Citation: Liu Gui-Cheng, Zhang Wen-Qiang, Wang Xiu-Li, Wang Yu-Zhong. Synthesis and performances of poly(butylene-succinate) with enhanced viscosity and crystallization rate via introducing a small amount of diacetylene groups[J]. Chinese Chemical Letters, ;2017, 28(2): 354-357. doi: 10.1016/j.cclet.2016.10.014 shu

Synthesis and performances of poly(butylene-succinate) with enhanced viscosity and crystallization rate via introducing a small amount of diacetylene groups

Center for Degradable and Flame-Retardant Polymeric Materials(ERCPM-MoE), College of Chemistry, State Key Laboratory of Polymer Materials Engineering, National Engineering Laboratory of Eco-Friendly Polymeric Materials(Sichuan), Sichuan University, Chengdu 610064, China

Corresponding author: Wang Xiu-Li, xiuliwang1@163.com Wang Yu-Zhong, yzwang@scu.edu.cn
Received Date: 6 June 2016
Revised Date: 13 September 2016
Accepted Date: 19 September 2016
Available Online: 15 February 2016

Figures(4)

A cross-linkable comonomer containing a diacetylene group, named dimethyl 4,4'-(buta-1,3-diyne-1,4-diyl)dibenzoate (DA) was synthesized and copolymerized with dimethyl succinate and 1,4-butanediol to prepare a series of slightly cross-linked PBS copolyesters (PBDASx). The chemical structure, crystallization and rheological behaviours of PBDASx were well investigated. Compared to neat PBS, PBDASx showed the greatly increased crystallization rate because of the promoting nucleation of the cross-linking domains, and the XRD results indicated that it had no influence on crystallization structure of PBS. The rheological behaviours indicate that PBDASx possessed higher viscosity than neat PBS even at high shear rate and temperature. PBDAS0.3 exhibited better comprehensive properties than neat PBS, which will widen applications of PBS.
- Poly(butylene succinate) (PBS),
- Slightly cross-linking,
- Diacetylene group,
- Crystallization property,
- Rheological behaviour
1. [1]
  J. Xu, B. Guo. Poly(butylene succinate) and its copolymers:research, development and industrialization[J]. Biotechnol. J., 2010,5:1149-1163. doi: 10.1002/biot.v5.11
2. [2]
  R.T. Duan, X. Dong, D.F. Li, X.L. Wang, Y.Z. Wang. Preparation and properties of bio-based PBS multiblock copolyesters containing isosoorbide units[J]. Acta Polym. Sin., 2016,1:70-77.
3. [3]
  D. Kim, W. Kim, D. Lee. Modification of poly(butylene succinate) with peroxide crosslinking physical and thermal properties, and biodegradation[J]. J. Appl. Polym. Sci., 2001,81:1115-1124. doi: 10.1002/(ISSN)1097-4628
4. [4]
  D. The, F. Yoshii, N. Nagasawa. Synthesis of poly(butylene succinate)/glass fiber composite by irradiation and its biodegradability[J]. J. Appl. Polym. Sci., 2004,91:2122-2127. doi: 10.1002/(ISSN)1097-4628
5. [5]
  N. Teramoto, M. Ozeki, I. Fujiwara, M. Shibata. Crosslinking and biodegradation of poly(butylene succinate) prepolymers containing itaconic or maleic acid units in the main chain[J]. J. Appl. Polym. Sci., 2005,95:1473-1480. doi: 10.1002/(ISSN)1097-4628
6. [6]
  X. Huang, C. Li, W. Zhu. Ultraviolet-induced crosslinking of poly(butylene succinate) and its thermal property dynamic mechanical property, and biodegradability[J]. Polym. Adv. Technol., 2011,22:648-656. doi: 10.1002/pat.v22.5
7. [7]
  P. Ma, Z. Ma, W. Dong, Y. Zhang, P.J. Lemstra. Structure/property relationships of partially crosslinked poly(butylene succinate)[J]. Macromol. Mater. Eng., 2013,298:910-918. doi: 10.1002/mame.v298.8
8. [8]
  J.M. Kim, J.S. Lee, H. Choi, D. Sohn, D.J. Ahn. Rational design and in-situ FTIR analyses of colorimetrically reversibe polydiacetylene supramolecules[J]. Macromolecules., 2005,38:9366-9376. doi: 10.1021/ma051551i
9. [9]
  D. Likhatchev, L. Alexandrova, R. Salcedo, T. Ogawa. Topochemical polymerization of butadiynylene dibenzamides[J]. Polym. Bull., 1995,34:149-154. doi: 10.1007/BF00316389
10. [10]
  B. Yoon, H. Shin, E.M. Kang. Inkjet-compatible single-component polydiacetylene precursors for thermochromic paper sensors[J]. ACS Appl. Mater. Interfaces., 2013,5:4527-4535. doi: 10.1021/am303300g
11. [11]
  R.T. Zeng, W. Hu, M. Wang, S.D. Zhang, J.B. Zeng. Morphology, rheological and crystallization behavior in non-covalently functionalized carbon nanotube reinforced poly(butylene succinate) nanocomposites with low percolation threshold[J]. Polym. Test., 2016,50:182-190. doi: 10.1016/j.polymertesting.2016.01.003
12. [12]
  M.H. Al-Saleh, U. Sundararaj. Processing-microstructure-property relationship in conductive polymer nanocomposites[J]. Polymer., 2010,51:2740-2747. doi: 10.1016/j.polymer.2010.03.022
13. [13]
  S.J. Chin, S. Vempati, P. Dawson. Electrical conduction and rheological behaviour of composites of poly(ε-caprolactone) and MWCNTs[J]. Polymer., 2015,58:209-221. doi: 10.1016/j.polymer.2014.12.034
14. [14]
  M. Avrami. Kinetics of phase change. I General theory[J]. J. Chem. Phys., 1939,7:1103-1112. doi: 10.1063/1.1750380
15. [15]
  B. Fillon, B. Lotz, A. Thierry, J.C. Wittmann. Self-nucleation and enhanced nucleation of polymers. definition of a convenient calorimetric efficiency scale and evaluation of nucleating additives in isotactic polypropylene (a phase)[J]. J. Polym. Sci. Polym. Phys., 1993,31:1395-1405. doi: 10.1002/polb.1993.090311014
16. [16]
  B. Fillon, J.C. Wittmann, B. Lotz, A. Thierry. Self-nucleation and recrystallization of isotactic polypropylene (a phase) investigated by differential scanning calorimetry[J]. J. Polym. Sci. Polym. Phys., 1993,31:1383-1393.
17. [17]
  J.B. Zeng, F. Wu, C.L. Huang, Y.S. He, Y.Z. Wang. Urethane ionic groups induced rapid crystallization of biodegradable poly(ethylene succinate)[J]. ACS Macro Lett., 2012,1:965-968. doi: 10.1021/mz300243t
1. [1]
  Haibo Ye , Qianyu Li , Juan Li , Didi Li , Zhimin Ao . Review on the abiotic degradation of biodegradable plastic poly(butylene adipate-terephthalate): Mechanisms and main factors of the degradation. Chinese Chemical Letters, 2025, 36(1): 109861-. doi: 10.1016/j.cclet.2024.109861
2. [2]
  Jun Lu , Jinrui Yan , Yaohao Guo , Junjie Qiu , Shuangliang Zhao , Bo Bao . Controlling solid form and crystal habit of triphenylmethanol by antisolvent crystallization in a microfluidic device. Chinese Chemical Letters, 2024, 35(4): 108876-. doi: 10.1016/j.cclet.2023.108876
3. [3]
  Xin Li , Zhen Xu , Donglei Bu , Jinming Cai , Huamei Chen , Qi Chen , Ting Chen , Fang Cheng , Lifeng Chi , Wenjie Dong , Zhenchao Dong , Shixuan Du , Qitang Fan , Xing Fan , Qiang Fu , Song Gao , Jing Guo , Weijun Guo , Yang He , Shimin Hou , Ying Jiang , Huihui Kong , Baojun Li , Dengyuan Li , Jie Li , Qing Li , Ruoning Li , Shuying Li , Yuxuan Lin , Mengxi Liu , Peinian Liu , Yanyan Liu , Jingtao Lü , Chuanxu Ma , Haoyang Pan , JinLiang Pan , Minghu Pan , Xiaohui Qiu , Ziyong Shen , Qiang Sun , Shijing Tan , Bing Wang , Dong Wang , Li Wang , Lili Wang , Tao Wang , Xiang Wang , Xingyue Wang , Xueyan Wang , Yansong Wang , Yu Wang , Kai Wu , Wei Xu , Na Xue , Linghao Yan , Fan Yang , Zhiyong Yang , Chi Zhang , Xue Zhang , Yang Zhang , Yao Zhang , Xiong Zhou , Junfa Zhu , Yajie Zhang , Feixue Gao , Li Wang . Recent progress on surface chemistry Ⅱ: Property and characterization. Chinese Chemical Letters, 2025, 36(1): 110100-. doi: 10.1016/j.cclet.2024.110100
4. [4]
  Zhongxiong Sun , Haili Song , Mei-Huan Zhao , Yijie Zeng , Man-Rong Li . Structural determination and exotic resistive behaviour of α-RuI3 under high-pressure. Chinese Journal of Structural Chemistry, 2025, 44(2): 100429-100429. doi: 10.1016/j.cjsc.2024.100429
5. [5]
  Yarui Li , Huangjie Lu , Yingzhe Du , Jie Qiu , Peng Lin , Jian Lin . Highly efficient separation of high-valent actinide ions from lanthanides via fractional crystallization. Chinese Journal of Structural Chemistry, 2025, 44(4): 100562-100562. doi: 10.1016/j.cjsc.2025.100562
6. [6]
  Mei Peng , Wei-Min He . Photochemical synthesis and group transfer reactions of azoxy compounds. Chinese Chemical Letters, 2024, 35(8): 109899-. doi: 10.1016/j.cclet.2024.109899
7. [7]
  Mengfan Zhang , Lingyan Liu , Peng Wei , Wei Feng , Tao Yi . A proximity tagging strategy utilizing an activated aldehyde group as the active site. Chinese Chemical Letters, 2025, 36(4): 110127-. doi: 10.1016/j.cclet.2024.110127
8. [8]
  Yijia Jiao , Yuzhu Li , Yuting Zhou , Peipei Cen , Yi Ding , Yan Guo , Xiangyu Liu . Structural evolution and zero-field SMM behaviour in ferromagnetically-coupled disk-type Co₇ clusters bearing exclusively end-on azido bridges. Chinese Chemical Letters, 2024, 35(8): 109082-. doi: 10.1016/j.cclet.2023.109082
9. [9]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
10. [10]
  Hao Cai , Xiaoyan Wu , Lei Jiang , Feng Yu , Yuxiang Yang , Yan Li , Xian Zhang , Jian Liu , Zijian Li , Hong Bi . Lysosome-targeted carbon dots with a light-controlled nitric oxide releasing property for enhanced photodynamic therapy. Chinese Chemical Letters, 2024, 35(4): 108946-. doi: 10.1016/j.cclet.2023.108946
11. [11]
  Ziyi Liu , Xunying Liu , Lubing Qin , Haozheng Chen , Ruikai Li , Zhenghua Tang . Alkynyl ligand for preparing atomically precise metal nanoclusters: Structure enrichment, property regulation, and functionality enhancement. Chinese Journal of Structural Chemistry, 2024, 43(11): 100405-100405. doi: 10.1016/j.cjsc.2024.100405
12. [12]
  Peipei CUI , Xin LI , Yilin CHEN , Zhilin CHENG , Feiyan GAO , Xu GUO , Wenning YAN , Yuchen DENG . Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234
13. [13]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
14. [14]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
15. [15]
  Yuqing Wang , Zhemin Li , Qingjun Lu , Qizhao Li , Jiaxin Luo , Chengjie Li , Yongshu Xie . Solar cells based on doubly concerted companion dyes with the efficiencies modulated by inserting an ethynyl group at different positions. Chinese Chemical Letters, 2024, 35(5): 109093-. doi: 10.1016/j.cclet.2023.109093
16. [16]
  Run-Han Li , Tian-Yi Dang , Wei Guan , Jiang Liu , Ya-Qian Lan , Zhong-Min Su . Evolution exploration and structure prediction of Keggin-type group IVB metal-oxo clusters. Chinese Chemical Letters, 2024, 35(5): 108805-. doi: 10.1016/j.cclet.2023.108805
17. [17]
  Junchen Peng , Xue Yin , Dandan Dong , Zhongyuan Guo , Qinqin Wang , Minmin Liu , Fei He , Bin Dai , Chaofeng Huang . Promotion effect of epoxy group neighboring single-atom Cu site on acetylene hydrochlorination. Chinese Chemical Letters, 2024, 35(6): 109508-. doi: 10.1016/j.cclet.2024.109508
18. [18]
  Yu-Yu Tan , Lin-Heng He , Wei-Min He . Copper-mediated assembly of SO₂F group via radical fluorine-atom transfer strategy. Chinese Chemical Letters, 2024, 35(9): 109986-. doi: 10.1016/j.cclet.2024.109986
19. [19]
  Wenyu Gao , Liming Zhang , Chuang Zhao , Lixiang Liu , Xingran Yang , Jinbo Zhao . Controlled semi-Pinacol rearrangement on a strained ring: Efficient access to multi-substituted cyclopropanes by group migration strategy. Chinese Chemical Letters, 2024, 35(9): 109447-. doi: 10.1016/j.cclet.2023.109447
20. [20]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(708)
HTML views(41)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142