Citation: Cheng Ying-Zhi, Sun Xiu-Yu, Xiao Xiao-Ling, Liu Xiang-Feng, Xue Li, Hu Zhong-Bo. Effects of doping Fe cations on crystal structure and thermal expansion property of Yb₂Mo₃O₁₂[J]. Chinese Chemical Letters, ;2017, 28(7): 1600-1606. doi: 10.1016/j.cclet.2017.03.002 shu

Effects of doping Fe cations on crystal structure and thermal expansion property of Yb₂Mo₃O₁₂

a.
School of Chemical Engineering, Shandong University of Technology, Zibo 255049, China
b.
College of Materials Science and Opto-Electronic Technology, University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Xue Li, lixue@sdut.edu.cn; xuelisdut@163.com Hu Zhong-Bo, huzq@ucas.ac.cn
Received Date: 7 December 2016
Revised Date: 24 January 2017
Accepted Date: 2 March 2017
Available Online: 4 July 2017

Figures(8)

Crystal structures and thermal expansion properties of Yb_2-xFe_xMo₃O₁₂ (x=0.0, 0.6, 1.0, 1.1, 1.4) solid solutions have been studied by X-ray powder diffraction (XRPD) at different temperatures. Rietveld analysis of the XRPD data shows that Yb_2-xFe_xMo₃O₁₂ solid solutions adopt orthorhombic structure and have variable thermal expansion coefficients controlled by the ratio of Yb³⁺ to Fe³⁺. Yb₂Mo₃O₁₂ shows anisotropic negative thermal expansion property, induced by the reductions in average Yb-O-Mo angle and average apparent Mo2-O bond length with increasing temperatures. As more Yb³⁺ substituted by Fe³⁺, the linear thermal expansion coefficients of Yb_2-xFe_xMo₃O₁₂ increase from negative to positive. A near-zero thermal expansion coefficient of 0.55×10^-6 K^-1 for Yb_0.6Fe_1.4Mo₃O₁₂ is observed in the temperature range of 573-873 K.
- Negative thermal expansion,
- Crystal structure,
- X-ray diffraction,
- Rietveld method,
- Molybdate
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effects of doping Fe cations on crystal structure and thermal expansion property of Yb2Mo3O12

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通讯作者: 陈斌, bchen63@163.com

Effects of doping Fe cations on crystal structure and thermal expansion property of Yb₂Mo₃O₁₂