Citation: Guo Yiting, Zhang Andong, Li Cheng, Li Weiwei, Zhu Daoben. A near-infrared porphyrin-based electron acceptor for non-fullerene organic solar cells[J]. Chinese Chemical Letters, ;2018, 29(3): 371-373. doi: 10.1016/j.cclet.2017.08.006 shu

A near-infrared porphyrin-based electron acceptor for non-fullerene organic solar cells

Guo Yiting ^a,b ,
Zhang Andong ^a,b ,
Li Cheng ^a,, ,
Li Weiwei ^a,, ,
Zhu Daoben ^a

a.
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Li Cheng, licheng1987@iccas.ac.cn Li Weiwei, liweiwei@iccas.ac.cn
Received Date: 11 June 2017
Revised Date: 7 July 2017
Accepted Date: 3 August 2017
Available Online: 12 March 2017

Figures(5)

In this work, a new star-shaped electron acceptor based on porphyrin as core, rhodanine and benzothiadiazole as end groups, was developed for non-fullerene solar cells. The molecule shows three distinct absorption regions due to the Soret and Q-bands of the porphyrin and the intramolecular charge transfer in the molecule. This molecule as electron acceptor was applied into non-fullerene solar cells by using a diketopyrrolopyrrole-based conjugated polymer as electron donor. An initial PCE of 1.9% was achieved with a broad photo-response from 300-850 nm. The results demonstrate that porphyrin can be used to design near-infrared electron acceptors for organic solar cells.
- Electron Acceptor,
- Non-fullerene organic solar cells,
- Porphyrin,
- Diketopyrrolopyrrole,
- Near-infrared
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