Citation: Zhang Qianfeng, Chang Guanjun, Zhang Lin. Synthesis and properties of novel heat-resistant fluorescent conjugated polymers with bisindolylmaleimide[J]. Chinese Chemical Letters, ;2018, 29(3): 513-516. doi: 10.1016/j.cclet.2017.08.019 shu

Synthesis and properties of novel heat-resistant fluorescent conjugated polymers with bisindolylmaleimide

a.
Research Center of Laser Fusion CAEP, China Academy of Engineering Physics, Mianyang 621900, China
b.
State Key Laboratory Cultivation Base for Nonmetal Composite and Functional Materials & School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, China

Corresponding author: Zhang Lin, zhlmy@sina.com
Received Date: 1 April 2017
Revised Date: 8 August 2017
Accepted Date: 13 August 2017
Available Online: 18 March 2017

Figures(4)

Conjugated polymers with bisindolylmaleimide (BIM) backbone are obtained by the condensation polymerization of methyl and octanyl N-substituted BIMs with 4, 4'-difluoro-diphenylsulfone and 4, 4'-difluoro-diphenylketone. The structures of polymers are confirmed by FTIR and NMR spectroscopy. The polymers exhibit both high glass transition temperatures (T_g > 175℃) and high decomposition temperatures (T₅ > 395℃). Meanwhile, The UV-vis absorption and fluorescence spectra of the polymers are similar to the corresponding substituted BIMs. The quantum chemistry calculations indicate that the first excited states of polymers are mostly contributed by BIM structures.
- Bisindolylmaleimide,
- Heat-resistant polymer,
- Photoluminescence,
- DFT calculations
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1.
沈阳化工大学材料科学与工程学院沈阳 110142