Citation: Wua Hongwei, Wu Bin, Yu Xiyuan, Zhao Pei, Chen Wenbo, Zhu Liangliang. Self-twisting for macrochirality from an achiral asterisk molecule with fluorescence-phosphorescence dual emission[J]. Chinese Chemical Letters, ;2017, 28(11): 2151-2154. doi: 10.1016/j.cclet.2017.08.002 shu

Self-twisting for macrochirality from an achiral asterisk molecule with fluorescence-phosphorescence dual emission

Wua Hongwei ^a,b ,
Wu Bin ^a ,
Yu Xiyuan ^a ,
Zhao Pei ^a ,
Chen Wenbo ^c ,
Zhu Liangliang ^a,,

a.
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200433, China
b.
Shanghai Key Lab of Polymer and Electrical Insulation, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
c.
Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power, Shanghai University of Electric Power, Shanghai 200090, China

Corresponding author: Zhu Liangliang, zhuliangliang@fudan.edu.cn
Received Date: 31 May 2017
Revised Date: 21 June 2017
Accepted Date: 2 August 2017
Available Online: 5 November 2017

Figures(4)

Understanding of the role of supramolecular chirality for tuning material optoelectronic properties has been restricted by the limited number of cases. A particular challenge is to impose supramolecular chirality onto multicolor luminescent systems that can emit in aggregation state. Here we present a selfassembly strategy from a well-selected asterisk molecule for generating supramolecular chirality with fluorescence-phosphorescence dual emission. The work takes advantages of (1) achiral chemical structure dependent peculiar self-assembly that can spontaneously undergo symmetry breaking to produce macrochirality, and (2) the assembly process can be monitored by time which due to the crystallization-driven self-assembly by self-twisting, allowing a self-progressing chiral amplification. A multicolor luminescence induced by the fluorescence-phosphorescence dual emission along with such a self-assembly behavior was also observed at a single solution system versus the time. The self-twisting chiral self-assembly fashion provides new prospects for understanding the establishment of nanochirality from achiral molecular building blocks.
- Achiral molecules self-twisting,
- Macrochirality,
- Fluorescence-phosphorescence,
- Dual emission
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