Citation: Ullah Fateh, Qian Sun, Yang Weitao, Shah Muhammad Naeem, Zhang Zhongqiang, Chen Hongzheng, Li Chang-Zhi. Donor-acceptor (D-A) terpolymers based on alkyl-DPP and t-BocDPP moieties for polymer solar cells[J]. Chinese Chemical Letters, ;2017, 28(12): 2223-2226. doi: 10.1016/j.cclet.2017.08.009 shu

Donor-acceptor (D-A) terpolymers based on alkyl-DPP and t-BocDPP moieties for polymer solar cells

MOE Key Laboratory of Macromolecular Synthesis and Functionalization, State Key Laboratory of Silicon Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: Li Chang-Zhi, czli@zju.edu.cn
Received Date: 25 April 2017
Revised Date: 3 August 2017
Accepted Date: 4 August 2017
Available Online: 8 December 2017

Figures(5)

A series of low band gap terpolymers based on 4, 8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1, 2-b:4, 5-b']dithiophene (BDTT) and diketopyrrolopyrrole (DPP) with varied solubilizing groups (i.e., tert-butoxycarbonyl, t-Boc and 2-octyldodecyl) are developed as electron donors for bulk heterojunction (BHJ) polymer solar cells (PSCs). The results reveal that the one with 50% t-Boc concentration (P3) performs better than the other terpolymers used in this study in conventional PSC devices with a power conversion efficiency of 2.92%
- Conjugated polymer,
- Organic semiconductor,
- Polymer solar cells,
- Bulk heterojunction,
- Diketopyrrolopyrrole
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