Citation: Alduhaish Osamah, Li Bin, Arman Hadi, Lin Rui-Biao, Zhao John Cong-Gui, Chen Banglin. A two-dimensional microporous metal-organic framework for highly selective adsorption of carbon dioxide and acetylene[J]. Chinese Chemical Letters, ;2017, 28(8): 1653-1658. doi: 10.1016/j.cclet.2017.04.025 shu

A two-dimensional microporous metal-organic framework for highly selective adsorption of carbon dioxide and acetylene

Department of Chemistry, University of Texas at San Antonio, San Antonio, TX 78249-0698, USA

Corresponding author: Lin Rui-Biao, ruibiao.lin@utsa.edu Chen Banglin, banglin.chen@utsa.edu
Received Date: 28 February 2017
Revised Date: 2 April 2017
Accepted Date: 12 April 2017
Available Online: 27 August 2017

Figures(5)

Solvothermal reaction of 3-aminoisonicotinic acid (Haina) and Cu(NO₃)₂·2.5H₂O gave a novel twodimensional (2D) microporous metal-organic framework, [Cu(aina)₂(DMF)]·DMF (1, DMF=N, N-dimethylformamide). Single-crystal X-ray crystallographic study of compound 1 revealed that Cu(Ⅱ) ions are linked by aina^- ligands forming square grid-like layers, which stack together via multiple hydrogen bonding interactions. The solvent-free framework of 1a displayed considerable porosity (void=46.5%) with one-dimensional (1D) open channels (4.7 Å×4.8 Å) functionalized by amino groups. Gas sorption measurements of 1 revealed selective carbon dioxide (CO₂) and acetylene (C₂H₂) adsorption over methane (CH₄) and nitrogen (N₂) at ambient temperature.
- Metal-organic frameworks,
- Two-dimensional structure,
- 3-Aminoisonicotinic acid,
- Hydrogen bonding,
- Gas separation,
- Acetylene
1. [1]
  (a) K. Z. House, A. C. Baclig, M. Ranjan, et al. , Economic and energetic analysis of capturing CO₂ from ambient air, Proc. Natl. Acad. Sci. U. S. A. 108(2011) 20428-20433;
  (b) K. S. Lackner, S. Brennan, J. M. Matter, et al. , The urgency of the development of CO₂ capture from ambient air, Proc. Natl. Acad. Sci. U. S. A. 109(2012) 13156-13162.
2. [2]
  (a) D. M. D’Alessandro, B. Smit, J. R. Long, Carbon dioxide capture: prospects for new materials, Angew. Chem. Int. Ed. 49(2010) 6058-6082;
  (b) E. S. Sanz-Pérez, C. R. Murdock, S. A. Didas, C. W. Jones, Direct capture of CO₂ from ambient air, Chem. Rev. 116(2016) 11840-11876.
3. [3]
  (a) C. A. Scholes, G. W. Stevens, S. E. Kentish, Membrane gas separation applications in natural gas processing, Fuel 96(2012) 15-28;
  (b) M. Tagliabue, D. Farrusseng, S. Valencia, et al. , Natural gas treating by selective adsorption: material science and chemical engineering interplay, Chem. Eng. J. 155(2009) 553-566;
  (c) S. Cavenati, C. A. Grande, A. E. Rodrigues, Adsorption equilibrium of methane, carbon dioxide, and nitrogen on zeolite 13X at high pressures, J. Chem. Eng. Data 49(2004) 1095-1101.
4. [4]
  (a) Y. He, R. Krishna, B. Chen, Metal-organic frameworks with potential for energy-efficient adsorptive separation of light hydrocarbons, Energy Environ. Sci. 5(2012) 9107-9120;
  (b) F. Luo, C. Yan, L. Dang, et al. , UTSA-74: a MOF-74 isomer with two accessible binding sites per metal center for highly selective gas separation, J. Am. Chem. Soc. 138(2016) 5678-5684.
5. [5]
  (a) H. -C. Zhou, S. Kitagawa, Metal-organic frameworks (MOFs), Chem. Soc. Rev. 43(2014) 5415-5418;
  (b) Y. Cui, B. Li, H. He, et al. , Metal-organic frameworks as platforms for functional materials, Acc. Chem. Res. 49(2016) 483-493;
  (c) P. Silva, S. M. F. Vilela, J. P. C. Tome, F. A. Almeida Paz, Multifunctional metal-organic frameworks: from academia to industrial applications, Chem. Soc. Rev. 44(2015) 6774-6803;
  (d) H. Furukawa, K. E. Cordova, M. O'Keeffe, O. M. Yaghi, The chemistry and applications of metal-organic frameworks, Science 641(2010) 1230444.
6. [6]
  (a) T. R. Cook, Y. R. Zheng, P. J. Stang, Metal-organic frameworks and selfassembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials, Chem. Rev. 113(2013) 734-777;
  (b) C. Wang, D. M. Liu, W. B. Lin, Metal-organic frameworks as a tunable platform for designing functional molecular materials, J. Am. Chem. Soc. 135(2013) 13222-13234;
  (c) Y. He, B. Li, M. O'Keeffe, B. Chen, Multifunctional metal-organic frameworks constructed from meta-benzenedicarboxylate units, Chem. Soc. Rev. 43(2014) 5618-5656;
  (d) C. Wang, T. Zhang, W. Lin, Rational synthesis of noncentrosymmetric metal-organic frameworks for second-order nonlinear optics, Chem. Rev. 112(2012) 1084-1104.
7. [7]
  (a) K. Sumida, D. L. Rogow, J. A. Mason, et al. , Carbon dioxide capture in metal-organic frameworks, Chem. Rev. 112(2012) 724-781;
  (b) H. Wu, Q. Gong, D. H. Olson, J. Li, Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks, Chem. Rev. 112(2012) 836-868;
  (c) M. P. Suh, H. J. Park, T. K. Prasad, D. -W. Lim, Hydrogen storage in metal-organic frameworks, Chem. Rev. 112(2012) 782-835;
  (d) Y. He, W. Zhou, G. Qian, B. Chen, Methane storage in metal-organic frameworks, Chem. Soc. Rev. 43(2014) 5657-5678.
8. [8]
  (a) Z. Zhang, Z. Yao, S. Xiang, B. Chen, Perspective of microporous metal-organic frameworks for CO₂ capture and separation, Energy Environ. Sci. 7(2014) 2868-2899;
  (b) Z. Bao, G. Chang, H. Xing, et al. , Potential of microporous metal-organic frameworks for separation of hydrocarbon mixtures, Energy Environ. Sci. 9(2016) 3612-3641;
  (c) B. Li, H. Wang, B. Chen, Microporous metal-organic frameworks for gas separation, Chem. -Asian J. 9(2014) 1474-1498;
  (d) J. R. Li, J. Sculley, H. C. Zhou, Metal-organic frameworks for separations, Chem. Rev. 112(2012) 869-932.
9. [9]
  (a) Z. Hu, W. P. Lustig, J. Zhang, et al. , Effective detection of mycotoxins by a highly luminescent metal-organic framework, J. Am. Chem. Soc. 137(2015) 16209-16215;
  (b) L. E. Kreno, K. Leong, O. K. Farha, et al. , Metal-organic framework materials as chemical sensors, Chem. Rev. 112(2012) 1105-1125;
  (c) Y. Cui, Y. Yue, G. Qian, B. Chen, Luminescent functional metal-organic frameworks, Chem. Rev. 112(2012) 1126-1162;
  (d) Z. Hu, B. J. Deibert, J. Li, Luminescent metal-organic frameworks for chemical sensing and explosive detection, Chem. Soc. Rev. 43(2014) 5815-5840.
10. [10]
  (a) M. Zhao, S. Ou, C. De Wu, Porous metal-organic frameworks for heterogeneous biomimetic catalysis, Acc. Chem. Res. 47(2014) 1199-1207;
  (b) G. Huang, Y. Chen, H. Jiang, Metal-organic frameworks for catalysis, Acta Chim. Sin. 74(2016) 113-129;
  (c) J. W. Ding, R. Wang, A new green system of HPW@MOFs catalyzed desulfurization using O₂ as oxidant, Chin. Chem. Lett. 27(2016) 655-658;
  (d) P. Li, S. Regati, H. -C. Huang, et al. , A sulfonate-based Cu(Ⅰ) metal-organic framework as a highly efficient and reusable catalyst for the synthesis of propargylamines under solvent-free conditions, Chin. Chem. Lett. 26(2015) 6-10;
  (e) Y. -Z. Chen, Z. U. Wang, H. Wang, et al. , Singlet oxygen-engaged selective photo-oxidation over Pt nanocrystals/porphyrinic MOF: the roles of photothermal effect and Pt electronic state, J. Am. Chem. Soc. 139(2017) 2035-2044.
11. [11]
  (a) K. Lu, C. He, W. Lin, Nanoscale metal-organic framework for highly effective photodynamic therapy of resistant head and neck cancer, J. Am. Chem. Soc. 136(2014) 16712-16715;
  (b) C. He, D. Liu, W. Lin, Nanomedicine applications of hybrid nanomaterials built from metal-ligand coordination bonds: nanoscale metal-organic frameworks and nanoscale coordination polymers, Chem. Rev. 115(2015) 11079-11108;
  (c) A. C. McKinlay, R. E. Morris, P. Horcajada, et al. , BioMOFs: metal-organic frameworks for biological and medical applications, Angew. Chem. Int. Ed. 49(2010) 6260-6266.
12. [12]
  (a) X. Cui, K. Chen, H. Xing, et al. , Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene, Science 353(2016) 141-144;
  (b) T. -L. Hu, H. Wang, B. Li, et al. , Microporous metal-organic framework with dual functionalities for highly efficient removal of acetylene from ethylene/acetylene mixtures, Nat. Commun. 6(2015) 7328.
13. [13]
  (a) S. Xiang, W. Zhou, J. M. Gallegos, Y. Liu, B. Chen, Exceptionally high acetylene uptake in a microporous metal-organic framework with open metal sites, J. Am. Chem. Soc. 131(2009) 12415-12419;
  (b) Q. Min Wang, D. Shen, M. Bulow, et al. , Metallo-organic molecular sieve for gas separation and purification, Micropor. Mesopor. Mater. 55(2002) 217-230.
14. [14]
  Llewellyn P.L., Bourrelly S., Serre C.. High uptakes of CO₂ and CH₄ in mesoporous metal-organic framework MIL-100 and MIL-101[J]. Langmuir, 2008:7245-7250.
15. [15]
  (a) L. Bastin, P. S. Ba, E. J. Hurtado, et al. , A microporous metal-organic framework for separation of CO₂/N₂ and CO₂/CH₄ by fixed-bed adsorption, J. Phys. Chem. C 112(2008) 1575-1581;
  (b) R. -B. Lin, F. Li, S. Y. Liu, et al. , A noble-metal-free porous coordinationframework with exceptional sensing efficiency for oxygen, Angew. Chem. Int. Ed. 52(2013) 13429-13433.
16. [16]
  Chen Z., Xiang S., Arman H.D.. A microporous metal-organic framework with immobilized OH functional groups within the pore surfaces for selective gas sorption[J]. Eur. J. Inorg. Chem, 2010:3745-3749.
17. [17]
  Lin R.-B., Chen D., Lin Y., Zhang J., Chen X.. A zeolite-like zinc triazolate framework with high gas adsorption and separation performance[J]. Inorg. Chem., 2012,51:9950-9955. doi: 10.1021/ic301463z
18. [18]
  Sheldrick G.M.. SHELXT-integrated space-group and crystal-structure determination[J]. Acta Crystallogr. Sect. A Found. Adv., 2015,71:3-8.
19. [19]
  CrystalClear-SM Expert 2. 0 r15, Rigaku Americas Co. , The Woodlands, Texas, USA, 2011.
20. [20]
  ABSCOR, Higashi, Rigaku Corporation, Tokyo, Japan, 1995.
21. [21]
  Myers A.L., Prausnitz J.M.. Thermodynamics of mixed-gas adsorption[J]. AIChE J., 1965,11:121-127. doi: 10.1002/(ISSN)1547-5905
22. [22]
  (a) D. Banerjee, Z. Zhang, A. M. Plonka, J. Li, J. B. Parise, A calcium coordination framework having permanent porosity and high CO₂/N₂ selectivity, Cryst. Growth Des. 12(2012) 2162-2165;
  (b) Y. Li, Z. Ju, B. Wu, D. Yuan, A water and thermally stable metal-organic framework featuring selective CO₂ adsorption, Cryst. Growth Des. 14(2013) 4125-4130.
23. [23]
  Serre C., Mellot-Draznieks C., Surbl S.. Role of solvent-host interactions that lead to very large swelling of hybrid frameworks[J]. Science, 2007,315:1828-1831. doi: 10.1126/science.1137975
24. [24]
  Xu H., He Y., Zhang Z.. A microporous metal-organic framework with both open metal and Lewis basic pyridyl sites for highly selective C₂H₂/CH₄ and C₂H₂/CO₂ gas separation at room temperature[J]. J. Mater. Chem. A, 2013,1:77-81. doi: 10.1039/C2TA00155A
25. [25]
  Alduhaish O., Wang H., Li B.. A threefold interpenetrated pillared-layer metal-organic framework for selective separation of C₂H₂/CH₄ and CO₂/CH₄[J]. ChemPlusChem, 2016,81:764-769. doi: 10.1002/cplu.201600088
26. [26]
  Li J.-R., Yu J., Lu W.. Porous materials with pre-designed single-molecule traps for CO₂ selective adsorption[J]. Nat. Commun, 2013,41538. doi: 10.1038/ncomms2552
27. [27]
  Xiang S., He Y., Zhang Z.. Microporous metal-organic framework with potential for carbon dioxide capture at ambient conditions[J]. Nat. Commun, 2012,3954. doi: 10.1038/ncomms1956
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