Citation: Yu Song-Bai, Zang Hong-Jun, Yang Xiao-Li, Zhang Ming-Chuan, Xie Rui-Rui, Yu Pei-Fei. Highly efficient preparation of 5-hydroxymethylfurfural from sucrose using ionic liquids and heteropolyacid catalysts in dimethyl sulfoxide-water mixed solvent[J]. Chinese Chemical Letters, ;2017, 28(7): 1479-1484. doi: 10.1016/j.cclet.2017.02.016 shu

Highly efficient preparation of 5-hydroxymethylfurfural from sucrose using ionic liquids and heteropolyacid catalysts in dimethyl sulfoxide-water mixed solvent

State Key Laboratory of Hollow Fiber Membrane Materials and Processes, Department of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, China

Corresponding author: Zang Hong-Jun, zanghongjun@tjpu.edu.cn
Received Date: 4 November 2016
Revised Date: 20 February 2017
Accepted Date: 28 February 2017
Available Online: 2 July 2017

Figures(4)

Several types of ILs and solid acids were used as catalysts in one-pot conversion of sucrose to 5-hydroxymethylfurfural (abbreviated as 5-HMF) in a dimethyl sulfoxide (DMSO)/water mixed solvent under hydrothermal conditions. A remarkable 5-HMF yield of 91.8% was achieved catalyzed by the cesium salt of dodecatungstophosphoric acid (Cs_2.3H_0.7PW₁₂O₄₀) within 3 h at 180 ℃. The ionic liquid N-methylimidazolium hydrogen sulfate ([Hmim][HSO₄]) gave the 5-HMF in 82.0% yield from sucrose. To the best of our knowledge, it was almost the highest yield of HMF from sucrose by now. Various reaction parameters including reaction temperature and time and catalyst dosage were optimized. A possible mechanism for this catalytic process was proposed. Furthermore, fructose and glucose were also investigated, good yields of 5-HMF was obtained respectively. This increases the possibility of large-scale production of 5-HMF from carbohydrates.
- 5-Hydroxymethylfurfural,
- Sucrose,
- Hydrothermal conversion,
- Ionic liquid,
- Solid acid
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