. Mater. 27(2015) 546-554. doi: 10.1002/adma.v27.3
18. [18]
  Z.M. Dang, J.K. Yuan, S.H. Yao, R.J. Liao, Adv. Mater. 25(2013) 6334-6365. doi: 10.1002/adma.v25.44
19. [19]
  Y. Shen, Y.H. Lin, Q.M. Zhang, MRS Bull. 40(2015) 753-759. doi: 10.1557/mrs.2015.199
20. [20]
  Y. Shen, D.S. Shen, X. Zhang, et al., J. Mater. Chem. A 4(2016) 8359-8365. doi: 10.1039/C6TA02186G
21. [21]
  Z.M. Dang, T. Zhou, S.H. Yao, et al., Adv. Mater. 21(2009) 2077-2082. doi: 10.1002/adma.v21:20
22. [22]
  Z. Dou, W. Liu, T. Lin, K. Zhou, L. Hang, Appl. Phys. Lett. 110(2017) 133902. doi: 10.1063/1.4979407
23. [23]
  G.Y. Wang, X.Y. Huang, P.K. Jiang, J. Mater. Chem. C 5(2017) 3112-3120. doi: 10.1039/C7TC00387K
24. [24]
  D. Zhang, X.F. Zhou, J. Roscow, et al., Sci. Rep. 7(2017) 45179. doi: 10.1038/srep45179
25. [25]
  H.A. Avila, L.A. Ramajo, M.S. Goes, et al., ACS Appl. Mater. Interfaces 5(2013) 505-510. doi: 10.1021/am302646z
26. [26]
  G.Y. Wang, X.Y. Huang, P.K. Jiang, ACS Appl. Mater. Interfaces 9(2017) 7547-7555. doi: 10.1021/acsami.6b14454
27. [27]
  P.H. Hu, Y. Shen, Y.H. Guan, et al., Adv. Funct. Mater. 24(2014) 3172-3178. doi: 10.1002/adfm.201303684
28. [28]
  P.H. Hu, Y. Song, H.Y. Liu, et al., J. Mater. Chem. A 1(2013) 1688-1693. doi: 10.1039/C2TA00948J
29. [29]
  Q. Li, L. Chen, M.R. Gadinski, et al., Nature 523(2015) 576-579. doi: 10.1038/nature14647
30. [30]
  F.H. Liu, Q. Li, J. Cui, et al., Adv. Funct. Mater. 27(2017) 1606292. doi: 10.1002/adfm.v27.20
31. [31]
  V. Tomer, E. Manias, C.A. Randall, J. Appl. Phys. 110(2011) 044107. doi: 10.1063/1.3609082
32. [32]
  S. Roy, P. Thakur, N.A. Hoque, B. Bagchi, S. Das, RSC Adv. 6(2016) 21881-21894. doi: 10.1039/C6RA00864J
33. [33]
  C.W. Nan, Prog. Mater. Sci. 37(1993) 1-116. doi: 10.1016/0079-6425(93)90004-5
34. [34]
  J.K. Yuan, S. Yao, W. Li, A. Sylvestre, J. Bai, J. Phys. Chem. C 118(2014) 22975-22983. doi: 10.1021/jp508206t
35. [35]
  J.K. Yuan, A. Luna, W. Neri, et al., Nat. Commun. 6(2015) 8700. doi: 10.1038/ncomms9700
36. [36]
  A.L. Efros, B.I. Shklovskii, Phys. Status Solidi B 76(1976) 475-485. doi: 10.1002/(ISSN)1521-3951
37. [37]
  A. Luna, M. Pruvost, J.K. Yuan, et al., Langmuir 33(2017) 4528-4536. doi: 10.1021/acs.langmuir.6b04185
38. [38]
  C.W. Nan, Y. Shen, J. Ma, Rev. Annu, Mater. Res. 40(2010) 131-151. doi: 10.1146/annurev-matsci-070909-104529
39. [39]
  A. Luna, J. Yuan, W. Neri, et al., Langmuir 31(2015) 12231-12239. doi: 10.1021/acs.langmuir.5b02318
40. [40]
  F. Carpi, D. De Rossi, R. Kornbluh, R. Pelrine, P. Sommer-Larsen, Dielectric Elastomers as Electromechanical Transducers, Elsevier, Amsterdam, 2008.
41. [41]
  Z.M. Dang, Y.H. Lin, C.W. Nan, Adv. Mater. 15(2003) 1625-1629. doi: 10.1002/(ISSN)1521-4095
42. [42]
  G. Kofod, S. Risse, H. Stoyanov, et al., ACS Nano 5(2011) 1623-1629. doi: 10.1021/nn103097q
43. [43]
  L.L. Sun, B. Li, Y. Zhao, G. Mitchell, W.H. Zhong, Nanotechnology 21(2010) 305702. doi: 10.1088/0957-4484/21/30/305702
44. [44]
  L. Wang, Z.M. Dang, Appl. Phys. Lett. 87(2005) 042903. doi: 10.1063/1.1996842
45. [45]
  J.K. Yuan, W.L. Li, S.H. Yao, et al., Appl. Phys. Lett. 98(2011) 032901. doi: 10.1063/1.3544942
46. [46]
  F. He, S. Lau, H.L. Chan, J.T. Fan, Adv. Mater. 21(2009) 710-715. doi: 10.1002/adma.v21:6
47. [47]
  N. Yousefi, X. Sun, X. Lin, et al., Adv. Mater. 26(2014) 5480-5487. doi: 10.1002/adma.201305293
48. [48]
  W. Ding, A. Eitan, F.T. Fisher, et al., Nano Lett. 3(2003) 1593-1597. doi: 10.1021/nl0345973
49. [49]
  Z.M. Dang, M.S. Zheng, J.W. Zha, Small 12(2016) 1688-1701. doi: 10.1002/smll.v12.13
50. [50]
  Q. Chen, P.Y. Du, L. Jin, W.J. Weng, G.R. Han, Appl. Phys. Lett. 91(2007) 022912. doi: 10.1063/1.2757131
51. [51]
  G. Chen, J. Lu, D. Wu, Mater. Chem. Phys. 104(2007) 240-243. doi: 10.1016/j.matchemphys.2007.01.011
52. [52]
  X. Gao, S. Zhang, F. Mai, et al., J. Mater. Chem. 21(2011) 6401-6408. doi: 10.1039/c0jm04543h
53. [53]
  M. Panda, V. Srinivas, A.K. Thakur, Appl. Phys. Lett. 93(2008) 242908. doi: 10.1063/1.3054163
54. [54]
  S.H. Yao, Z.M. Dang, M.J. Jiang, H.P. Xu, J.B. Bai, Appl. Phys. Lett. 91(2007) 212901. doi: 10.1063/1.2817746
55. [55]
  W. Li, J. Yuan, Y. Lin, et al., Carbon 51(2013) 355-364. doi: 10.1016/j.carbon.2012.08.064
56. [56]
  Z.M. Dang, L. Wang, Y. Yin, Q. Zhang, Q.Q. Lei, Adv. Mater. 19(2007) 852-857. doi: 10.1002/(ISSN)1521-4095
57. [57]
  J.K. Yuan, S.H. Yao, Z.M. Dang, et al., J. Phys. Chem. C 115(2011) 5515-5521. doi: 10.1021/jp1117163
58. [58]
  C. Wu, X. Huang, L. Xie, J. Yu, P. Jiang, J. Mater. Chem. 21(2011) 17729-17736. doi: 10.1039/c1jm12903a
59. [59]
  Z.N. Zhang, J. Zhang, P. Chen, et al., Carbon 44(2006) 692-698. doi: 10.1016/j.carbon.2005.09.027
60. [60]
  T. Zhou, J.W. Zha, Y. Hou, et al., ACS Appl. Mater. Interfaces 3(2011) 4557-4560. doi: 10.1021/am201454e
61. [61]
  C. Wu, X. Huang, X. Wu, et al., Compos. Sci. Technol. 72(2012) 521-527. doi: 10.1016/j.compscitech.2011.12.014
62. [62]
  S. Zhang, H. Wang, G. Wang, Z. Jiang, Appl. Phys. Lett. 101(2012) 012904. doi: 10.1063/1.4733723
63. [63]
  H. Liu, Y. Shen, Y. Song, et al., Adv. Mater. 23(2011) 5104-5108. doi: 10.1002/adma.201102079
64. [64]
  Z. Chen, L.Y. Xie, X.Y. Huang, S.T. Li, P.K. Jiang, Carbon 95(2015) 895-903. doi: 10.1016/j.carbon.2015.09.020
65. [65]
  J.K. Yuan, S. Yao, W. Li, A. Sylvestre, J. Bai, J. Phys. Chem. C 121(2017) 12063-12070. doi: 10.1021/acs.jpcc.7b03372
66. [66]
  A. Dichiara, J.K. Yuan, S.H. Yao, A. Sylvestre, J. Bai, J. Nanosci. Nanotechnol. 12(2012) 6935-6940. doi: 10.1166/jnn.2012.6573
67. [67]
  H. Zhao, M.H. Yang, D.L. He, J.B. Bai, J. Mater. Chem. C 4(2016) 8911-8919. doi: 10.1039/C6TC02386J
68. [68]
  J.K. Yuan, S.H. Yao, A. Sylvestre, J. Bai, J. Phys. Chem. C 116(2012) 2051-2058. doi: 10.1021/jp210872w
69. [69]
  X.D. Zhao, J. Zhao, J.P. Cao, et al., Mater. Des. 56(2014) 807-815. doi: 10.1016/j.matdes.2013.11.073
70. [70]
  X.D. Zhao, J.P. Cao, J. Zhao, G.H. Hu, Z.M. Dang, J. Mater. Chem. A 2(2014) 10614-10622. doi: 10.1039/c4ta01214c
71. [71]
  J.P. Cao, J. Zhao, X.D. Zhao, et al., Compos. Sci. Technol. 89(2013) 142-148. doi: 10.1016/j.compscitech.2013.09.024
72. [72]
  X.D. Zhao, J. Zhao, J.P. Cao, et al., J. Phys. Chem. B 117(2013) 2505-2515. doi: 10.1021/jp310021r
73. [73]
  H. Pang, L. Xu, D.X. Yan, Z.M. Li, Prog. Poly. Sci. 39(2014) 1908-1933. doi: 10.1016/j.progpolymsci.2014.07.007
74. [74]
  N. George, P.K. Bipinbal, B. Bhadran, A. Mathiazhagan, R. Joseph, Polymer 112(2017) 264-277. doi: 10.1016/j.polymer.2017.01.082
75. [75]
  J.C. Grunlan, A.R. Mehrabi, M.V. Bannon, J.L. Bahr, Adv. Mater. 16(2004) 150-153. doi: 10.1002/(ISSN)1521-4095
76. [76]
  E. Charlaix, J. Phys. A:Math Gen. 19(1986) L533-L536. doi: 10.1088/0305-4470/19/9/013
77. [77]
  S. Naficy, R. Jalili, S.H. Aboutalebi, et al., Mater. Horiz. 1(2014) 326-331. doi: 10.1039/C3MH00144J
78. [78]
  M. Mathew, T. Schilling, M. Oettel, Phys. Rev. E 85(2012) 061407. doi: 10.1103/PhysRevE.85.061407
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