Citation: Wang Qi, Cheng Ming, Jiang Ju-Li, Wang Le-Yong. Modulating the properties of quadruple hydrogen bonded supramolecular polymers by photo-cross-linking between the coumarin moieties[J]. Chinese Chemical Letters, ;2017, 28(4): 793-797. doi: 10.1016/j.cclet.2017.02.008 shu

Modulating the properties of quadruple hydrogen bonded supramolecular polymers by photo-cross-linking between the coumarin moieties

Wang Qi ^a,b,, ,
Cheng Ming ^b ,
Jiang Ju-Li ^b,c,, ,
Wang Le-Yong ^b,c

a.
Key Laboratory for Organic Electronics & Information Displays(KLOEID)and Institute of Advanced Materials(IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM), Nanjing University of Posts & Telecommunications, Nanjing 210023, China
b.
School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
c.
Institute for Natural & Synthetic Organic Chemistry, Changzhou University, Changzhou 213164, China

Corresponding author: Wang Qi, iamqwang@njupt.edu.cn Jiang Ju-Li, jjl@nju.edu.cn
Received Date: 12 December 2016
Revised Date: 31 January 2017
Accepted Date: 13 February 2017
Available Online: 16 April 2017

Figures(7)

Novel linear supramolecular polymers were successfully constructed by self-assemblies of coumarin-bridged bifunctional UPy derivative.Benefitting from the photodimerization ability of the coumarin moieties, the linear supramolecular polymers could form the large three-dimensional polymer networks upon UV light irradiation via photo-cross-linking, which provides a viable and alternative procedure to modulate the properties of supramolecular polymers.
- Quadruple hydrogen bonding,
- Supramolecular polymers,
- Coumarin unit,
- Photodimerization
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