Citation: Guo Zhi-Yan, Zhong Yang, Liu Yu, Mao Chang-Ming, Li Gui-Cun. MoS₂ nanosheet arrays supported on hierarchical porous carbon with enhanced lithium storage properties[J]. Chinese Chemical Letters, ;2017, 28(4): 743-747. doi: 10.1016/j.cclet.2016.10.007 shu

MoS₂ nanosheet arrays supported on hierarchical porous carbon with enhanced lithium storage properties

College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China

Corresponding author: Mao Chang-Ming, mcm@qust.edu.cn Li Gui-Cun, guicunli@qust.edu.cn
Received Date: 13 July 2016
Revised Date: 23 September 2016
Accepted Date: 29 September 2016
Available Online: 14 April 2016

Figures(6)

MoS₂ nanosheet arrays supported on hierarchical nitrogen-doped porous carbon(MoS₂@C)have been synthesized by a facile hydrothermal approach combined with high-temperature calcination.The hierarchical nitrogen-doped porous carbon can serve as three-dimensional conductive frameworks to improve the electronic transport of semiconducting MoS₂.When evaluated as anode material for lithium-ion batteries, the MoS₂@C exhibit enhanced electrochemical performances compared with pure MoS₂ nanosheets, including high capacity(1305.5 mA h g^-1 at 100 mA g^-1), excellent rate capability (438.4 mA h g^-1 at 1000 mA g^-1).The reasons for the improved electrochemical performances are explored in terms of the high electronic conductivity and the facilitation of lithium ion transport arising from the hierarchical structures of MoS₂@C.
- Molybdenum disulfide,
- Hydrothermal,
- Nitrogen-doped porous carbon,
- Anode material,
- Lithium-ion batteries
1. [1]
  Goodenough J.B., Park K.S.. The Li-ion rechargeable battery:a perspective[J]. J. Am.Chem.Soc., 2013,135:1167-1176. doi: 10.1021/ja3091438
2. [2]
  Tarascon J.M., Armand M.. Issues and challenges facing rechargeable lithium batteries[J]. Nature, 2001,414:359-367. doi: 10.1038/35104644
3. [3]
  Tang Y.X., Zhang Y.Y., Li W.L., Ma B., Chen X.D.. Rational material design for ultrafast rechargeable lithium-ion batteries[J]. Chem.Soc.Rev., 2015,44:5926-5940. doi: 10.1039/C4CS00442F
4. [4]
  Yang S.L., Zhou B.H., Lei M.. Sub-100 nm hollow SnO₂@C nanoparticles as anode material for lithium ion batteries and significantly enhanced cycle performances[J]. Chin.Chem.Lett., 2015,26:1293-1297. doi: 10.1016/j.cclet.2015.05.051
5. [5]
  Chhowalla M., Shin H.S., Eda G.. The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets[J]. Nat.Chem., 2013,5:263-275. doi: 10.1038/nchem.1589
6. [6]
  Ramakrishna Matte H.S.S., Gomathi A., Manna A.K.. MoS₂ and WS₂ analogues of graphene[J]. Angew.Chem., 2010,122:4153-4156. doi: 10.1002/ange.201000009
7. [7]
  Yang L.C., Wang S.N., Mao J.J.. Hierarchical MoS₂/polyaniline nanowires with excellent electrochemical performance for lithium-ion batteries[J]. Adv. Mater., 2013,25:1180-1184. doi: 10.1002/adma.201203999
8. [8]
  Laursen A.B., Kegnæs S., Dahl S., Chorkendorff I.. Molybdenum sulfides-efficient and viable materials for electro-and photoelectrocatalytic hydrogen evolution[J]. Energy Environ.Sci., 2012,5:5577-5591. doi: 10.1039/c2ee02618j
9. [9]
  Zhang L., Lou X.W.. Hierarchical MoS₂ shells supported on carbon spheres for highly reversible lithium storage[J]. Chem.Eur.J., 2014,20:5219-5223. doi: 10.1002/chem.v20.18
10. [10]
  Guo Z.Y., Zhong Y., Xuan Z.W.. Polypyrrole-assisted synthesis of roselike MoS₂/nitrogen-containing carbon/graphene hybrids and their robust lithium storage performances[J]. RSC Adv., 2015,5:62624-62629. doi: 10.1039/C5RA09092J
11. [11]
  Mao C.M., Zhong Y., Shang H.J.. Carbon encapsulated nanosheet-assembled MoS₂ nanospheres with highly reversible lithium storage[J]. Chem. Eng.J., 2016,304:511-517. doi: 10.1016/j.cej.2016.06.120
12. [12]
  Zuo X.X., Chang K., Zhao J.. Bubble-template-assisted synthesis of hollow fullerene-like MoS₂ nanocages as a lithium ion battery anode material[J]. J. Mater.Chem.A, 2016,4:51-58. doi: 10.1039/C5TA06869J
13. [13]
  Ding S.J., Chen J.S., Lou X.W.. Glucose-assisted growth of MoS₂ nanosheets on CNT backbone for improved lithium storage properties[J]. Chem.Eur.J., 2011,17:13142-13145. doi: 10.1002/chem.201102480
14. [14]
  Wang J., Liu J.L., Chao D.L.. Self-assembly of honeycomb-like MoS₂ nanoarchitectures anchored into graphene foam for enhanced lithium-ion storage[J]. Adv.Mater., 2014,26:7162-7169. doi: 10.1002/adma.v26.42
15. [15]
  Deng Z.Q., Hu Y.J., Ren D.Y.. Reciprocal hybridization of MoO₂ nanoparticles and few-layer MoS₂ for stable lithium-ion batteries[J]. Chem. Commun., 2015,51:13838-13841. doi: 10.1039/C5CC05069C
16. [16]
  Liao J.Y., De Luna B., Manthiram A.. TiO₂-B nanowire arrays coated with layered MoS₂ nanosheets for lithium and sodium storage[J]. J.Mater.Chem.A, 2016,4:801-806. doi: 10.1039/C5TA07064C
17. [17]
  Wu Z.S., Ren W.C., Xu L., Li F., Cheng H.M.. Doped graphene sheets as anode materials with superhigh rate and large capacity for lithium ion batteries[J]. ACS Nano, 2011,5:5463-5471. doi: 10.1021/nn2006249
18. [18]
  Zhang Z.H., Zhou Z.F., Peng H.R., Qin Y., Li G.C.. Nitrogen-and oxygen-containing hierarchical porous carbon frameworks for high-performance supercapacitors[J]. Electrochim.Acta, 2014,134:471-477. doi: 10.1016/j.electacta.2014.04.107
19. [19]
  Zhang L., Wu H.B., Yan Y., Wang X., Lou X.W.. Hierarchical MoS₂ microboxes constructed by nanosheets with enhanced electrochemical properties for lithium storage and water splitting[J]. Energy Environ.Sci., 2014,7:3302-3306. doi: 10.1039/C4EE01932F
20. [20]
  Li G.C., Zhang Z.H., Peng H.R., Chen K.Z.. Mesoporous hydrogenated TiO₂ microspheres for high rate capability lithium ion batteries[J]. RSC Adv., 2013,3:11507-11510. doi: 10.1039/c3ra41858h
21. [21]
  Zhang S.P., Chowdari B.V.R., Wen Z.Y., Jin J., Yang J.H.. Constructing highly oriented configuration by few-layer MoS₂:toward high-performance lithium-ion batteries and hydrogen evolution reactions[J]. ACS Nano, 2015,9:12464-12472. doi: 10.1021/acsnano.5b05891
22. [22]
  Chen B., Liu E.Z., He F.. 2D sandwich-like carbon-coated ultrathin TiO₂@defect-rich MoS₂ hybrid nanosheets:synergistic-effect-promoted electrochemical performance for lithium ion batteries[J]. Nano Energy, 2016,26:541-549. doi: 10.1016/j.nanoen.2016.06.003
23. [23]
  Hu S., Chen W., Zhou J.. Preparation of carbon coated MoS₂ flower-like nanostructure with self-assembled nanosheets as high-performance lithium-ion battery anodes[J]. J.Mater.Chem.A, 2014,2:7862-7872. doi: 10.1039/c4ta01247j
24. [24]
  Chang K., Geng D.S., Li X.F.. Ultrathin MoS₂/nitrogen-doped graphene nanosheets with highly reversible lithium storage[J]. Adv.Energy Mater., 2013,3:839-844. doi: 10.1002/aenm.v3.7
25. [25]
  Wang P.P., Sun H.Y., Ji Y.J., Li W.H., Wang X.. Three-dimensional assembly of single-layered MoS₂[J]. Adv.Mater., 2014,26:964-969. doi: 10.1002/adma.v26.6
26. [26]
  Lingappan N., Van N.H., Lee S., Kang D.J. Growth of three dimensional flower-like molybdenum disulfide hierarchical structures on graphene/carbon nanotube network:an advanced heterostructure for energy storage devices[J]. J. Power Sources, 2015,280:39-46. doi: 10.1016/j.jpowsour.2015.01.064
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MoS₂ nanosheet arrays supported on hierarchical porous carbon with enhanced lithium storage properties