Citation: Zhang Tianyun, Lang Junwei, Liu Li, Liu Lingyang, Li Hongxia, Gu Yipeng, Yan Xingbin, Ding Xin. Effect of carboxylic acid groups on the supercapacitive performance of functional carbon frameworks derived from bacterial cellulose[J]. Chinese Chemical Letters, ;2017, 28(12): 2212-2218. doi: 10.1016/j.cclet.2017.08.013 shu

Effect of carboxylic acid groups on the supercapacitive performance of functional carbon frameworks derived from bacterial cellulose

Zhang Tianyun ^a,b,c ,
Lang Junwei ^c ,
Liu Li ^c ,
Liu Lingyang ^c ,
Li Hongxia ^c ,
Gu Yipeng ^c ,
Yan Xingbin ^c ,
Ding Xin ^a,,

a.
College of Textiles, Donghua University, Shanghai 201620, China
b.
School of Mechanical and Electronical Engineering, Lanzhou University of Technology, Lanzhou 730050, China
c.
Laboratory of Clean Energy Chemistry and Materials, State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

Corresponding author: Ding Xin, xding@dhu.edu.cn
Received Date: 2 May 2017
Revised Date: 27 July 2017
Accepted Date: 13 August 2017
Available Online: 18 December 2017

Figures(6)

Three-dimensional (3D) carbonaceous materials derived from bacterial cellulose (BC) has been introduced as electrode for supercapacitors in recent. Here, we report a simple strategy for the synthesis of functional carbon frameworks through 2, 2, 6, 6-tetramethylpilperidine l-oxyl radical (TEMPO) mediated oxidation of bacterial cellulose (BC) followed by carbonization. TEMPO-mediated oxidation can efficiently convert the hydroxyls on the surface of BC to carboxylate groups to improve electrochemical activity. Because of its high porosity, good hydrophilicity, rich oxygen groups, and continuous ion transport in-between sheet-like porous network, the TEMPO-oxidized BC delivers a much higher gravimetric capacitance (137.3 F/g) at low annealing temperature of 500℃ than that of pyrolysis BC (31 F/g) at the same annealing temperature. The pyrolysis modified BC obtained at 900℃ shows specific capacitance (160.2 F/g), large current stability and long-term stability (84.2% of its initial capacitance retention after 10, 000 cycles).
- Bacterial cellulose,
- Carboxylic acid groups,
- TEMPO-meditated oxidation,
- Pseudocapacitance,
- Supercapacitor,
- Rate capability
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1.
沈阳化工大学材料科学与工程学院沈阳 110142